Microstructure and mechanical properties of new Mg-Zn-Y-Zr alloys with high castability and ignition resistance

Complex studies of new Mg-Zn-Y-Zr system alloys have been carried out.The content range for the formation of the two-phase structure MgSS(Mg solid solution)+LPSO(long-period stacking ordered)in alloys of the Mg-Zn-Y-Zr system was determined by thermodynamic calculations.The effect of heat treatment regimes on microstructure,mechanical,and corrosion properties was invest-igated.The fluidity,hot tearing tendency,and ignition temperature of the alloys were determined.The best combination of castability,mechanical,and corrosion properties was found for the Mg-2.4Zn-4Y-0.8Zr alloy.The alloys studied are superior to their industrial counterparts in terms of technological properties,while maintain high corrosion and mechanical properties.The increased level of pro-perties is achieved by a suitable heat treatment regime that provides a complete transformation of the 18R to 14H modification of the LPSO phase.

Nitrogen-Doped Chemical Vapour Deposited Diamond： a New Material for Room-Temperature Solid State Maser

Electron spin resonance （ESR） in polycrystalline diamond films grown by dc arc-jet and microwave plasma chemical vapour deposition is studied. The films with nitrogen impurity concentration up to 8 × 10^18 cm^-3 are also characterized by Raman, cathodoluminescence and optical absorption spectra. The ESR signal from P1 centre with g-factor of 2.0024 （nitrogen impurity atom occupying C site in diamond lattice） is found to exhibit an inversion with increasing the microwave power in an H102 resonator. The spin inversion effect could be of interest for further consideration of N-doped diamonds as a medium for masers operated at room temperature.

Structure,mechanical characteristics,biodegradation,and in vitro cytotoxicity of magnesium alloy ZX11 processed by rotary swaging

Rotary swaging(RS)of alloy Mg-1.03Zn-0.66Ca(ZX11)was shown to refine the average grain size to 4.5±1.2μm in a longitudinal section and 4.8±0.9μm in a transverse section.In addition,a small amount of Mg2Ca particles about 300nm in size and Mg6Zn3Ca2 particles with a size of about lOOnm was detected.This resulted in pronounced strengthening:the yield strength and the ultimate tensile strength rose to 210±8 MPa and 276±6 MPa,respectively,while the elongation hardly decreased(22.0±1.8% and 18.3±2.9% before and after RS).Furthermore,RS led to an increase in the fatigue limit of the alloy from 120 MPa to 135 MPa and did not impair its resistance to chemical corrosion.The studies in vitro showed that ZX11 induces hemolysis without inhibiting the viability of peripheral blood mononuclear cells and has a more pronounced cytotoxic effect on tumor cells in comparison with non-transformed cells.No significant difference of the latter effect between the initial and the deformed states was observed.

To the space by laser light (II)

New approach to the problem of laser jet engine (LJE) creation is based on the use of shock waves (SW) resonance association mechanism, generated by the optical pulsating discharge (OPD). For the creation OPD is proposed to use powerful pulse - periodic (P-P) laser radiation with duration of pulses ~ 100 - 150 ns and high pulse repetition frequency ~ 50 - 100 kHz. OPD is formed with the help of matrix of reflectors (MR). This is allowed: several times to increase the effectiveness of laser emission use for purposes of LJE creation, to avoid strong impact loads on the apparatus, to exclude the thermal action of laser plasma on the reflector, to decrease the laser emission screening by plasma, to remove the problem of the resonance oscillations appearance into the object moved with the help of laser. In our article the estimations of possible LJE thrust levels under the conditions of the proposed mechanism of reactive motion are given. Also, the new approaches to the creation of the high power high repetition rate laser systems for the “Impulsar” program are examined.

Outgassing from internal adhesive joints of vacuum devices

Kinetics of the formation of residual atmosphere in vacuum devices with internal adhesive joints and the application of the mass spectral and chromatographic methods to measure the specific outgassing rate of volatile compounds from the cured adhesives are considered in this paper.The outgassing comparison data for the various types of adhesives are given and the effectiveness of the outgassing of adhesive joints is demonstrated.The possible options to provide vacuum in the various devices are considered.At moderate requirements to the residual pressure(about10-2Pa),it is enough to degass the adhesive joints during a few hours.It is much more difficult to provide vacuum in devices with internal adhesive joints at the level of about10-4Pa.This requires the use of the built-in getter and the high temperature degassing.It is expedient to provide deep vacuum(10-5-10-4Pa)in the rare-used or once-used devices by short(a few minutes)activation the built-in getters before operating the vacuum devices.This allows to remove the main residual gas hydrocarbons component from the vacuum house and provide the necessary level of vacuum for a certain interval of time.

Long channel for energy deliver (III)

At present time the development of new methods of the single-wire long distance energy transfer is of great interest of science. These works are the prolongation and development of Tesla studies in the beginning of XX century. In particular, not so long ago highly effective energy transfer between two resonant circuits, connected by very thin wire (100 mkm) with more than kilometer length had been demonstrated. In these experiments Tesla type transformers with the output voltage about several ten kilovolts and output power up to 10 kW were used [1]. An effective replacement of wire by laser-plasma channel in that configuration of experiment would be the obvious improvement of demonstrated technology.

