Different methods of calibrating ultra high frequency(UHF) sensors for gas-insulated substations(GIS) were investigated in the past.The first approach was to use strip lines,triplates and TEM calibration cells.These c...Different methods of calibrating ultra high frequency(UHF) sensors for gas-insulated substations(GIS) were investigated in the past.The first approach was to use strip lines,triplates and TEM calibration cells.These cells had already been in use for years for example to test the electromagnetic compatibility of electronic devices.The smaller the size of the cell,the higher its bandwidth-but the cell should be large enough to not disturb the electric field with the installed sensor under test.To overcome this problem,a calibration procedure using a gigahertz transverse electromagnetic (GTEM) test cell and a pulsed signal source were introduced in 1997.Although this procedure has many advantages and is easy to understand,measurements show several shortcomings of this calibration method.To overcome the disadvantages of the known systems,a calibration cell using a monopole cone antenna and a metallic ground plane were developed and tested.The UHF sensor was placed in a region with minimum distortion of the electric field due to its installation.Experience shows that the new method for calibrating UHF sensors is necessary in order to overcome the limits in the calibration of large sensors and to suppress the propagation of higher order modes and reflections.Due to its surprisingly simple structure,its low price and low overall measurement uncertainty,it is the preferred method for calibrating UHF sensors for GIS applications.展开更多
Kinetic parameters of the decomposition of hazardous chemicals can be applied for the estimation of their thermal behavior under any temperature profile.Presented paper describes the application of the advanced kineti...Kinetic parameters of the decomposition of hazardous chemicals can be applied for the estimation of their thermal behavior under any temperature profile.Presented paper describes the application of the advanced kinetic approach for the determination of the thermal behavior also under adiabatic conditions occurring e.g.in batch reactors in case of cooling failure.The kinetics of the decomposition of different samples(different manufacturers and batches) of 3-methyl-4-nitrophenol were investigated by conventional DSC in non-isothermal(few heating rates varying from 0.25 to 8.0K/min) and isothermal(range of 200~260℃) modes.The kinetic parameters obtained with AKTS-Thermokinetics Software were applied for calculating reaction rate and progress under different heating rates and temperatures and verified by comparing simulated and experimental signals.After application of the heat balance to compare the amount of heat generated during reaction and its removal from the system,the knowledge of reaction rate at any temperature profiles allowed the determination of the temperature increase due to the self-heating in adiabatic and pseudo-adiabatic conditions.Applied advanced kinetic approach allowed simulation the course of the Heat-Wait-Search(HWS) mode of operation of adiabatic calorimeters.The thermal safety diagram depicting dependence of Time to Maximum Rate(TMR) on the initial temperature was calculated and compared with the results of HWS experiments carried out in the system with Ф-factor amounting to 3.2.The influence of the Ф-factor and reaction progress reached at the end of the HWS monitoring on the TMR is discussed.Presented calculations clearly indicate that even very minor reaction progress reduces the TMRad of 24h characteristic for a sample with initial reaction progress amounting to zero.Described estimation method can be verified by just one HWS-ARC,or by one correctly chosen ISO-ARC run of reasonable duration by knowing in advance the dependence of the TMR on the initial temperature for any Ф-factor.Proposed procedure results in significant shortening of the measuring time compared to a safety hazard approach based on series of ARC experiments carried out at the beginning of a process safety evaluation.展开更多
文摘Different methods of calibrating ultra high frequency(UHF) sensors for gas-insulated substations(GIS) were investigated in the past.The first approach was to use strip lines,triplates and TEM calibration cells.These cells had already been in use for years for example to test the electromagnetic compatibility of electronic devices.The smaller the size of the cell,the higher its bandwidth-but the cell should be large enough to not disturb the electric field with the installed sensor under test.To overcome this problem,a calibration procedure using a gigahertz transverse electromagnetic (GTEM) test cell and a pulsed signal source were introduced in 1997.Although this procedure has many advantages and is easy to understand,measurements show several shortcomings of this calibration method.To overcome the disadvantages of the known systems,a calibration cell using a monopole cone antenna and a metallic ground plane were developed and tested.The UHF sensor was placed in a region with minimum distortion of the electric field due to its installation.Experience shows that the new method for calibrating UHF sensors is necessary in order to overcome the limits in the calibration of large sensors and to suppress the propagation of higher order modes and reflections.Due to its surprisingly simple structure,its low price and low overall measurement uncertainty,it is the preferred method for calibrating UHF sensors for GIS applications.
文摘Kinetic parameters of the decomposition of hazardous chemicals can be applied for the estimation of their thermal behavior under any temperature profile.Presented paper describes the application of the advanced kinetic approach for the determination of the thermal behavior also under adiabatic conditions occurring e.g.in batch reactors in case of cooling failure.The kinetics of the decomposition of different samples(different manufacturers and batches) of 3-methyl-4-nitrophenol were investigated by conventional DSC in non-isothermal(few heating rates varying from 0.25 to 8.0K/min) and isothermal(range of 200~260℃) modes.The kinetic parameters obtained with AKTS-Thermokinetics Software were applied for calculating reaction rate and progress under different heating rates and temperatures and verified by comparing simulated and experimental signals.After application of the heat balance to compare the amount of heat generated during reaction and its removal from the system,the knowledge of reaction rate at any temperature profiles allowed the determination of the temperature increase due to the self-heating in adiabatic and pseudo-adiabatic conditions.Applied advanced kinetic approach allowed simulation the course of the Heat-Wait-Search(HWS) mode of operation of adiabatic calorimeters.The thermal safety diagram depicting dependence of Time to Maximum Rate(TMR) on the initial temperature was calculated and compared with the results of HWS experiments carried out in the system with Ф-factor amounting to 3.2.The influence of the Ф-factor and reaction progress reached at the end of the HWS monitoring on the TMR is discussed.Presented calculations clearly indicate that even very minor reaction progress reduces the TMRad of 24h characteristic for a sample with initial reaction progress amounting to zero.Described estimation method can be verified by just one HWS-ARC,or by one correctly chosen ISO-ARC run of reasonable duration by knowing in advance the dependence of the TMR on the initial temperature for any Ф-factor.Proposed procedure results in significant shortening of the measuring time compared to a safety hazard approach based on series of ARC experiments carried out at the beginning of a process safety evaluation.
