Magnetic refrigeration is a revolutionary, efficient, environmentally friendly cooling technology, which is on the threshold of commercialization. The magnetic rare earth materials are utilized as the magnetic refrige...Magnetic refrigeration is a revolutionary, efficient, environmentally friendly cooling technology, which is on the threshold of commercialization. The magnetic rare earth materials are utilized as the magnetic refrigerants in most cooling devices, and for many cooling application the Nd2Fe14B permanent magnets are employed as the source of the magnetic field. The status of the near room temperature magnetic cooling was reviewed.展开更多
Fish oils are important substances in the field of food and drug delivery.Due to their unstable double bonds,fishy taste,and poor water solubility,it is pivotal to investigate novel dosage forms for fish oils,such as ...Fish oils are important substances in the field of food and drug delivery.Due to their unstable double bonds,fishy taste,and poor water solubility,it is pivotal to investigate novel dosage forms for fish oils,such as encapsulated droplets.In this work,we primarily prepared gelatin-stabilized fish oil-loaded traditional emulsions and investigated their emulsion forms,droplets,and storage stability under different preparation and storage conditions.Our results showed that higher gelatin solution pH,higher storage temperature in the range of 4–37℃,and increased storage time induced the emulsion form switch from a liquid form to a redispersible gel form of the fish oil emulsion.The droplets had core-shell microstructures and a trimodal size distribution,which decreases linearly with increasing gelatin solution pH and homogenizing time,but decreases exponentially with increasing homogenizing speed.In addition,storage temperature showed a notably different effect on traditional emulsion storage.This work provides a fundamental knowledge for the formation,microstructure,and properties of gelatin-based traditional emulsions.It also provides a promising new application for fish oil-loaded emulsions in food beverages,soft candy,and other food products.展开更多
Anion exchange membrane(AEM)fuel cells have gained great attention partially due to the advantage of using non-precious metal as catalysts.However,the reaction kinetics of hydrogen oxidation reaction(HOR)is two orders...Anion exchange membrane(AEM)fuel cells have gained great attention partially due to the advantage of using non-precious metal as catalysts.However,the reaction kinetics of hydrogen oxidation reaction(HOR)is two orders of magnitude slower in alkaline systems than in acid.To understand the slower kinetics of HOR in base,two major theories have been proposed,such as(1)pH dependent hydrogen binding energy as a major descriptor for HOR;and(2)bifunctional theory based on the contributions of both hydrogen and hydroxide adsorption for HOR in alkaline electrolyte.Here,we discuss the possible HOR mechanisms in alkaline electrolytes with the corresponding change in their Tafel behavior.Apart from the traditional Tafel-Volmer and Heyrovsky-Volmer HOR mechanisms,the recently proposed hydroxide adsorption step is also discussed to illustrate the difference in HOR mechanisms in acid and base.We further summarize the representative works of alkaline HOR catalyst design(e.g.,precious metals,alloy,intermetallic materials,Ni-based alloys,carbides,nitrides,etc.),and briefly describe their fundamental HOR reaction mechanism to emphasize the difference in elementary reaction steps in alkaline medium.The strategy of strengthening local interaction that facilitates both H2 desorption and Hads+OHads recombination is finally proposed for future HOR catalyst design in alkaline environment.展开更多
The production of chemicals from lignocellulosic biomass provides opportunities to synthesize chemicals with new functionalities and grow a more sustainable chemical industry. However, new challenges emerge as researc...The production of chemicals from lignocellulosic biomass provides opportunities to synthesize chemicals with new functionalities and grow a more sustainable chemical industry. However, new challenges emerge as research transitions from petrochemistry to biorenewable chemistry. Compared to petrochemisty, the selective conversion of biomass-derived carbohydrates requires most catalytic reactions to take place at low temperatures (< 300 °C) and in the condensed phase to prevent reactants and products from degrading. The stability of heterogeneous catalysts in liquid water above the normal boiling point represents one of the major challenges to overcome. Herein, we review some of the latest advances in the field with an emphasis on the role of carbon materials and carbon nanohybrids in addressing this challenge.展开更多
