Flow pattern identification in oil wells by electromagnetic image logging

Petroleum production logging needs to determine the interpretation models first and flow pattern identification is the foundation, but traditional flow pattern identification methods have some limitations. In this paper, a new method of flow pattern identification in oil wells by electromagnetic image logging is proposed. First, the characteristics of gas-water and oil-water flow patterns in horizontal and vertical wellbores are picked up. Then, the continuous variation of the two phase flow pattern in the vertical and horizontal pipe space is discretized into continuous fluid distribution models in the pipeline section. Second, the electromagnetic flow image measurement responses of all the eight fluid distribution models are simulated and the characteristic vector of each response is analyzed in order to distinguish the fluid distribution models. Third, the time domain changes of the fluid distribution models in the pipeline section are used to identify the flow pattern. Finally, flow simulation experiments using electromagnetic flow image logging are operated and the experimental and simulated data are compared. The results show that the method can be used for flow pattern identification of actual electromagnetic image logging data.

Progress in the application of cold gas dynamic spraying to repairing continuous casting molds

A new continuous casting mold repairing method--cold gas dynamic spraying （CGDS） is introduced. The study investigates the advantages of the CGDS process regarding repairing operation, such as convenient, in-situ repairation,little heat delivery, microstructural and dimensional stability and other special applications. Microstructure and mechanical properties of the copper alloy coating, nickel coating, ceramic composite coating, and their interface to the substrates ,which are usually used in repairing operation have been researched by means of optical microscopy （ OM）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and micro-hardness tests. Experimental results have demonstrated the relative density of the copper alloy coating is as high as 98.7%, and that no obvious difference can be observed between the CrZrCu substrate and the Cu alloy coating in terms of microstructures; thus the interface is quite difficult to be identified. The bonding strength and micro-hardness of the Cu alloy coating reach up to 37 MPa and 310 HV0.2 ,respectively. The interface between the copper alloy coating and the nickel coating is either zigzag or wave shaped, and the cohesion is relatively good. As-sprayed nickel coating is dominated by severely deformed particles,and the relative density is up to 98.5%. Complete recrystallization occurred after annealing at 900℃ for one hour,while its micro-hardness remains as high as 124.1 HV02. All these results have indicated that CGDS is a promising technology for repairing the continuous casting mold and that its future development is prosperous as well.

The effect of annealing treatment on the microstructures and mechanical properties of cold-sprayed nickel coating

The effect of annealing treatment on the microstructures and mechanical properties of cold-sprayed Ni coating was investigated by conducting micro-hardness and tensile tests and using a normal optical microscope （OM） ,a scanning electron microscope （ SEM）, a transmission electron microscope （TEM） and an electron probe X-ray microanalyzer （EPMA）. The results show that following the increase of the annealing temperature ,the micro-hardness of cold-sprayed Ni coating decreases and the elongation after fracture increases, while the tensile strength increases before decreasing. The tensile deformation and fracture behavior change from a typical brittle fracture to a hybrid brittle and ductile fracture, then to a typical ductile failure. It is found that when annealed at an elevated temperature （ e. g. 900℃ ） ,the grains tend to grow abnormally with the oxides spheroidizing and the defects agglomerating at the interfaces, causing the tensile strength reduction of the cold-sprayed nickel coating. It is also pointed out that the tensile strength of the cold-sprayed Ni coating can be significantly improved by the appropriate annealing procedures, but the elongation after fracture cannot be clearly increased because it is difficult to eliminate the main defects in the coating by the following heat treatments.

Numerical simulation of the effects of the impact velocity on the particle deposition characteristics in cold gas dynamic spraying

In this study, the effects of the impact velocity on the particle deposition characteristics in cold gas dynamic spraying （CGDS） of 304 stainless steel （SS） on an interstitial free （IF） steel substrate are numerical simulated by means of a finite element analysis （FEA）. The results have illustrated that when the particle impact velocity exceeds a critical value at which adiabatic shear instability of the particle starts to occur. Meanwhile, the fatten ratio and impact crater depth （or the effective contacting area ） increase rapidly. The particle-substrate bonding and deposition mechanism can be attributed to such an adiabatic shear deformation induced by both the compressive force and the slide friction force of particle. The critical velocity can be predicted by numerical simulation, which is useful to optimize the CGDS processing parameters for various materials.

Experimental and mathematical modeling of metal spray forming process

The metal spray forming process was examined using mathematical simulation and verified through the prototyping evaluation at Baosteel＇ s test and development facilities. The mathematical model comprised of four sections, including jet gas flow in the deposition chamber;single droplet behavior along its trajectory path;probability and statistical analysis of droplet mass behavior, and forecast of the shape and temperature distribution of the billet during the spray forming process.

