Using the molten salt and polyvinyl alcohol-protected reduction method,we fabricated Co3O4 octahedron-supported Au-Pd（x（AuPdy）/Co3O4;x =（0.18,0.47,and 0.96） wt%;y（Pd/Au molar ratio） =1.85-1.97） nanocatalysts.T...Using the molten salt and polyvinyl alcohol-protected reduction method,we fabricated Co3O4 octahedron-supported Au-Pd（x（AuPdy）/Co3O4;x =（0.18,0.47,and 0.96） wt%;y（Pd/Au molar ratio） =1.85-1.97） nanocatalysts.The molten salt-derived Co3O4 sample possessed well-defined octahedral morphology,with an edge length of 300 nm.The Au-Pd nanoparticles,with sizes of 2.7-3.2 nm,were uniformly dispersed on the surface of Co3O4.The 0.96（AuPd1.92）/Co3O4 sample showed the highest catalytic activity for toluene and o-xylene oxidation,and the temperature required for achieving 90%conversion of toluene and o-xylene was 180 and 187 ℃,respectively,at a space velocity of 40000 mL/（g·h）.The high catalytic performance of Co3O4 octahedron-supported Au-Pd nanocatalysts was associated with the interaction between Au-Pd nanoparticles and Co3O4 and high concentration of adsorbed oxygen species.展开更多
基金supported by the National Natural Science Foundation of China (21377008, 21477005, U1507108)National High Technology Re-search and Development Program of China (2015AA034603)+1 种基金Beijing Nova Program (Z141109001814106)Natural Science Foundation of Bei-jing Municipal Commission of Education (KM201410005008)~~
文摘Using the molten salt and polyvinyl alcohol-protected reduction method,we fabricated Co3O4 octahedron-supported Au-Pd（x（AuPdy）/Co3O4;x =（0.18,0.47,and 0.96） wt%;y（Pd/Au molar ratio） =1.85-1.97） nanocatalysts.The molten salt-derived Co3O4 sample possessed well-defined octahedral morphology,with an edge length of 300 nm.The Au-Pd nanoparticles,with sizes of 2.7-3.2 nm,were uniformly dispersed on the surface of Co3O4.The 0.96（AuPd1.92）/Co3O4 sample showed the highest catalytic activity for toluene and o-xylene oxidation,and the temperature required for achieving 90%conversion of toluene and o-xylene was 180 and 187 ℃,respectively,at a space velocity of 40000 mL/（g·h）.The high catalytic performance of Co3O4 octahedron-supported Au-Pd nanocatalysts was associated with the interaction between Au-Pd nanoparticles and Co3O4 and high concentration of adsorbed oxygen species.