Energy-proportional computing is one of the foremost constraints in the design of next generation exascale systems. These systems must have a very high FLOP-per-watt ratio to be sustainable, which requires tremendous ...Energy-proportional computing is one of the foremost constraints in the design of next generation exascale systems. These systems must have a very high FLOP-per-watt ratio to be sustainable, which requires tremendous improvements in power efficiency for modern computing systems. This paper focuses on the processor—as still the biggest contributor to the power usage—by considering both its core and uncore power subsystems. The uncore describes those processor functions that are not handled by the core, such as L3 cache and on-chip interconnect, and contributes significantly to the total system power. The uncore frequency scaling (UFS) capability has been available to the user since the Intel Haswell processor generation. In this paper, performance and power models are proposed to use both the UFS and dynamic voltage and frequency scaling (DVFS) to reduce the energy consumption in parallel applications. Then, these models are incorporated into a runtime strategy that performs processor frequency scaling during parallel application execution. The strategy can be implemented at the kernel/firmware level, which makes it suitable for improving the energy efficiency of exascale design. Experiments on a 20-core Haswell-EP machine using the quantum chemistry application GAMESS and NAS benchmark resulted in up to 24% energy savings with as little as 2% performance loss.展开更多
The properties of Pbn（n=2―30） clusters including binding energies,second differences in energy,and HOMO-LUMO gaps,especially fragmentation energies and ionization potentials,have been studied by ab initio calculati...The properties of Pbn（n=2―30） clusters including binding energies,second differences in energy,and HOMO-LUMO gaps,especially fragmentation energies and ionization potentials,have been studied by ab initio calculation.The main fragmentation products of Pbn＋ are shown to be Pb＋Pbn-1＋ for n≤14 and two small cluster fragments for larger ones with n14.The Pb13＋ appears frequently as the products in the fragmentations of large clusters.Also,the calculated ionization potentials of the clusters are consistent with the experiment data.展开更多
A new rare-earth magnet recycling process developed by researchers at the Critical Materials Institute (CMI) dissolves magnets in an acid-free solution and recovers high purity rare earth elements. For shredded magnet...A new rare-earth magnet recycling process developed by researchers at the Critical Materials Institute (CMI) dissolves magnets in an acid-free solution and recovers high purity rare earth elements. For shredded magnet-containing electronic wastes, the process does not require pre-processing such as pre-sorting or demagnetization of the electronic waste.展开更多
The formation and evolution of glacier moraine-dammed lakes are closely related to past glacier expansion and retreat. Geomorphic markers such as lacustrine terraces and beach ridges observed in these lakes provide im...The formation and evolution of glacier moraine-dammed lakes are closely related to past glacier expansion and retreat. Geomorphic markers such as lacustrine terraces and beach ridges observed in these lakes provide important evidence for regional paleoenvironment reconstruction. We document the magnitude of paleo-shoreline fluctuations and timings of highstands of lake water by using cosmogenic 10Be surface exposure dating and optically stimulated luminescence(OSL) dating on samples collected from lacustrine sediment and bedrock strath in Lake Khagiin Khar. The lake was initially impounded by glacier moraine at the Global Last Glacial maximum(gLGM;21–19 ka), and the lake reached its maximum paleo-shoreline level of 1840 m at sea level(a.s.l.). At that time, the stored lake water amount was up to seven times greater and the surface area was three times larger than the present values. The paleolake experienced higher shoreline levels at 1832, 1822, and 1817 m a.s.l. and reached the present lake level after 0.4 ka. We interpret that decrease in the paleolake level was caused by spillover. The increase in melt water after the gLGM and the Late Glacial exceeded the storage threshold of the lake, and the paleolake water overflowed across the lowest drainage divides. The lake spilled over across the lowest bedrock ridge at 15.9 ± 0.6 ka, and the outlet was incised since that time at a rate of 3.72 ± 0.15 mm/yr. The initial stream of the Khiidiin Pass River was disturbed by LGM moraine damming and was rerouted into the present course running through moraine after the spillover at 15.9 ± 0.6 ka.展开更多
