Spatial distribution of organic carbon in soils is difficult to estimatebecause of inherent spatial variability and insufficient data. A soil-landscape model for a region,based on 151 samples for parent material and t...Spatial distribution of organic carbon in soils is difficult to estimatebecause of inherent spatial variability and insufficient data. A soil-landscape model for a region,based on 151 samples for parent material and topographic factors, was established using a GISspatial analysis technique and a digital elevation model (DEM) to reveal spatial distributioncharacteristics of soil organic carbon (SOC). Correlations between organic carbon and topographicfactors were analyzed and a regression model was established to predict SOC content. Results forsurface soils (0-20 cm) showed that the average SOC content was 12.8 g kg^(-1), with the SOC contentbetween 6 and 12 g kg^(-1) occupying the largest area and SOC over 24 g kg^(-1) the smallest. Also,soils derived from phyllite were the highest in the SOC content and area, while soils developed onpurple shale the lowest. Although parent material, elevation, and slope exposure were allsignificant topographic variables (P < 0.01), slope exposure had the highest correlation to SOCcontent (r = 0.66). Using a multiple regression model (R^2 = 0.611) and DEM (with a 30 m X 30 mgrid), spatial distribution of SOC could be forecasted.展开更多
The diversity of soils derived from different parent materials and developed on different terrains inShandong Province, China, was analyzed with the theory of pedodiversity using a 1:1000000 scale soilsand terrain dig...The diversity of soils derived from different parent materials and developed on different terrains inShandong Province, China, was analyzed with the theory of pedodiversity using a 1:1000000 scale soilsand terrain digital database (SOTER) of Shandong Province in a geographical information system (GIS)environment. Diversity index of soils derived from different parent materials followed the sequence of igneousrock > sedimentary rock > metamorphic rock > unconsolidated material. Diversity index of soils developedon different terrains followed the sequence of plain > medium-gradient mountain > medium-gradient hill> valley floor > medium-gradient escarpment zone > depression > high-gradient mountain. Abundancedistributions of these soil groups matched the logarithmic normal distributions.展开更多
By interpreting the remote sensing data of aerial photos and satellite images in different time, combining with field investigation, landform and water level observation, collecting data of weather, hydrology in Chaoh...By interpreting the remote sensing data of aerial photos and satellite images in different time, combining with field investigation, landform and water level observation, collecting data of weather, hydrology in Chaohu Lake, Anhui Province from 1957 to 2003, the reasons for collapse of Chaohu lakeshore were analyzed. The results are as follows: 1) The collapse of the Chaohu lakeshore is controlled macroscopically by two sets of north-east and the north-west faults, and the degree of collapse is determined microcosmically by lithology. 2) The constant change of water level, resulting from precipitation, wind speed and its direction, is one of the main reasons for intermittence collapse. 3) The soil and water loss or mud and sand filling up, resulting from artificial factors, such as inconsequence control of Chaohu sluice or irrational agricultural and industrial activities, etc., can uplift the lake′s bed and drive water level up. The high water level also results in the collapse. Judging from the above mentioned reasons for the collapse, we have proposed some countermeasures: 1) Putting the lakeshore slope protection project such as stone and cement mortar into practice, and upstream slope should be 1∶2.5 or 1∶3, some parts of them should be 1∶4, if they were not stable. The back slope, which is from Gui Mountain to Zhongmiao Temple, should be 1∶1.5-1∶3. 2) Constructing a greenbelt for the lakeshore, planting some vegetation such as osier, bulrush and poplar, to resist waves between the high and the low water level. 3) Controlling Chaohu Lake water level scientifically. Corrosion of lakeshore that contains gravel clay and ferruginous-manganese concretionary structures, can decrease at low water level. 4) Renovating Chaohu Lake drainage area, strengthening the administration and supervision, breaking regionalism and establishing special administration organization.展开更多
