Regulating metal-acid double site balance on mesoporous SiO_(2)-Al_(2)O_(3) composite oxide for supercritical n-decane cracking

The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low coking.Nevertheless,how to control acid-metal sites balance and its relationship with cracking performance are reported scarcely.In this work,a series of Pt/Al_(2)O_(3)-SiO_(2) dual sites catalysts with different metal to acid active sites ratio(C_(M)/C_(SA))were constructed by ethanolassisted impregnation method and the impact on n-decane cracking under supercritical conditions was systematically and deeply investigated.The results showed that the conversion and carbon deposition increased gradually with varied C_(M)/C_(SA)and reached the balance at C_(M)/C_(SA)of 0.13.The proper ratio C_(M)/C_(SA)(0.13)can balance the deep dehydrogenation coking over metal active sites and high heat sink of cracking over acid active sites,the chemical heat sink reaches amazing 1.75 MJ/kg and carbon deposition is only22.03 mg/cm^(2) at 750℃.Meanwhile,the few metal sites at low C_(M)/C_(SA)and the few strong acid sites at high C_(M)/C_(SA)are the main factors limiting the cracking activity.Low C_(M)/C_(SA)limit the activation of C-H bond and deep dehydrogenation of coking precursor,resulting in relative low cracking activity and carbon deposition,while high C_(M)/C_(SA)limit the activation of C-C bond and increase the deep dehydrogenation.In this contribution,design and construction of metal-acid dual sites can not only provide the technical solution for the preparation of high heat sink and low coking cracking catalyst,but also deepen the understanding of the cracking path of hydrocarbon fuel.

Effect of HEA/Al composite interlayer on microstructure and mechanical property of Ti/Mg bimetal composite by solid-liquid compound casting

In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HEA layer was prepared by magnetron sputtering onto the Al layer.The influence of the HEA layer thickness and pouring temperature on interface evolution was investigated based on SEM observation and thermodynamic analysis.Results indicate that the sluggish diffusion effect of HEA can effectively inhibit the interfacial diffusion between Al and Mg,which is conducive to the formation of solid solution,especially when the thickness of HEA is 800 nm.With the increase of casting temperature from 720 ℃ to 730 ℃,740℃,and 750 ℃,α-Al(Mg),α-Al(Mg)+Al3Mg2,Al3Mg2+Al12Mg17,and Al12Mg17+δ-Mg are formed at the interface of Ti/Mg bimetal,respectively.When the thickness of the HEA layer is 800 nm and the pouring temperature is 720 ℃,the bonding strength of the Ti/Mg bimetal can reach the maximum of 93.6 MPa.

结构用集成材拼方自动上料设备的研制

介绍了一种基于PLC控制的自动上料设备。该设备应用于结构用集成材拼方过程中,具有自动传送、自动翻转、步进推靠、自动卸料等功能。对该设备的主要机械结构、动作方式和电气控制原理做了详细的表述。此设备已经成功应用于生产实践,并且运行稳定可靠,操作方便快捷。

基于机器视觉的锯材表面缺陷检测系统设计

锯材表面缺陷对锯材的质量和性能有着重要的影响。设计了基于机器视觉的锯材表面缺陷自动检测系统和计算机软件检测识别方法,确定了主要参数。通过对锯材表面图像的主要缺陷进行统计分析,综合评价整根锯材。检测系统的硬件主要由传送机构、电控系统、图像采集控制、分等系统等部分组成。软件主要由图像采集、图像处理、缺陷统计分析等部分组成。

竹木结构外墙热湿模拟研究

为了探索不同材料及构造外墙的热湿表现,设计了包括基准墙体在内的7种竹木结构外墙,分别以上海及北京典型气象年气象数据为边界条件,采用WUFI Plus进行全建筑热湿模拟。通过模拟,从居住舒适性、冷凝、霉菌生长、能耗等方面进行比较分析。模拟结果显示,综合来看W4号墙体有着较好的热湿表现;两种气候条件下较短时间段内需关注冷凝现象的发生;上海气候条件下发生霉菌的隐患低,北京气候条件下不存在霉菌隐患。验证了将竹质材料应用于墙体设计的可行性,同时也为新型墙体设计提供了思路。