Understanding of metal oxidation is very critical to corrosion control,catalysis synthesis,and advanced materials engineering.Metal oxidation is a very complex phenomenon,with many different processes which are couple...Understanding of metal oxidation is very critical to corrosion control,catalysis synthesis,and advanced materials engineering.Metal oxidation is a very complex phenomenon,with many different processes which are coupled and involved from the onset of reaction.In this work,the initial stage of oxidation on titanium surface was investigated in atomic scale by molecular dynamics(MD)simulations using a reactive force field(ReaxFF).We show that oxygen transport is the dominant process during the initial oxidation.Our simulation also demonstrate that a compressive stress was generated in the oxide layer which blocked the oxygen transport perpendicular to the Titanium(0001)surface and further prevented oxidation in the deeper layers.The mechanism of initial oxidation observed in this work can be also applicable to other self-limiting oxidation.展开更多
The Transantarctic Mountains are an important corridor between the East Antarctic Ice Sheet and the Western Ross Sea,where most current ice streams and outlet glaciers arise.We investigated Ricker Hills,the largest ex...The Transantarctic Mountains are an important corridor between the East Antarctic Ice Sheet and the Western Ross Sea,where most current ice streams and outlet glaciers arise.We investigated Ricker Hills,the largest exposed mountainous region between Southern Victoria Land and Terra Nova Bay,and dated the glacial landforms using in-situ cosmogenic-nuclide 10 Be surface exposure dating to reconstruct the paleo-glacial dynamics.The surface of the Hollingsworth glacier lowered since the middle of Marine Isotope Stage(MIS)2(22.1 ka);therefore,the Last Glacial Maximum(LGM)occurred before that period.Cosmogenic,geomorphic,and climatic records constrained the glacial surface slope to be between 5.4°and 6.8°.The ice was 270-320 m thicker at the LGM(MIS 2)than presently but did not override the top surface of the Benson Knob.Moreover,previous glacial periods such as the local LGM(MIS 4)or Penultimate Glacial Maximum(MIS 6)maintained thicker ice than the LGM(MIS 2).The Ross Ice Shelf opening during the mid-Holocene(~6 ka)caused the rapid collapse of the terminal outlet glaciers and supplied notable snow accumulation upstream,which stagnated lowering.The greatest lowering and retreat occurred during the late Holocene(2.3~0.8 ka),when elephant seal colonies thrived in the Ross Embayment.展开更多
It was found for the first time that the compounds with only one functional group, such as pyridine, can show the promotion effect for the electrochemical reaction of cytochrome C at gold electrodes.
Energy efficiency and energy-proportional computing have become a central focus in modern supercomputers. These supercomputers should provide high throughput per unit of power to be sustainable in terms of operating c...Energy efficiency and energy-proportional computing have become a central focus in modern supercomputers. These supercomputers should provide high throughput per unit of power to be sustainable in terms of operating cost and failure rates. In this paper, a power-bounded strategy is proposed that maximizes parallel application performance under a given power constraint. The strategy dynamically allocates power to core, uncore, and memory power domains within a node to maximize performance under a given power budget. Experiments on a 20-core Haswell-EP platform for a real-world parallel application GAMESS demonstrate that the proposed strategy delivers performance within 4% of the best possible performance for as much as 25% reduction in the minimum power budget required for maximum performance.展开更多
The world has become highly dependent on reliable refrigeration technology. Without it, our food supply would be still seasonal and limited to locally produced nonperishable items; comfortable living conditions via cl...The world has become highly dependent on reliable refrigeration technology. Without it, our food supply would be still seasonal and limited to locally produced nonperishable items; comfortable living conditions via climate control would be impossible; and certain medical advancements, e.g. MRI diagnostics, organ transplantation, organ and tissue cryo-storage, and cryo-surgery would be impossible. This technology remains essentially unchanged since it was invented 100 years ago.展开更多
基金Project supported bythe U.S .Department of Energy ,Office of Basic Energy Sciences , Materials Science and Engineering Division and Astronautics Corporation of America , Milwaukee , Wisconsin
文摘Magnetic refrigeration is a revolutionary, efficient, environmentally friendly cooling technology, which is on the threshold of commercialization. The magnetic rare earth materials are utilized as the magnetic refrigerants in most cooling devices, and for many cooling application the Nd2Fe14B permanent magnets are employed as the source of the magnetic field. The status of the near room temperature magnetic cooling was reviewed.