Tourism development surely has social, economic and environmental impacts on tourist destinations.The study on resorts residents' attitudes can help understand the nature of tourism development and the extent to w...Tourism development surely has social, economic and environmental impacts on tourist destinations.The study on resorts residents' attitudes can help understand the nature of tourism development and the extent to which it may influence on tourist destinations. By now, researches on residents' perception and attitudes are plenteous in the international circle and achievements are great, yet few are found in developing countries. As a most representative cultural tourist destination, World Cultural Heritage-Xidi and Hong villages in Yi County of Anhui Province, are drawing the attention of both tourists and academic circles. This article, taking Xidi and Hong villages as examples, seeks to analyze ancient village residents' attitudes towards tourism impacts and then tries further to explore the connection between tourism development and residents' attitudes. Both qualitative and quantitative surveys are applied in the exploratory investigation into local residents' attitudes of tourism impacts. Based on abundant face-to-face interviews with the local households, tourism enterprises concerned, local government and tourists from July to August of 2002, we are able to have a better understanding of local residents' attitudes to community life, and perception of tourism impacts on society, economy and environment. By this we can promote domestic study on resorts residents' attitudes, and provide some theoretical grounds for establishing tourism development planning and perfect community participation system at tourist destinations.展开更多
Radar remote sensing can acquire information of sub-surface covered by sand in arid area, detect surface roughness and vegetation coronet's layer and linear feature such as linear structure and channel sensitively...Radar remote sensing can acquire information of sub-surface covered by sand in arid area, detect surface roughness and vegetation coronet's layer and linear feature such as linear structure and channel sensitively. With sediment facies analysis, this paper studies the features of environmental evolution in mid-late Epipleistocene (60 ka BP-20 ka BP) in northeastern Ejin Banner. The conclusions are listed as follows: (1) The evolution of the three lakes, i.e. Gaxunnur, Sugunur and Tian'e lakes, are dominated by faults and regional climate. (2) By analyzing sedimentary section of old Juyanze Lake, the three lakes used to be a large outflow lake before 50 ka BP in northeastern Ejin Banner, and at 50 ka BP, temperature declined rapidly in northwestern China. The event caused the lake's shrinkage. (3) By fault activity uplift in the northern part of old Juyan Lake and depression in the southern part, the lake's water followed from north to south at around 35 ka BP, old Juyanze fluvial fan was formed. At the same time, Juyan Lake separated from Sugunur Lake and Wentugunr old channel was abandoned. (4) In recent 2000 years, Ruoshui River is a wandering river, sometimes it flows into Juyan Lake and sometimes Sugunur and Gaxunnur lakes. Due to human activities and over exploitation, the oasis ecosystem is rapidly degenerated in 15 years (1986-2000).展开更多
The surface of nano-TiO_2 was encapsulated with hydroxyl-propyl-methyl cellulose(HPMC),and then cograftedwith acrylates.Conditions of absorbing and grafting have been studied.Modified nano-TiO_2 particles were charact...The surface of nano-TiO_2 was encapsulated with hydroxyl-propyl-methyl cellulose(HPMC),and then cograftedwith acrylates.Conditions of absorbing and grafting have been studied.Modified nano-TiO_2 particles were characterized byFT-IR spectra,TEM and TG analysis.It was convinced from FT-IR studies that both methyl methacrylate(MMA)and butyl-methacrylate(BMA)were co-grafted onto the surface of nano-TiO_2 particles.TEM images show that the surface of nano-TiO_2 particles was successfully modified by a thick layer of film-like polymer.TG results demonstrate that the decompositiontemperature of HPMC-g-PMMA/PBMA,which has been grafted onto the surface of nano-TiO_2,is 56.9 K higher than that ofHPMC-g-PMMA/PBMA.展开更多
Considering the interaction between excited triplet molecule and doublet radical, based on the second-order perturbation theory and the motion equation of density matrix, the polarization intensity of RTPM were theore...Considering the interaction between excited triplet molecule and doublet radical, based on the second-order perturbation theory and the motion equation of density matrix, the polarization intensity of RTPM were theoretically calculated with the overpopulated doublet spin states and quartet spin states of radical-triplet pairs as initial conditions respectively. The results of calculation indicate that the net emissive polarization and the net absorptive polarization on the radical result from the zero-field-splitting (zfs) and the multiplet A/E and E/A polarization result from hyperfine (hf) interactions of the triplet molecule. The hyperfine related A+A/E or E+E/A CIDEP on the radical were the overpopulation of the net absorptive or emissive polarization and multiplet A/E or E/A polarization..展开更多