Effects of two-step annealing on properties of Cd_(1-x)Zn_xTe single crystals

The Cd1-xZnxTe（CZT） single crystals were annealed by a two-step method including a vapor-environment step and a liquid-environment step in sequence. The effects of annealing on the properties of CZT were analyzed in detail. IR transmission measurement results show that IR transmission of CZT is improved dramatically after annealing. X-ray rocking curves indicate that the annealing treatment ameliorates crystal quality obviously, which is ascribed to the release of residual stress and the reduction of point defects. Photoluminescence（PL） spectra reveal that the full width at half maximum（FWHM） of the donor-bound exciton （D0, X） peak is reduced obviously, and the free exciton emission is weakened after annealing. Meanwhile, the intensity of the donor-acceptor pair（DAP） peak decreases to a great degree, which implies that the impurities are removed from CZT wafers. In addition, the deep defect-related emission band Dcomplex disappears after annealing, which mean that Cd vacancies are well-compensated. The results confirm that the two-step annealing is an effective approach to improve the qualities of CZT single crystals.

An efficient unstructured WENO method for supersonic reactive flows

An efficient high-order numerical method for supersonic reactive flows is proposed in this article.The reactive source term and convection term are solved separately by splitting scheme.In the reaction step,an adaptive time-step method is presented,which can improve the efficiency greatly.In the convection step,a third-order accurate weighted essentially non-oscillatory（WENO）method is adopted to reconstruct the solution in the unstructured grids.Numerical results show that our new method can capture the correct propagation speed of the detonation wave exactly even in coarse grids,while high order accuracy can be achieved in the smooth region.In addition,the proposed adaptive splitting method can reduce the computational cost greatly compared with the traditional splitting method.

WUFI Pro热湿模拟软件的应用及评价

建筑围护结构热湿性能是建筑物理研究的重要内容,它影响着建筑的耐久性、能耗水平及居住舒适性。通过WUFI Pro(一维瞬态热湿传递模型)进行热湿分析,需要正确的构建结构模型、设置边界条件及运用合理的计算方式,以尽可能的获取真实的结果。WUFI Pro已经被广泛应用于包括木结构在内的多种建筑形式中,对于新型材料及构造形式的开发利用具有积极推动作用。输入参数确定需要的大量工作也一定程度限制了软件的使用。

Gas Path Fault Tolerant Control of Aero-Engine Based on On-Board Model

A fault tolerant control method is proposed in this paper for a turbofan engine gas path degradation through the full flight envelope. A Quantum-behaved Particle Swarm Optimization(QPSO) algorithm is applied to obtain engine inputs adjustments, which contribute to construct off-line performance accommodation interpolation schedules. With a double closed-loop control system structure, command control is corrected based on real-time fault diagnostic results. Simulations indicate that fault tolerant control could reduce thrust and stall margin loss effectively in gas path faults.

Thermodynamic performance modeling,optimization and numerical simulation of RBCC ejector mode

Ejector mode is a unique and critical phase of wide-range rocket-based combined cycle(RBCC)engine.In this paper,a quasi-one-dimensional thermodynamic performance modeling method,with more detailed model treatments for the inlet-diffuser system,pri-mary/secondaryflow interaction,and pressure feedback matching,was developed for operating characteristics studies and multi-objective optimization analysis of the ejector mode of an actual RBCC engine.A series of three-dimensional simulations of separate inlet and fullflowpath was completed to validate the modeling study and provide further insight into the operating charac-teristics.The primary/secondary equilibrium pressure ratio functions a significant effect on ejector mode performance,a higher performance augmentation can be obtained by lower rocket pressure ratio,larger mixing section area ratio,smaller throttling throat and higher equivalence ratio,within an appropriate range.The positive performance augmentation can be realized at lowflight Mach conditions,the coordination and trade-off relationships between specific im-pulse,performance augmentation ratio and thrust-to-area ratio during ejector mode are present by the Pareto-front from MOP analysis.It is further verified by CFD simulation that,the operating back-pressure at the exit of inlet-diffuser system functions a decisive influence on the airbreathing characteristics,the pressure feedback and matching should be well-controlled for secondaryflowrate and performance augmentation.The thermodynamic modeling analysis re-sults are basically consistent with those of numerical simulation,to validate the rationality and effectiveness of the modeling method.

