The present paper aims to investigate the influence of the current density in the electroplating process on the microstructure, crystal texture transformations, and corrosion behavior of Ni/Co pumice multilayer nanoco...The present paper aims to investigate the influence of the current density in the electroplating process on the microstructure, crystal texture transformations, and corrosion behavior of Ni/Co pumice multilayer nanocomposite coatings. The Ni/Co pumice composite coatings were prepared by deposition of Ni, followed by the simultaneous deposition of pumice nanoparticles (NPs) in a Co matrix via an electroplating process at various current densities. Afterward, the morphology, size, topography, and crystal texture of the obtained samples were investigated. Furthermore, electrochemical methods were used to investigate the corrosion behavior of the produced coatings in a solution of 3.5wt% NaCl. The results indicated that increasing the plating current density changed the mechanism of coating growth from the cell state to the column state, in- creased the coating thickness, roughness, and texture coefficient (TC) of the Co (203) plane, and reduced the amount of pumice NPs incorporated into the Ni/Co pumice composite. The electrochemical results also indicated that increasing the current density enhanced the corrosion resistance of the Ni/Co pumice composite.展开更多
ZnS/graphene nanocomposites with different graphene concentrations (5, 10 and 15 wt.%) were synthesized using L-cysteine as surfactant and graphene oxide (GO) powders as graphene source. Excellent performance for ...ZnS/graphene nanocomposites with different graphene concentrations (5, 10 and 15 wt.%) were synthesized using L-cysteine as surfactant and graphene oxide (GO) powders as graphene source. Excellent performance for nanocomposites to remove methylene blue (MB) dye and hexavalent chromium (Cr(VI)) under visible-light illumina- tion was revealed. TEM images showed that ZnS NPs were decorated on GO sheets and the GO caused a significant decrease in the ZnS diameter size. XRD patterns, XPS and FTIR spectroscopy results indicated that GO sheets changed into reduced graphene oxide (rGO) during the synthesis process. Photocurrent measurements under a visible- light source indicated a good chemical reaction between ZnS NPs and rGO sheets.展开更多
文摘The present paper aims to investigate the influence of the current density in the electroplating process on the microstructure, crystal texture transformations, and corrosion behavior of Ni/Co pumice multilayer nanocomposite coatings. The Ni/Co pumice composite coatings were prepared by deposition of Ni, followed by the simultaneous deposition of pumice nanoparticles (NPs) in a Co matrix via an electroplating process at various current densities. Afterward, the morphology, size, topography, and crystal texture of the obtained samples were investigated. Furthermore, electrochemical methods were used to investigate the corrosion behavior of the produced coatings in a solution of 3.5wt% NaCl. The results indicated that increasing the plating current density changed the mechanism of coating growth from the cell state to the column state, in- creased the coating thickness, roughness, and texture coefficient (TC) of the Co (203) plane, and reduced the amount of pumice NPs incorporated into the Ni/Co pumice composite. The electrochemical results also indicated that increasing the current density enhanced the corrosion resistance of the Ni/Co pumice composite.
文摘ZnS/graphene nanocomposites with different graphene concentrations (5, 10 and 15 wt.%) were synthesized using L-cysteine as surfactant and graphene oxide (GO) powders as graphene source. Excellent performance for nanocomposites to remove methylene blue (MB) dye and hexavalent chromium (Cr(VI)) under visible-light illumina- tion was revealed. TEM images showed that ZnS NPs were decorated on GO sheets and the GO caused a significant decrease in the ZnS diameter size. XRD patterns, XPS and FTIR spectroscopy results indicated that GO sheets changed into reduced graphene oxide (rGO) during the synthesis process. Photocurrent measurements under a visible- light source indicated a good chemical reaction between ZnS NPs and rGO sheets.