From the Gibbs free energy and the equations of two-phase equilibrium curves of the two-dimensionalbinary system which has the Lennard-Jones potential, using the Collins model, the eutectic-type phase diagram and thep...From the Gibbs free energy and the equations of two-phase equilibrium curves of the two-dimensionalbinary system which has the Lennard-Jones potential, using the Collins model, the eutectic-type phase diagram and theperitectic-type phase diagram of the binary system are obtained, whose results are quite similar to the behavior of thethree-dimensional (3D) substances.展开更多
Via layer-by-layer assembly, the polyoxometalates of Keggin type, SiW_ 11O_ 39Ni(H_2O) 6-(SiNiW_ 11) and {SiW_ 11O_ 39Mn(H_2O) 6-}(SiMnW_ 11) were first immobilized on a 4-aminothiophenol(4-ATP) modified glassy carbon...Via layer-by-layer assembly, the polyoxometalates of Keggin type, SiW_ 11O_ 39Ni(H_2O) 6-(SiNiW_ 11) and {SiW_ 11O_ 39Mn(H_2O) 6-}(SiMnW_ 11) were first immobilized on a 4-aminothiophenol(4-ATP) modified glassy carbon electrode surface. The electrochemical behavior of these polyoxometalates was investigated. They exhibited some special properties in the films, which are different from those in a homogeneous aqueous solution. Their reaction mechanism in a multilayer film is proposed. The electrocatalytic behavior of these multilayer film electrodes for the reduction of BrO-_3 and NO-_2 were comparatively studied.展开更多
Functionalized nano-PbS has been prepared and characterized. The functionalized nanoparticles have good dispersibility in water. Reaction of functionalized nanoPbS with gglobulin (gIgG) results an enhanced resonance...Functionalized nano-PbS has been prepared and characterized. The functionalized nanoparticles have good dispersibility in water. Reaction of functionalized nanoPbS with gglobulin (gIgG) results an enhanced resonance light scattering (RLS) around 385 nm. However, when the content of HSA is lower than 0.5 mg ml-1 the RLS enhancement is very weak and is nonlinear to concentration of HSA. Based on these results, a new direct quantitative determination method for gglobulin in blood serum samples without separation is established. Under optimal conditions, the enhanced RLS intensity is in proportion to the gIgG concentration in the range 10500 ng/mL. The limit of detection is 2.75 ng/mL. This method is proved to be very sensitive, rapid, simple and selective for detection of gIgG in blood serum.展开更多
A class of quasilinear singularly perturbed problems with boundary perturbation is considered. Under suitable conditions, using theory of differential inequalities we studied the asymptotic behavior of the solution fo...A class of quasilinear singularly perturbed problems with boundary perturbation is considered. Under suitable conditions, using theory of differential inequalities we studied the asymptotic behavior of the solution for the boundary value problem.展开更多
The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodyn...The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.展开更多
We present a quantum measurement model where the meter is taken to be a squeezed reservoir. life realize decoherence in macroscopic limits using Bogoliubov transformation, and this kind of system-meter coupling has a ...We present a quantum measurement model where the meter is taken to be a squeezed reservoir. life realize decoherence in macroscopic limits using Bogoliubov transformation, and this kind of system-meter coupling has a dramatic influence on decoherence.展开更多
The Lennard-Jones potential is introduced into the Collins model and is generalized to the two-dimensionalalternative binary system. The Gibbs free energy of the binary system is calculated. According to the thermodyn...The Lennard-Jones potential is introduced into the Collins model and is generalized to the two-dimensionalalternative binary system. The Gibbs free energy of the binary system is calculated. According to the thermodynamicconditions of solid-liquid equilibrium, the "cigar-type" phase diagram and the phase diagram with a minimum areobtained. The results are quite analogous to the behavior of three-dimensional substances.展开更多