Microstructure and forming characteristics of spray-formed M42 high speed steel

M42 high speed steel （HSS）, a high grade alloy, was produced using the spray forming technology. Optical metallography （OM）,X-ray diffraction （XRD） and scanning electron microscope （SEM） were used to investigate the microstructures of the as-sprayed M42 HSS and the as-atomized powders. It is found that as-sprayed M42 HSS is composed of martensite, retained austenite and carbides. The grain size, as well as the morphology, size and distribution of the carbides have been greatly improved compared with those of the as-cast M42 steel （ a traditional process）. The size of the powder obtained at a high cold speed was ranged from 50 μm to 100μm in diameter. Its representative microstructures include dendrite, dendritic fragments, a mixture of dendrites, equiaxed grains and dendritic fragments,and equiaxed grains. The rapid solidification in the spray forming is a key factor to cause the refinement of the M42 HSS.

Mesoporous cadmium bismuth niobate(CdBi2Nb2O9)nanospheres for hydrogen generation under visible light

Herein, we report visible light active mesoporous cadmium bismuth niobate（CBN） nanospheres as a photocatalyst for hydrogen（H） generation from copious hydrogen sulfide（HS）. CBN has been synthesized by solid state reaction（SSR） and also using combustion method（CM） at relatively lower temperatures.The as-synthesized materials were characterized using different techniques. X-ray diffraction analysis shows the formation of single phase orthorhombic CBN. Field emission scanning electron microscopy and high resolution-transmission electron microscopy showed the particle size in the range of.5–1 μm for CBN obtained by SSR and 50–70 nm size nanospheres using CM, respectively. Interestingly, nanospheres of size 50–70 nm self assembled with 5–7 nm nanoparticles were observed in case of CBN prepared by CM.The optical properties were studied using UV–visible diffuse reflectance spectroscopy and showed band gap around.0 eV for SSR and 3.1 eV for CM. The slight shift in band gap of CM is due to nanocrystalline nature of material. Considering the band gap in visible region, the photocatalytic activity of CBN for hydrogen production from HS has been performed under visible light. CBN prepared by CM has shown utmost hydrogen evolution i.e. 6912 μmol/h/0.5 g which is much higher than CBN prepared using SSR.The enhanced photocatalytic property can be attributed to the smaller particle size, crystalline nature,high surface area and mesoporous structure of CBN prepared by combustion method. The catalyst was found to be stable, active and can be utilized for water splitting.

Research on directly cold-rolled AISI 304 stainless steel strip with the twin-roll strip casting process

In order to improve the surface quality and properties of AISI 304 stainless steel strip produced with the twinroll strip casting process,the strip was directly cold-rolled. The results show that cold rolling clearly improves the surface roughness,microstructure and properties. Residual δ ferrite is greatly decreased, anisotropy becomes less obvious and corrosion resistance is greatly improved. These results demonstrate the feasibility of directly cold-rolled AISI 304 stainless steel strip.

Preface

In the mid-1980s, scientist A. Papyrin and his colleagues from the Institute of Theoretical and Applied Mechanics, the Russian Academic of Science in Novosibirsk, discovered some metal particles on the tunnel wall ,when they conducted wind tunnel experiments. The adhesion was not simple mechanical riveting, but they contained metallurgical bonding to some degree, and the bonding strength was very high.

The development of China's special steel and the application prospects of spray-formed materials

Suggestions have been put forward speeding up the development of high-level tool steel and mold steel in China based on the analysis of products and development status of special steel home and abroad. Feasibility and necessity to produce high-level tool steel and mold steel by applying the spray forming method in future have been put forward.

Numerical simulation of tube profile growth during spray forming process

Spray forming is a new type of metal material forming process,which can produce metal blanks such as billet, tube,plate etc. A mathematical model has been developed to forecast the shape evolution of tube billets during the spray forming process. The atomizer mass flux as ,radial distribution coefficient bs, draw velocity and diameter of mandrel were considered in this model and the influence of different parameters such as metal flowrate, draw velocity of mandrel, diameter of mandrel on the tube＇ s shape change were simulated and analyzed in this paper. The simulation results obtained from this model can be provided to engineers as reference.

Microstructure and micro-hardness of the Inconel 718 superalloy coating prepared by cold gas dynamic spraying

Inconel 718 superalloy coating was prepared on a martensitic steel substrate by cold gas dynamic spraying （ CGDS ）. Microstructure and micro-hardness of the coating were characterized by means of scanning electronic microscope （SEM） ,energy dispersive spectrometer （EDS）, and micro-hardness and nano-indentation tests. The results have indicated that the coating＇ s thickness can reach more than 300 um, and there exists a good interfacial cohesion between the coating and the substrate. The quantity and size of the defects at the bottom, middle and top areas increase gradually. There is no significant change to the original microstructure of the Inconel 718 superalloy particle after the process of CGDS ;and an obvious torsional deformation on the particle＇ s profile is produced while little deformation at the center part occurs. The micro-hardness of the coating at the bottom, middle and top areas decreases in turn. Compared with the bottom area, the micro-hardness of the middle and top areas decreases by about 10% and 21%, respectively. The nano-hardness of the coating is much lower than the original particle,which decreases by about 13.5% at the bottom area and 28% at the top area,respectively. The distribution of micro-defects is an important factor to the micro-hardness of the coating.