基金This research has been supported by research grants from the National Key R&D Program of China(No.2019YFD0902003-2)and Shanghai Municipal Education Commission-Gaoyuan Discipline of Food Science&Technology Grant Support(Shanghai Ocean University).
文摘Fish oils are important substances in the field of food and drug delivery.Due to their unstable double bonds,fishy taste,and poor water solubility,it is pivotal to investigate novel dosage forms for fish oils,such as encapsulated droplets.In this work,we primarily prepared gelatin-stabilized fish oil-loaded traditional emulsions and investigated their emulsion forms,droplets,and storage stability under different preparation and storage conditions.Our results showed that higher gelatin solution pH,higher storage temperature in the range of 4–37℃,and increased storage time induced the emulsion form switch from a liquid form to a redispersible gel form of the fish oil emulsion.The droplets had core-shell microstructures and a trimodal size distribution,which decreases linearly with increasing gelatin solution pH and homogenizing time,but decreases exponentially with increasing homogenizing speed.In addition,storage temperature showed a notably different effect on traditional emulsion storage.This work provides a fundamental knowledge for the formation,microstructure,and properties of gelatin-based traditional emulsions.It also provides a promising new application for fish oil-loaded emulsions in food beverages,soft candy,and other food products.
文摘Anion exchange membrane(AEM)fuel cells have gained great attention partially due to the advantage of using non-precious metal as catalysts.However,the reaction kinetics of hydrogen oxidation reaction(HOR)is two orders of magnitude slower in alkaline systems than in acid.To understand the slower kinetics of HOR in base,two major theories have been proposed,such as(1)pH dependent hydrogen binding energy as a major descriptor for HOR;and(2)bifunctional theory based on the contributions of both hydrogen and hydroxide adsorption for HOR in alkaline electrolyte.Here,we discuss the possible HOR mechanisms in alkaline electrolytes with the corresponding change in their Tafel behavior.Apart from the traditional Tafel-Volmer and Heyrovsky-Volmer HOR mechanisms,the recently proposed hydroxide adsorption step is also discussed to illustrate the difference in HOR mechanisms in acid and base.We further summarize the representative works of alkaline HOR catalyst design(e.g.,precious metals,alloy,intermetallic materials,Ni-based alloys,carbides,nitrides,etc.),and briefly describe their fundamental HOR reaction mechanism to emphasize the difference in elementary reaction steps in alkaline medium.The strategy of strengthening local interaction that facilitates both H2 desorption and Hads+OHads recombination is finally proposed for future HOR catalyst design in alkaline environment.
基金supported by the National Science Foundation under NSF Grant Number EEC-0813570the Iowa Energy Center under IEC Grant Number 13-01supported by the U.S. Department of Energy-Laboratory Royalty Revenue through Contract No. DE-AC02-07CH11358.
