Uniform nanoparticles of molybdenum nitride were synthesized by temperature-programmed reaction(TPR) using MoO3 and ammonia as reactants. This material was characterized by X-ray diffractometry(XRD), transmission elec...Uniform nanoparticles of molybdenum nitride were synthesized by temperature-programmed reaction(TPR) using MoO3 and ammonia as reactants. This material was characterized by X-ray diffractometry(XRD), transmission electron microscopy(TEM), scanning electron microcopy(SEM) and cyclic voltammetry(CV). Results show that the material consists of a pure phase of γ-Mo2N nanoparticles with average diameter of about 16 nm. The material presents a specific capacitance of 172 F/g in 1 mol/L H2SO4 electrolyte at a scan rate of 1 mV/s and the potential window is broadened to 1.1 V (-0.6 to 0.5 V). At the 6 000th cycle, the material remains 94.9% and 94.7% of the initial capacitance in 1 mol/L H2SO4 and KCl solution, respectively. A possible mechanism comprising surface control and diffusion control is proposed to explain the effect of scan rates on specific capacitance.展开更多
For the ever-growing demand of advanced lithium-ion batteries, it is highly desirable to grow self-supported micro-/nanostructured arrays on metal substrates as electrodes directly. The in-situ growth of electrode mat...For the ever-growing demand of advanced lithium-ion batteries, it is highly desirable to grow self-supported micro-/nanostructured arrays on metal substrates as electrodes directly. The in-situ growth of electrode materials on the conducting substrates greatly simplifies the electrode fabrication process without using any binders or conductive additives. Moreover, the well-ordered arrays closely connected to the current collectors can provide direct electron transport pathways and enhanced accommodation of strains arisen from lithium ion lithiation/delithiation. This article summarizes our recent work on design and construction of lithium-ion battery electrodes on metal substrates. An aqueous solution-based process and a microemulsion-mediated process have been respectively presented to control the kinetic and thermodynamic processes for the micro-/nanostructured array growth on metal substrates, with particular attention to CuO nanorod arrays and microcog arrays successfully prepared on Cu foil substrates. They can be directly used as binder-free electrodes to build advanced lithium-ion batteries with high energy, high safety and high stability.展开更多
Lithium-ion batteries (LIBs) are currently recognized as one of the most popular power sources available. To construct advanced LIBs exhibiting long-term endurance, great attention has been paid to enhancing their p...Lithium-ion batteries (LIBs) are currently recognized as one of the most popular power sources available. To construct advanced LIBs exhibiting long-term endurance, great attention has been paid to enhancing their poor cycle stabilities. As the performance of LIBs is dependent on the electrode materials employed, the most promising approach to improve their life span is the design of novel electrode materials. We herein describe the rational design of a three-dimensional (3D) porous MnO/C-N nanoarchitecture as an anode material for long cycle life LIBs based on their preparation from inexpensive, renewable, and abundant rapeseed pollen (R-pollen) via a facile immersion-annealing route. Remarkably, the as-prepared MnO/C-N with its optimized 3D nanostructure exhibited a high specific capacity (756.5 mAh·g^-1 at a rate of 100 mA·g^-1), long life span (specific discharge capacity of 513.0 mAh·g^-1, -95.16% of the initial reversible capacity, after 400 cycles at 300 mA·g^-1), and good rate capability. This material therefore represents a promising alternative candidate for the high-performance anode of next-generation LIBs.展开更多
基金Projects(08020203005, 07020203003) supported by the Annual Key Projects of Anhui Province, China
文摘Uniform nanoparticles of molybdenum nitride were synthesized by temperature-programmed reaction(TPR) using MoO3 and ammonia as reactants. This material was characterized by X-ray diffractometry(XRD), transmission electron microscopy(TEM), scanning electron microcopy(SEM) and cyclic voltammetry(CV). Results show that the material consists of a pure phase of γ-Mo2N nanoparticles with average diameter of about 16 nm. The material presents a specific capacitance of 172 F/g in 1 mol/L H2SO4 electrolyte at a scan rate of 1 mV/s and the potential window is broadened to 1.1 V (-0.6 to 0.5 V). At the 6 000th cycle, the material remains 94.9% and 94.7% of the initial capacitance in 1 mol/L H2SO4 and KCl solution, respectively. A possible mechanism comprising surface control and diffusion control is proposed to explain the effect of scan rates on specific capacitance.
基金Supported by the National Natural Science Foundation of China(NSFC Grants21176054 and 21271058)
文摘For the ever-growing demand of advanced lithium-ion batteries, it is highly desirable to grow self-supported micro-/nanostructured arrays on metal substrates as electrodes directly. The in-situ growth of electrode materials on the conducting substrates greatly simplifies the electrode fabrication process without using any binders or conductive additives. Moreover, the well-ordered arrays closely connected to the current collectors can provide direct electron transport pathways and enhanced accommodation of strains arisen from lithium ion lithiation/delithiation. This article summarizes our recent work on design and construction of lithium-ion battery electrodes on metal substrates. An aqueous solution-based process and a microemulsion-mediated process have been respectively presented to control the kinetic and thermodynamic processes for the micro-/nanostructured array growth on metal substrates, with particular attention to CuO nanorod arrays and microcog arrays successfully prepared on Cu foil substrates. They can be directly used as binder-free electrodes to build advanced lithium-ion batteries with high energy, high safety and high stability.
基金Acknowledgements This work is supported by the National Natural Science Foundation of China (Nos. 21431006 and 21503207), the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (No. 21521001), the National Basic Research Program of China (Nos. 2014CB931800, 2013CB933900), and Scientific Research Grant of Hefei Science Center of Chinese Academy of Sciences (Nos. 2015HSC-UE007 and 2015SRG-HSC038), the China Postdoctoral Science Foundation (Nos. 2015T80662 and 2014M550346), and the Fundamental Research Funds for the Central Universities (No. WK2060190047). The authors also thank the help provided by Dr. Yue Lin and Prof. Yan-Wei Ding in Instruments' Center for Physical Science at the University of Science and Technology of China.
文摘Lithium-ion batteries (LIBs) are currently recognized as one of the most popular power sources available. To construct advanced LIBs exhibiting long-term endurance, great attention has been paid to enhancing their poor cycle stabilities. As the performance of LIBs is dependent on the electrode materials employed, the most promising approach to improve their life span is the design of novel electrode materials. We herein describe the rational design of a three-dimensional (3D) porous MnO/C-N nanoarchitecture as an anode material for long cycle life LIBs based on their preparation from inexpensive, renewable, and abundant rapeseed pollen (R-pollen) via a facile immersion-annealing route. Remarkably, the as-prepared MnO/C-N with its optimized 3D nanostructure exhibited a high specific capacity (756.5 mAh·g^-1 at a rate of 100 mA·g^-1), long life span (specific discharge capacity of 513.0 mAh·g^-1, -95.16% of the initial reversible capacity, after 400 cycles at 300 mA·g^-1), and good rate capability. This material therefore represents a promising alternative candidate for the high-performance anode of next-generation LIBs.