Taking South Lake and Jingyue Pool in Changchun as examples, we determined particulate Hg in ambient air and Hg concentration in precipitation. Results indicated that particulate Hg in air and Hg concentration in prec...Taking South Lake and Jingyue Pool in Changchun as examples, we determined particulate Hg in ambient air and Hg concentration in precipitation. Results indicated that particulate Hg in air and Hg concentration in precipitation in both sites in nonheating period were lower than that in heating period, which is influenced by coal combustion. The annual particulate Hg concentrations of South Lake and Jingyue Pool were 0.254ng/m3 and 0.109ng/m3. The yearly average Hg concentrations in precipitation were 0.268μg/L(South Lake) and 0.108μg/L(Jingyue Pool). The higher particulate Hg concentration in air and Hg concentration in precipitation in South Lake than that of Jingyue Pool indicated that mercury deposition was influenced by anthropogenic sources(especially from coas combustion). Hg concentration in precipitation is related with particulate Hg in the atmosphere. Dry deposition fluxes were estimated by using dry deposition model on the base of particulate Hg concentrations in the atmosphere, they were 35.5μg/(m2.a) for South lake and 15.3μg/(m2.a) for Jingyue Pool. Combined with precipitation amount, wet deposition fluxes were estimated in these two sites, 152.2μg/(m2.a) for South Lake and 61.2μg/(m2.a) for Jingyue Pool. Atmospheric Hg deposition fluxes were 160.2g/a for South Lake and 328.62g/a for Jingyue Pool.展开更多
The locally rotationally symmetric Bianchi-type II string cosmological models with bulk viscosity are obtained, where an equation of state, , and a relation between metric potentials, , are adopted. The physical featu...The locally rotationally symmetric Bianchi-type II string cosmological models with bulk viscosity are obtained, where an equation of state, , and a relation between metric potentials, , are adopted. The physical features of the models are also discussed. In special cases the model reduces to the string models without viscosity that was previously given in the literatures.展开更多
The study on sediment production and its relationship with climatic and hydrological factors in watershed is a major environment issue of concern in the international community. Based on the observational records cove...The study on sediment production and its relationship with climatic and hydrological factors in watershed is a major environment issue of concern in the international community. Based on the observational records covering the period from 1954 to 1999, the characteristics of precipitation changing over the Dasha River Watershed in Anhui Province and its relation to sediment yield were studied using tendency analysis and correlation analysis.Results showed that the precipitation of the Dasha River Watershed has high variability. In those 46 years, 34% of spring rainfall, 58% of summer rainfall and 30% of annual rainfall will be considered anomaly. The gray correlation analysis shows that sediment discharge correlates most closely with the frequency of the rainstorm with a daily precipitation above 100mm, secondly with the frequency of the rainstorm with a daily precipitation of 50-100mm, and thirdly with the number of rainy days. Their correlation coefficients are 0.98,0.90 and 0.85 respectively. In addition,the paper suggests the major countermeasures and methods for controlling of soil and water losses in this area.展开更多
Based on the questionnaire investigation, the authors make a comparative study on local residents′ perception of tourism impacts in Xidi, Zhouzhuang and Jiuhua Mountain. The result shows that residents of the three p...Based on the questionnaire investigation, the authors make a comparative study on local residents′ perception of tourism impacts in Xidi, Zhouzhuang and Jiuhua Mountain. The result shows that residents of the three places tend to have strong and consistent perception of its positive economic, socio-cultural and environmental impacts, but distinctly diverse ones of its negative impacts. Residents in Xidi and Zhouzhuang also have noticeable perception of its negative environmental impacts while those in Jiuhua Mountain have weaker perception of them. The research confirms the fact that residents are more liable to have positive perceptions at the early stage of the life cycle of the tourist places. The authors conclude that there exists a nonlinear relationship between residents′ perception and tourism development stages, and that tourism socio-cultural impact may appear at an early stage of tourism development instead of being no universal.展开更多
The title compound (C10H11BrO4, Mr = 275.10) was synthesized and its crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n with a = 7.2960(8), b = 1...The title compound (C10H11BrO4, Mr = 275.10) was synthesized and its crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n with a = 7.2960(8), b = 12.209(1), c = 12.568(1) ? b = 98.120(2)? l = 0.71073 ? m(MoKa) = 3.700 mm-1, V = 1108.3(2) 3, Z = 4, Dc = 1.649 g/cm3 and F(000) = 552. The structure was solved by direct methods and refined by full-matrix least-squares methods. R = 0.0375 and wR = 0.0864 for 1598 reflections with I > 2s(I). X-ray diffraction reveals that there exist two rings in the molecule, and the dihedral between them is 177.5?展开更多