文摘The production of chemicals from lignocellulosic biomass provides opportunities to synthesize chemicals with new functionalities and grow a more sustainable chemical industry. However, new challenges emerge as research transitions from petrochemistry to biorenewable chemistry. Compared to petrochemisty, the selective conversion of biomass-derived carbohydrates requires most catalytic reactions to take place at low temperatures (< 300 °C) and in the condensed phase to prevent reactants and products from degrading. The stability of heterogeneous catalysts in liquid water above the normal boiling point represents one of the major challenges to overcome. Herein, we review some of the latest advances in the field with an emphasis on the role of carbon materials and carbon nanohybrids in addressing this challenge.
文摘Energy-proportional computing is one of the foremost constraints in the design of next generation exascale systems. These systems must have a very high FLOP-per-watt ratio to be sustainable, which requires tremendous improvements in power efficiency for modern computing systems. This paper focuses on the processor—as still the biggest contributor to the power usage—by considering both its core and uncore power subsystems. The uncore describes those processor functions that are not handled by the core, such as L3 cache and on-chip interconnect, and contributes significantly to the total system power. The uncore frequency scaling (UFS) capability has been available to the user since the Intel Haswell processor generation. In this paper, performance and power models are proposed to use both the UFS and dynamic voltage and frequency scaling (DVFS) to reduce the energy consumption in parallel applications. Then, these models are incorporated into a runtime strategy that performs processor frequency scaling during parallel application execution. The strategy can be implemented at the kernel/firmware level, which makes it suitable for improving the energy efficiency of exascale design. Experiments on a 20-core Haswell-EP machine using the quantum chemistry application GAMESS and NAS benchmark resulted in up to 24% energy savings with as little as 2% performance loss.
基金Supported by the National Natural Science Foundation of China(Nos.20773047 and 21043001)
文摘The properties of Pbn（n=2―30） clusters including binding energies,second differences in energy,and HOMO-LUMO gaps,especially fragmentation energies and ionization potentials,have been studied by ab initio calculation.The main fragmentation products of Pbn＋ are shown to be Pb＋Pbn-1＋ for n≤14 and two small cluster fragments for larger ones with n14.The Pb13＋ appears frequently as the products in the fragmentations of large clusters.Also,the calculated ionization potentials of the clusters are consistent with the experiment data.
文摘A new rare-earth magnet recycling process developed by researchers at the Critical Materials Institute (CMI) dissolves magnets in an acid-free solution and recovers high purity rare earth elements. For shredded magnet-containing electronic wastes, the process does not require pre-processing such as pre-sorting or demagnetization of the electronic waste.
基金supported by the Ministry of Education of the Republic of Koreathe National Research Foundation of Korea (grant NRF-2018S1A5A2A01031348 awarded to Y.B. Seong)
文摘The formation and evolution of glacier moraine-dammed lakes are closely related to past glacier expansion and retreat. Geomorphic markers such as lacustrine terraces and beach ridges observed in these lakes provide important evidence for regional paleoenvironment reconstruction. We document the magnitude of paleo-shoreline fluctuations and timings of highstands of lake water by using cosmogenic 10Be surface exposure dating and optically stimulated luminescence(OSL) dating on samples collected from lacustrine sediment and bedrock strath in Lake Khagiin Khar. The lake was initially impounded by glacier moraine at the Global Last Glacial maximum(gLGM;21–19 ka), and the lake reached its maximum paleo-shoreline level of 1840 m at sea level(a.s.l.). At that time, the stored lake water amount was up to seven times greater and the surface area was three times larger than the present values. The paleolake experienced higher shoreline levels at 1832, 1822, and 1817 m a.s.l. and reached the present lake level after 0.4 ka. We interpret that decrease in the paleolake level was caused by spillover. The increase in melt water after the gLGM and the Late Glacial exceeded the storage threshold of the lake, and the paleolake water overflowed across the lowest drainage divides. The lake spilled over across the lowest bedrock ridge at 15.9 ± 0.6 ka, and the outlet was incised since that time at a rate of 3.72 ± 0.15 mm/yr. The initial stream of the Khiidiin Pass River was disturbed by LGM moraine damming and was rerouted into the present course running through moraine after the spillover at 15.9 ± 0.6 ka.
