In this paper, strontium aluminate phosphors of Sr Al2O4: Eu2+, Dy3+ and Sr4Al14O25: Eu2+, Dy3+ were prepared via solid state reactions and subsequent surface modification with Si O2 by a chemical precipitation method...In this paper, strontium aluminate phosphors of Sr Al2O4: Eu2+, Dy3+ and Sr4Al14O25: Eu2+, Dy3+ were prepared via solid state reactions and subsequent surface modification with Si O2 by a chemical precipitation method. The strontium aluminate phosphors were characterized by measurement-ray diffraction. According to the analysis by transmission electron microscopy, a continuous Si O2 coating layer with a thickness of 50 nm can be formed on the surface of Si O2-coated phosphor. The covalent bond that attached the phosphor and the Si O2 coating was determined by Fourier transform infrared spectroscopy. The water resistance and optical measurements indicate that the optimum ratio of Si O2 coating to phosphors is 30% by mass. Also, the Si O2-coated phosphors could be used in a water-borne paint with the superior luminous performance.展开更多
基金financially supported by the Bayer-Tongji Eco-Construction and Materials Academythe open Funds from the Key Laboratory of Advanced Civil Engineering Materials (Tongji University)
文摘In this paper, strontium aluminate phosphors of Sr Al2O4: Eu2+, Dy3+ and Sr4Al14O25: Eu2+, Dy3+ were prepared via solid state reactions and subsequent surface modification with Si O2 by a chemical precipitation method. The strontium aluminate phosphors were characterized by measurement-ray diffraction. According to the analysis by transmission electron microscopy, a continuous Si O2 coating layer with a thickness of 50 nm can be formed on the surface of Si O2-coated phosphor. The covalent bond that attached the phosphor and the Si O2 coating was determined by Fourier transform infrared spectroscopy. The water resistance and optical measurements indicate that the optimum ratio of Si O2 coating to phosphors is 30% by mass. Also, the Si O2-coated phosphors could be used in a water-borne paint with the superior luminous performance.