High power lasers and ecology of atmosphere (I)

There are many appearances in the literature of reliable observations of studying so-called “jets” and “sprites” - the discharges in the gigantic natural capacitor “Ionosphere-Earth” [1]. The volume of such a discharge is approximately 5-10 thousand cubic kilometers and usually it appears above the surface of ocean. There are the cases also of above mentioned discharges on the ground. The value of the energy transferred to the earth can comprise to several terajoule. Events are accompanied by the emission of the waves of ultra-low frequency. Their study has the significant interest from many points of view. The essence of the observed irregular phenomena consists of the electromechanical conversion of the energy excesses of natural electricity into mechanical and thermal energy of cyclones, typhoons and other natural cataclysms. The ionosphere can retain only the specific quantity of energy. Otherwise, it discards the surpluses of electricity through the atmosphere or transforms them into the energy of storms, in that number and inside the Earth. By using the part of the natural electricity for useful purposes it is possible to govern the weather of planet. Causing the artificial breakdowns of the ionosphere it could be possible to arrange the discharge of the controlled aqueous sediments at the necessary points of the globe. It could be possible as well to attempt to regulate the climate of planet and to decrease the amplitudes of the magnetic storms, earthquakes and hurricanes.

Nonlinear Change in Refractive Index and Transmission Coefficient of ZnSe:Fe²⁺at Long-Pulse 2.94-μm Excitation

An experimental study of the nonlinear changes in refractive index and transmission coefficient of single-crystal ZnSe:Fe2+, fabricated through the Fe-diffusion method, at long-pulse (~300 ns), sub-mJ, 2.94-mm Z-scan probing is reported. As well, a theoretical model based on the generalized Avizonis-Grotbeck equations is developed and applied for straightforward fitting of the open- and closed-aperture Z-scans, obtained for ZnSe:Fe2+ with different Fe2+ centers concentrations. The modeling results reveal that the contributions in the absorption and refractive index nonlinearities of ZnSe:Fe2+ are “common” resonant-absorption saturation (the minor part) and pulse-induced heating of the samples (the major part), which are strongly dependent on Fe2+ concentrations. Large values of the index change (>~10-3) and partial resonant-absorption bleaching (limited by ~50%), both produced via the thermal effect mainly, are the features of the ZnSe:Fe2+ samples inherent to this type of excitation.

Conductive Channel for Energy Transmission

Laser spark obtained by using a conical optics is much more appropriate to form conducting channels in atmosphere. Only two types of lasers are actively considered to be used in forming high-conductivity channels in atmosphere, controlled by laser spark： pulsed sub-microsecond gas and chemical lasers （CO2, DF （deuterium fluoride））, short pulse solid-state and UV （ultraviolet） lasers. Main advantage of short pulse lasers is their ability in forming of super long ionized channels with a characteristic diameter of- 100 mm in atmosphere along the beam propagation direction. At estimated electron densities below 1,016 cm3 in these filaments and laser wavelengths in the range of 0.5-1.0 mm, the plasma barely absorbs laser radiation. In this case, the length of the track composed of many filaments is determined by the laser intensity and may reach many kilometers at a femtosecond pulse energy of-100 mJ. However, these lasers could not be used to form high-conductivity long channels in atmosphere. The ohmic resistance of this type a conducting channels turned out to be very high, and the gas in the channels could not be strongly heated （〈 1 J）. An electric breakdown controlled by radiation of femtosecond solid-state laser was implemented in only at a length of 3 m with a voltage of 2 MV across the discharge gap （670 kV/m）. Not so long ago scientific group from P.N. Lebedev physical institute has improved that result, the discharge gap （-1m） had been broken under KrF laser irradiation when switching high-voltage （up to 390 kV/m） electric discharge by 100-ns UV pulses. Our previous result -16 m long conducting channel controlled by a laser spark at the voltage -3 MV was obtained more than 20 years ago in Russia and Japan by using pulsed CO2 laser with energy -0.5 kJ. An average electric field strength was 〈 190 kV/m. It is still too much for efficient applications.

Structure and transport properties of zirconia crystals co-doped by scandia,ceria and yttria

This work is a study of the effect of co-doping(ZrO_(2))_(0.9)(Sc_(2)O_(3))_(0.1)solid solution with yttria and/or ceria on the phase composition,local structure and transport properties of the crystals.The solid solution crystals were grown using directional melt crystallization in cold crucible.We show that ceria co-doping of the crystals does not stabilize the high-temperature cubic phase in the entire crystal bulk,unlike yttria codoping.Ceria co-doping of the(ZrO_(2))_(0.9)(Sc_(2)O_(3))_(0.1)crystals increases their conductivity,whereas the addition of 1 mol.%yttria tangibly reduces the conductivity.Equimolar co-doping of the(ZrO_(2))0.9(-Sc_(2_O_(3))0.1 crystals with ceria and yttria changes the conductivity but slightly.Optical spectroscopy of the local structure of the crystals identified different types of optical centers.We found that the fraction of the trivalent cations having a vacancy in the first coordination sphere in the ceria co-doped crystals is smaller compared with that in the yttria co-doped crystals.

Low Temperature Growth of SWNTs on a Nickel Catalyst by Thermal Chemical Vapor Deposition

Single-walled carbon nanotubes （SWNTs） have been grown on a silica-supported monometallic nickel （Ni） catalyst at temperatures ranging from as low as 450℃to 800℃. Different spectroscopic techniques, such as Raman, photoluminescence emission （PLE）, and ultra violet-visible-near infrared （UV-vis-NIR） absorption spectroscopy were used to evaluate file diameter and quality of the SWNTs grown over the Ni catalyst at different temperatures. The analysis revealed that high quality SWNTs with a very narrow diameter distribution were obtained at a growth temperature of 500 ℃. In the PLE and absorption spectra, differences were observed between the SWNTs grown oil Ni and those grown on cobalt （Co）. This result expands the potential of growing a specific （n, m） tube species with relatively high abundance by tuning the catalyst composition. Furthermore, the prerequisites for the low temperature growth of SWNTs over a monometallic transition metal catalyst have been elucidated.