The numerical simulation of the movements and thermal states of atomized metal droplets in the spray forming process

Numerical simulation was performed in an atomizing chamber to investigate the movements and thermal states of the atomized metal droplets in the spray forming process. The velocity, temperature and solid fractions of metal droplets with different diameters and under different atomizing pressures were investigated. The results indicate that a higher atomizing pressure results in the increased flying velocity of the metal droplets and a decrease in the cone-shaped angle formed by their flight paths. Synchronously, the cooling of the metal droplets is accelerated and the time of the complete solidification process is shortened. Under the same atomization pressure, large metal droplets have a lower flying speed and a lower rate of temperature decrease in the atomizing chamber than small metal droplets. In addition, metal droplets flying along the edge of the atomizing region cool faster than those flying in the core region.

The microstructural nanoindentation characteristics of different phases in precision annealed GCr15 steel

This study characterizes the mechanical properties and volume fractions of the different phases in precision annealed GCr15 steel using nanoindentation technology. Experimental results indicate that the nanoindentation hardness of cementite grains is between 14.15 GPa and 17.61 GPa,with a mean value of 15.40 GPa. This hardness is much higher than the hardness of ferrite grains. The nanoindentation hardness of ferrite is between 2.78 GPa and 4.89 GPa, with a mean value of 3.35 GPa. The volume fractions of the different phases were also determined using nanoindentation technology, and the volume fraction of cementite in the steel was identified as 15%.

Hydraulic simulation of the feeding system in the strip casting process

A 1：1 water model of a twin-roll strip caster was set up based on the Froude number（Fr） and Reynolds number （Re） similarity criteria. Fluctuation and the mixing effect in the molten pool of twin-roll strip casting process were analyzed through hydraulic simulation. The height of the fluctuation of the liquid pool surface and the residence time were measured by DJ800 multifunctional monitor under different process conditions. The results show that the casting velocity, the insertion depth and the pool level have a great effect on the fluctuation.

High temperature mechanical properties of low carbon silicon-bearing steel by twin-roll strip casting

The tensile equipment of the advanced confocal scanning laser microscope （CSLM） was used to research the high temperature mechanical properties of low carbon silicon-bearing steel by twin-roll strip casting. The results show that, at the strain rate of 0. 000 5 s ^-1, the strip clearly shows signs of brittleness at around 600 ℃ and its plasticity falls considerably between 750 ℃ and 600 ℃. This is because during the transformation from austenite to ferrite, the low strength ferrite at the austenite grain boundaries greatly reduces the steel＇ s high temperature plasticity. The subsequent strip coiling process should be controlled at less than the brittle temperature of approximately 600 ℃, so cracks at the coiling stage can be prevented.

Numerical simulation of particle tracks in the cold gas dynamic spraying process

In this study,the distribution behavior of the particle flow field in cold gas dynamic spraying （CGDS） was simulated through the Computational fluid dynamics （CFD） method. Traces of the particles with different diameters in the gas flow field were analyzed, and effects of fiat and sphere substrates on the particle tracks were also compared .Simulation results indicate that different escaping directions of particles flow with the two substrates. These investigations. gave instructions on how to design the powder recovery and dusting machines in a CGDS system.

Effects of standoff distance on the supersonic flow fields in cold gas dynamic spraying

In this study,the effects of standoff distance （SOD） on the supersonic flow fields （including gas and particle flow fields） during cold gas dynamic spraying （ CGDS ） are investigated by means of computational fluid dynamics （CFD）. The variation of velocity,temperature,pressure and density with different SoD is elucidated through the analysis of the distribution properties of the flow fields. It is found that the shock waves in front of the substrate remarkably influence the gas and particle flow fields. The wave system of expansion waves and pressure waves come into being continuously. The velocity of gas reaches the super.,;onic speed at the position of the Mach disc, while it decreases sharply when the gas flow crosses the Mach disc. The optirnal SoDs are 40 mm for 1 um particles and 50 mm for both 5 um and 22 um particles.

Numerical simulation of the liquid steel flow and solidification phenomena in the slab continuous casting process

A 3D coupling mathematical simulation program of the fluid flow, thermal transfer and solidification was developed based on the slab continuous casting process. Some characteristics such as fluid flow, solidification and temperature distribution near the submerged entry nozzle （SEN） and the corner of the mold were simulated and analyzed. The result of the calculation indicates that the flow of molten metal forms two big cycling zones in the mold after it flows out of the SEN, and the temperature at the center of the two zones is relatively low. Moreover, there is a small narrow cycling zone near the narrow side of the mold due to casting. The velocity of the surface flow, the turbulent kinetic energy and the F value might reveal the relationship between the fluctuation of meniscus and the quality of the slab to some degree.