基金Project supported by the National Key Basic Research Support Foundation of China (No. G1999011810) the Key Innovation Project of Chinese Academy of Sciences (No. KZCX1-SW01-19) the Frontier Project of the Chinese Academy of Sciences (No. ISSASIP0201
文摘Spatial distribution of organic carbon in soils is difficult to estimatebecause of inherent spatial variability and insufficient data. A soil-landscape model for a region,based on 151 samples for parent material and topographic factors, was established using a GISspatial analysis technique and a digital elevation model (DEM) to reveal spatial distributioncharacteristics of soil organic carbon (SOC). Correlations between organic carbon and topographicfactors were analyzed and a regression model was established to predict SOC content. Results forsurface soils (0-20 cm) showed that the average SOC content was 12.8 g kg^(-1), with the SOC contentbetween 6 and 12 g kg^(-1) occupying the largest area and SOC over 24 g kg^(-1) the smallest. Also,soils derived from phyllite were the highest in the SOC content and area, while soils developed onpurple shale the lowest. Although parent material, elevation, and slope exposure were allsignificant topographic variables (P < 0.01), slope exposure had the highest correlation to SOCcontent (r = 0.66). Using a multiple regression model (R^2 = 0.611) and DEM (with a 30 m X 30 mgrid), spatial distribution of SOC could be forecasted.
基金Project supported by the National Natural Science Foundation of China(No.40171044).
文摘The diversity of soils derived from different parent materials and developed on different terrains inShandong Province, China, was analyzed with the theory of pedodiversity using a 1:1000000 scale soilsand terrain digital database (SOTER) of Shandong Province in a geographical information system (GIS)environment. Diversity index of soils derived from different parent materials followed the sequence of igneousrock > sedimentary rock > metamorphic rock > unconsolidated material. Diversity index of soils developedon different terrains followed the sequence of plain > medium-gradient mountain > medium-gradient hill> valley floor > medium-gradient escarpment zone > depression > high-gradient mountain. Abundancedistributions of these soil groups matched the logarithmic normal distributions.
基金Under the auspices of Sciences Fund of Anhui Provincial Bureau of Education (No. 2004kj165 zd), High Edu-cation Teaching Research of Anhui Province (No. 2005021), the Natural Sciences Fund of Anhui Province, Key Subject of Physi-cal Geographyof Anhui Normal University
文摘By interpreting the remote sensing data of aerial photos and satellite images in different time, combining with field investigation, landform and water level observation, collecting data of weather, hydrology in Chaohu Lake, Anhui Province from 1957 to 2003, the reasons for collapse of Chaohu lakeshore were analyzed. The results are as follows: 1) The collapse of the Chaohu lakeshore is controlled macroscopically by two sets of north-east and the north-west faults, and the degree of collapse is determined microcosmically by lithology. 2) The constant change of water level, resulting from precipitation, wind speed and its direction, is one of the main reasons for intermittence collapse. 3) The soil and water loss or mud and sand filling up, resulting from artificial factors, such as inconsequence control of Chaohu sluice or irrational agricultural and industrial activities, etc., can uplift the lake′s bed and drive water level up. The high water level also results in the collapse. Judging from the above mentioned reasons for the collapse, we have proposed some countermeasures: 1) Putting the lakeshore slope protection project such as stone and cement mortar into practice, and upstream slope should be 1∶2.5 or 1∶3, some parts of them should be 1∶4, if they were not stable. The back slope, which is from Gui Mountain to Zhongmiao Temple, should be 1∶1.5-1∶3. 2) Constructing a greenbelt for the lakeshore, planting some vegetation such as osier, bulrush and poplar, to resist waves between the high and the low water level. 3) Controlling Chaohu Lake water level scientifically. Corrosion of lakeshore that contains gravel clay and ferruginous-manganese concretionary structures, can decrease at low water level. 4) Renovating Chaohu Lake drainage area, strengthening the administration and supervision, breaking regionalism and establishing special administration organization.