Experimental study on flow excursion instability of supercritical hydrocarbon fuel in scramjet regenerative cooling parallel channels

Flow instability of supercritical hydrocarbon fuel is a crucial issue in scramjet regenerative cooling structure. In this study, flow excursion instability and flow distribution in parallel tubes were experimentally studied for supercritical fluids. Two types of flow excursion occur in a single tube. Type Ⅰ and Type Ⅱ excursions, and they are corresponding to decreasing and increasing flow rate respectively. They can trigger flow maldistribution between parallel tubes and the hysteresis phenomenon of flow distribution. The effects of system parameters, including inlet temperature,system pressure, and heat flux, on flow distribution were analyzed. In addition, the relationship between flow excursion and the pseudo-critical interval proposed in the literature was established according to the heated tube outlet temperature at the onset of flow instability. Finally, the flow excursion instability boundary was obtained using two dimensionless parameters. These experimental results can provide helpful insight on the mechanism of Scramjet regenerative cooling.

Effect of Brazing Conditions on Microstructure and Mechanical Properties of Al_2O_3/Ti—6Al—4V Alloy Joints Reinforced by TiB Whiskers

Al2O3 and Ti-6Al-4V alloy were brazed with Ag-Cu-Ti ＋B fillers in different brazing conditions. Effects of brazing temperature, holding time and additive Ti content on joints microstructure and shear strength were investigated by scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction, transmission electron microscopy and shear testing. Results indicate that TiCu and Ti（Cu,Al） decrease, but Ti2Cu and -Ti2（Cu,Al） increase in brazing seam with increasing brazing temperature, holding time and additive Ti content. Area consisting of Ti3（Cu,Al）30 and TiO near Al2O3 becomes gradually discontinuous from continuity when brazing temperature rises or holding time extends. As Ti additive content increases, TiO is absent near Al2O3, area consisting of only Ti3（Cu,Al）30 thickens. TiB whiskers are in situ synthesized by Ti and B atoms during brazing process. The brazing temperature, holding time and additive Ti content on joints microstructure influence the joints shear strength directly. The shear strength of joints, obtained at 850 ℃ holding for 10 min, reaches the maximum of 78 MPa. According to the experimental results, phase diagram and thermodynamics calculation, the interface evolution mechanism of the Al2O3/Ti-6Al-4V alloy joint was analyzed.

Effects of Reynolds number on the performance of a high pressure-ratio turbocharger compressor

The effects of Reynolds number on the performance of a high pressure-ratio turbocharger compressor were investigated by both experiments and numerical simulation. The experimental results show that the pressure ratio and the efficiency of the compressor respectively decrease by 7.9% and 6.9% when Reynolds number drops from 9.86×10 5 to 2.96×10 5 . The numerical simulation predicts a similar trend as the experimental results although it underestimates the deterioration of the performance under low Reynolds number conditions. According to simulation results, the boundary layer thickness increases at the inducer, which decreases the throat area and leads to smaller choke mass flow rate. The increments of the boundary thickness are relatively small at the rear part of the impeller. The boundary layer separation flow is severe. The interaction between boundary layer separation flows and leakage flows causes the high loss region at the rear part of the impeller passage under low Reynolds number condition.

Running Test and Optimization of Bamboo OSB Medium Experimental Line

Bamboo OSB(BOSB) medium experimental line and key equipments are presented for the first time based on the analysis of BOSB production technologies and processes requirements. Component of BOSB medium experimental line and key equipments stated.The paper illustrated BOSB flaker,glue blender,orienting former.Then medium experimental line is given to a great deal of test run and optimization.The tests indicated that the medium experimental line operated smoothly for producing BOSB.Tested BOSB key performance indicators were higher than the LY/T 1580 - 2000(OSB /4).