基金Support of this work from the National Natural Science Foundation of China(Grant No.51361009)Work at Ames Laboratory was supported by the US Department of Energy,Basic Energy Sciences,Division of Materials Science and Engineering under Contract No.DE-AC02-07CH11358,including a grant of computer time at the National Energy Research Scientific Computing Centre(NERSC)in Berkeley,CA.
文摘Understanding of metal oxidation is very critical to corrosion control,catalysis synthesis,and advanced materials engineering.Metal oxidation is a very complex phenomenon,with many different processes which are coupled and involved from the onset of reaction.In this work,the initial stage of oxidation on titanium surface was investigated in atomic scale by molecular dynamics(MD)simulations using a reactive force field(ReaxFF).We show that oxygen transport is the dominant process during the initial oxidation.Our simulation also demonstrate that a compressive stress was generated in the oxide layer which blocked the oxygen transport perpendicular to the Titanium(0001)surface and further prevented oxidation in the deeper layers.The mechanism of initial oxidation observed in this work can be also applicable to other self-limiting oxidation.
基金supported by Korea Polar Research Institute(PE22090)。
文摘The Transantarctic Mountains are an important corridor between the East Antarctic Ice Sheet and the Western Ross Sea,where most current ice streams and outlet glaciers arise.We investigated Ricker Hills,the largest exposed mountainous region between Southern Victoria Land and Terra Nova Bay,and dated the glacial landforms using in-situ cosmogenic-nuclide 10 Be surface exposure dating to reconstruct the paleo-glacial dynamics.The surface of the Hollingsworth glacier lowered since the middle of Marine Isotope Stage(MIS)2(22.1 ka);therefore,the Last Glacial Maximum(LGM)occurred before that period.Cosmogenic,geomorphic,and climatic records constrained the glacial surface slope to be between 5.4°and 6.8°.The ice was 270-320 m thicker at the LGM(MIS 2)than presently but did not override the top surface of the Benson Knob.Moreover,previous glacial periods such as the local LGM(MIS 4)or Penultimate Glacial Maximum(MIS 6)maintained thicker ice than the LGM(MIS 2).The Ross Ice Shelf opening during the mid-Holocene(~6 ka)caused the rapid collapse of the terminal outlet glaciers and supplied notable snow accumulation upstream,which stagnated lowering.The greatest lowering and retreat occurred during the late Holocene(2.3~0.8 ka),when elephant seal colonies thrived in the Ross Embayment.
基金The project is supported by National Natural Science Foundation of China
文摘It was found for the first time that the compounds with only one functional group, such as pyridine, can show the promotion effect for the electrochemical reaction of cytochrome C at gold electrodes.
文摘Energy efficiency and energy-proportional computing have become a central focus in modern supercomputers. These supercomputers should provide high throughput per unit of power to be sustainable in terms of operating cost and failure rates. In this paper, a power-bounded strategy is proposed that maximizes parallel application performance under a given power constraint. The strategy dynamically allocates power to core, uncore, and memory power domains within a node to maximize performance under a given power budget. Experiments on a 20-core Haswell-EP platform for a real-world parallel application GAMESS demonstrate that the proposed strategy delivers performance within 4% of the best possible performance for as much as 25% reduction in the minimum power budget required for maximum performance.
基金Project operatedfor U.S .Department of Energy byIowa State University ( W-7405-ENG-82) and supported by Office of BasicEnergy Sciences
文摘The world has become highly dependent on reliable refrigeration technology. Without it, our food supply would be still seasonal and limited to locally produced nonperishable items; comfortable living conditions via climate control would be impossible; and certain medical advancements, e.g. MRI diagnostics, organ transplantation, organ and tissue cryo-storage, and cryo-surgery would be impossible. This technology remains essentially unchanged since it was invented 100 years ago.