基金Under the auspices of the National Social Science Foundation of China (No.03BJY084)
文摘Tourism development surely has social, economic and environmental impacts on tourist destinations.The study on resorts residents' attitudes can help understand the nature of tourism development and the extent to which it may influence on tourist destinations. By now, researches on residents' perception and attitudes are plenteous in the international circle and achievements are great, yet few are found in developing countries. As a most representative cultural tourist destination, World Cultural Heritage-Xidi and Hong villages in Yi County of Anhui Province, are drawing the attention of both tourists and academic circles. This article, taking Xidi and Hong villages as examples, seeks to analyze ancient village residents' attitudes towards tourism impacts and then tries further to explore the connection between tourism development and residents' attitudes. Both qualitative and quantitative surveys are applied in the exploratory investigation into local residents' attitudes of tourism impacts. Based on abundant face-to-face interviews with the local households, tourism enterprises concerned, local government and tourists from July to August of 2002, we are able to have a better understanding of local residents' attitudes to community life, and perception of tourism impacts on society, economy and environment. By this we can promote domestic study on resorts residents' attitudes, and provide some theoretical grounds for establishing tourism development planning and perfect community participation system at tourist destinations.
文摘Radar remote sensing can acquire information of sub-surface covered by sand in arid area, detect surface roughness and vegetation coronet's layer and linear feature such as linear structure and channel sensitively. With sediment facies analysis, this paper studies the features of environmental evolution in mid-late Epipleistocene (60 ka BP-20 ka BP) in northeastern Ejin Banner. The conclusions are listed as follows: (1) The evolution of the three lakes, i.e. Gaxunnur, Sugunur and Tian'e lakes, are dominated by faults and regional climate. (2) By analyzing sedimentary section of old Juyanze Lake, the three lakes used to be a large outflow lake before 50 ka BP in northeastern Ejin Banner, and at 50 ka BP, temperature declined rapidly in northwestern China. The event caused the lake's shrinkage. (3) By fault activity uplift in the northern part of old Juyan Lake and depression in the southern part, the lake's water followed from north to south at around 35 ka BP, old Juyanze fluvial fan was formed. At the same time, Juyan Lake separated from Sugunur Lake and Wentugunr old channel was abandoned. (4) In recent 2000 years, Ruoshui River is a wandering river, sometimes it flows into Juyan Lake and sometimes Sugunur and Gaxunnur lakes. Due to human activities and over exploitation, the oasis ecosystem is rapidly degenerated in 15 years (1986-2000).
基金This work was funded by the Natural Science Fund of Anhui Educational Committeethe Youth Fund of Anhui Normal University.
文摘The surface of nano-TiO_2 was encapsulated with hydroxyl-propyl-methyl cellulose(HPMC),and then cograftedwith acrylates.Conditions of absorbing and grafting have been studied.Modified nano-TiO_2 particles were characterized byFT-IR spectra,TEM and TG analysis.It was convinced from FT-IR studies that both methyl methacrylate(MMA)and butyl-methacrylate(BMA)were co-grafted onto the surface of nano-TiO_2 particles.TEM images show that the surface of nano-TiO_2 particles was successfully modified by a thick layer of film-like polymer.TG results demonstrate that the decompositiontemperature of HPMC-g-PMMA/PBMA,which has been grafted onto the surface of nano-TiO_2,is 56.9 K higher than that ofHPMC-g-PMMA/PBMA.
