Methylene-bis[benzobicyclo(diaza-diphenyl) stannoxide,C_(41)H_(34)N_4O_4Sn_2·1/2C_6H_6],Mr=923.19,m.p.126-127℃,triclinic,P1,a=9.780(4),b=14.485(2),c=15.122(6),α=74. 95(3),β=72.21(3),γ=82.68(2)°,V=1967(1)...Methylene-bis[benzobicyclo(diaza-diphenyl) stannoxide,C_(41)H_(34)N_4O_4Sn_2·1/2C_6H_6],Mr=923.19,m.p.126-127℃,triclinic,P1,a=9.780(4),b=14.485(2),c=15.122(6),α=74. 95(3),β=72.21(3),γ=82.68(2)°,V=1967(1) Z=2,Dx=1.56 g/cm￣3, MoKα(λ=0.71073),μ=13.20 cm-1,F(000)=922;final R=0.045, Rw=0.046 for 3637 observed reflections(I≥3σ(I)).The title compound is a bimetallo-heterocyclic complex prepared by condensation.Each tin atom has a trigonal bipyramidal coordination with two oxygen atoms occupying the axial positions.展开更多
文摘Methylene-bis[benzobicyclo(diaza-diphenyl) stannoxide,C_(41)H_(34)N_4O_4Sn_2·1/2C_6H_6],Mr=923.19,m.p.126-127℃,triclinic,P1,a=9.780(4),b=14.485(2),c=15.122(6),α=74. 95(3),β=72.21(3),γ=82.68(2)°,V=1967(1) Z=2,Dx=1.56 g/cm￣3, MoKα(λ=0.71073),μ=13.20 cm-1,F(000)=922;final R=0.045, Rw=0.046 for 3637 observed reflections(I≥3σ(I)).The title compound is a bimetallo-heterocyclic complex prepared by condensation.Each tin atom has a trigonal bipyramidal coordination with two oxygen atoms occupying the axial positions.