文摘Considering the interaction between excited triplet molecule and doublet radical, based on the second-order perturbation theory and the motion equation of density matrix, the polarization intensity of RTPM were theoretically calculated with the overpopulated doublet spin states and quartet spin states of radical-triplet pairs as initial conditions respectively. The results of calculation indicate that the net emissive polarization and the net absorptive polarization on the radical result from the zero-field-splitting (zfs) and the multiplet A/E and E/A polarization result from hyperfine (hf) interactions of the triplet molecule. The hyperfine related A+A/E or E+E/A CIDEP on the radical were the overpopulation of the net absorptive or emissive polarization and multiplet A/E or E/A polarization..
文摘From the Gibbs free energy and the equations of two-phase equilibrium curves of the two-dimensionalbinary system which has the Lennard-Jones potential, using the Collins model, the eutectic-type phase diagram and theperitectic-type phase diagram of the binary system are obtained, whose results are quite similar to the behavior of thethree-dimensional (3D) substances.
文摘Via layer-by-layer assembly, the polyoxometalates of Keggin type, SiW_ 11O_ 39Ni(H_2O) 6-(SiNiW_ 11) and {SiW_ 11O_ 39Mn(H_2O) 6-}(SiMnW_ 11) were first immobilized on a 4-aminothiophenol(4-ATP) modified glassy carbon electrode surface. The electrochemical behavior of these polyoxometalates was investigated. They exhibited some special properties in the films, which are different from those in a homogeneous aqueous solution. Their reaction mechanism in a multilayer film is proposed. The electrocatalytic behavior of these multilayer film electrodes for the reduction of BrO-_3 and NO-_2 were comparatively studied.
文摘Functionalized nano-PbS has been prepared and characterized. The functionalized nanoparticles have good dispersibility in water. Reaction of functionalized nanoPbS with gglobulin (gIgG) results an enhanced resonance light scattering (RLS) around 385 nm. However, when the content of HSA is lower than 0.5 mg ml-1 the RLS enhancement is very weak and is nonlinear to concentration of HSA. Based on these results, a new direct quantitative determination method for gglobulin in blood serum samples without separation is established. Under optimal conditions, the enhanced RLS intensity is in proportion to the gIgG concentration in the range 10500 ng/mL. The limit of detection is 2.75 ng/mL. This method is proved to be very sensitive, rapid, simple and selective for detection of gIgG in blood serum.
基金Project supported by the National Natural Science Foundation of China (No. 90211004)the Hundred Talents Project of Chinese Academy of Sciences, China
文摘A class of quasilinear singularly perturbed problems with boundary perturbation is considered. Under suitable conditions, using theory of differential inequalities we studied the asymptotic behavior of the solution for the boundary value problem.
基金The project supported by National Natural Science Foundation of China
文摘The Collins model is introduced into the two-dimensional (2D) alternative ternary system having the Lennard-Jones (L-J) potential. The Gibbs free energy of this ternary system is calculated, and according to thermodynamic theory, a group of equations that determine the solid-liquid diagram of ternary system are derived, someisothermal sectional diagrams of the 2D ternary system are obtained. The results are quite similar to the behavior ofthree-dimensional substances.
基金the Key Subject Foundation for Atomic and Molecular Physics of Anhui Province under,安徽师范大学校科研和教改项目
文摘We present a quantum measurement model where the meter is taken to be a squeezed reservoir. life realize decoherence in macroscopic limits using Bogoliubov transformation, and this kind of system-meter coupling has a dramatic influence on decoherence.
文摘The Lennard-Jones potential is introduced into the Collins model and is generalized to the two-dimensionalalternative binary system. The Gibbs free energy of the binary system is calculated. According to the thermodynamicconditions of solid-liquid equilibrium, the "cigar-type" phase diagram and the phase diagram with a minimum areobtained. The results are quite analogous to the behavior of three-dimensional substances.
文摘Taking South Lake and Jingyue Pool in Changchun as examples, we determined particulate Hg in ambient air and Hg concentration in precipitation. Results indicated that particulate Hg in air and Hg concentration in precipitation in both sites in nonheating period were lower than that in heating period, which is influenced by coal combustion. The annual particulate Hg concentrations of South Lake and Jingyue Pool were 0.254ng/m3 and 0.109ng/m3. The yearly average Hg concentrations in precipitation were 0.268μg/L(South Lake) and 0.108μg/L(Jingyue Pool). The higher particulate Hg concentration in air and Hg concentration in precipitation in South Lake than that of Jingyue Pool indicated that mercury deposition was influenced by anthropogenic sources(especially from coas combustion). Hg concentration in precipitation is related with particulate Hg in the atmosphere. Dry deposition fluxes were estimated by using dry deposition model on the base of particulate Hg concentrations in the atmosphere, they were 35.5μg/(m2.a) for South lake and 15.3μg/(m2.a) for Jingyue Pool. Combined with precipitation amount, wet deposition fluxes were estimated in these two sites, 152.2μg/(m2.a) for South Lake and 61.2μg/(m2.a) for Jingyue Pool. Atmospheric Hg deposition fluxes were 160.2g/a for South Lake and 328.62g/a for Jingyue Pool.
文摘The locally rotationally symmetric Bianchi-type II string cosmological models with bulk viscosity are obtained, where an equation of state, , and a relation between metric potentials, , are adopted. The physical features of the models are also discussed. In special cases the model reduces to the string models without viscosity that was previously given in the literatures.
基金Under the auspices of the Natural Science Foundation of Anhui Education Office (No. 2003KJ102)Special Fund Project of Anhui Provincial Irrigation Office (No. 2001-11)
文摘The study on sediment production and its relationship with climatic and hydrological factors in watershed is a major environment issue of concern in the international community. Based on the observational records covering the period from 1954 to 1999, the characteristics of precipitation changing over the Dasha River Watershed in Anhui Province and its relation to sediment yield were studied using tendency analysis and correlation analysis.Results showed that the precipitation of the Dasha River Watershed has high variability. In those 46 years, 34% of spring rainfall, 58% of summer rainfall and 30% of annual rainfall will be considered anomaly. The gray correlation analysis shows that sediment discharge correlates most closely with the frequency of the rainstorm with a daily precipitation above 100mm, secondly with the frequency of the rainstorm with a daily precipitation of 50-100mm, and thirdly with the number of rainy days. Their correlation coefficients are 0.98,0.90 and 0.85 respectively. In addition,the paper suggests the major countermeasures and methods for controlling of soil and water losses in this area.
基金Undertheauspicesof the Fund Project of Anhui Provincial Education Office (No. 2003kj155)
文摘Based on the questionnaire investigation, the authors make a comparative study on local residents′ perception of tourism impacts in Xidi, Zhouzhuang and Jiuhua Mountain. The result shows that residents of the three places tend to have strong and consistent perception of its positive economic, socio-cultural and environmental impacts, but distinctly diverse ones of its negative impacts. Residents in Xidi and Zhouzhuang also have noticeable perception of its negative environmental impacts while those in Jiuhua Mountain have weaker perception of them. The research confirms the fact that residents are more liable to have positive perceptions at the early stage of the life cycle of the tourist places. The authors conclude that there exists a nonlinear relationship between residents′ perception and tourism development stages, and that tourism socio-cultural impact may appear at an early stage of tourism development instead of being no universal.
文摘The title compound (C10H11BrO4, Mr = 275.10) was synthesized and its crystal structure has been determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n with a = 7.2960(8), b = 12.209(1), c = 12.568(1) ? b = 98.120(2)? l = 0.71073 ? m(MoKa) = 3.700 mm-1, V = 1108.3(2) 3, Z = 4, Dc = 1.649 g/cm3 and F(000) = 552. The structure was solved by direct methods and refined by full-matrix least-squares methods. R = 0.0375 and wR = 0.0864 for 1598 reflections with I > 2s(I). X-ray diffraction reveals that there exist two rings in the molecule, and the dihedral between them is 177.5?