Acidichromism in the LB film of bolaform Schiff base

bolaform (BNC10 ) 并且领导单人赛(HNOA ) 包含 naphthyl 组的 amphiphilic Schiff 被设计，他们的 Langmuir Blodgett 电影被调查。两个都， LB 电影显示出 acidichromism，这被发现，即在或者分别地暴露这些电影到 HCl 和 NH3 气体之上的可逆变色。bolaform Schiff 电影能在 acidichromic 过程期间套住 NH3 气体，这进一步被发现。

Synthesis of new 1,3-bis(phenylethynyl)disilazanes

Three new 1,3-bis（phenylethynyl）disilazanes were synthesized from the reaction of 1,3-dichlorodisilazanes with （phenylethynyl）lithium, and characterized by infrared （IR） spectra, nuclear magnetic resonance （NMR） and mass spectrometry （MS）.

Solution-phase Synthesis of One-dimensional Semiconductor Nanostructures

The synthesis of one-dimensional （1D） semiconductor nanostructures has been studied intensively for a wide range of materials due to their unique structural and physical properties and promising potential for future technological applications. Among various strategies for synthesizing 1D semiconductor nanostructures, solution-phase synthetic routes are advantageous in terms of cost, throughput, modulation of composition, and the potential for large-scale and environmentally benign production. This article gives a concise review on the recent developments in the solution-phase synthesis of ID semiconductor nanostructures of different compositions, sizes, shapes, and architectures. We first introduce several typical solution-phase synthetic routes based on controlled precipitation from homogeneous solutions, including hydrothermal/solvothermal process, solution-liquid-solid （SLS） process, high-temperature organic-solution process, and low-temperature aqueous-solution process. Subsequently, we discuss two solution-phase synthetic strategies involving solid tem- plates or substrates, such as the chemical transformation of 1D sacrificial templates and the oriented growth of 1D nanostructure arrays on solid substrates. Finally, prospects of the solution-phase approaches to 1D semiconductor nanostructures will be briefly discussed.

Synthesis of new borazines containing crosslinkable groups

Three new functional group containing borazine derivatives, 2,4,6-tri（allylamino）borazine, 2,4,6-tri（3-ethynylanilino）borazine, and 2,4,6-tri（4-propargyl oxyanilino）borazine were synthesized by aminolysis reaction of 2,4,6-trichloroborazine ClaB3N3H3（TCB）. The new compounds were characterized by infrared （IR） spectra, nuclear magnetic resonance （NMR）, and mass spectrometry （MS）.

Production and Characterization of Monoclonal Antibody Against Recombinant Human Erythropoietin

Objective To produce specific monoclonal antibody （mAb） against recombinant human erythropoietin （rHuEPO） for development of highly efficient methods for erythropoietin detection in biological fluids. Methods rHuEPO was covalently coupled with bovine serum albumin （BSA） and the conjugate was used to immunize mice to produce specific mAb against rHuEPO based on hybridoma technology. The obtained F3-mAb was characterized by enzyme-linked irmnunosorbent assay （ELISA）, SDS-PAGE and Western blot. Results The isotype of F3-mAb was found to be IgM with an affinity constant of 2.1x10s L/mol. The competitive ELISA using the obtained IgM showed a broader linear range and lower detection limit compared with previous work. Conclusions The modification of rHuEPO was proved to be successful in generating required specific mAb with high avidity to rHuEPO.

Mass Spectrometric Studies on Metal-hexafluorobenzene Anionic Complexes(M=Ag, Au, Pd, Pt, Pb and Bi)

The anionic products from the reactions between metal（M=Ag, Au, Pd, Pt, Pb and Bi） vapour produced by laser ablation and hexafluorobenzene seeded in carrier gas（Ar） were studied by means of a homemade reflectron time-of-flight mass spectrometry（RTOF-MS）. Experimental results show that the dominant products were [MmC6F6]^- complexes for the reactions ofAg, Au, Pd and Pt with C6F6, while the dominant products were [MmC6F5]^- complexes for the reactions of Pb and Bi with C6F6. The formation mechanisms of the products, including the adsorption of metal cluster anions on hexafluorobenzene and the C--F cleavage induced by metal cluster anions, were discussed.

A Miniature Droplet Reactor Built on Nanoparticle-Derived Superhydrophobic Pedestals

设计并且调制材料，形状，热转移，和团在开发化学反应堆的过程期间混合的能力允许研究人员探索百万化学反应和试金。尽管有在设计基于数组的 microreactors 或 microfluidic 系统的优点，然而，在试剂 / 产品和玻璃或集装箱的聚合物底层的答案之间的弄湿的附件在有效地收集产品并且阻止隧道阻塞导致困难。此处我们在场利用导出 nanoparticle 的 superhydrophobic 柱脚的弄湿反、低粘合剂的性质的一个缩小的微滴反应堆，允许水的微滴自由地被操作而且为在小规模上执行一系列水的阶段化学药品反应提供限制环境。煤气形成或猛抛形成反应能也在这个缩小的反应堆内被执行。最重要地，在液体，固体或气体的状态的反应产品能有效地被收集，它允许收获在有限数量形成的珍贵产品。在 superhydrophobic 柱脚上造的如此的一个缩小的反应堆提供执行普通化学反应的一个新方法并且可以打开门到下一代的 microreaction 系统的设计。

Self-assembly of latex particles for colloidal crystals

Self-assembly of latex particles is of great importance for fabricating various functional colloidal crystals. In this paper, we review recent research on the self-assembly of latex particles for colloidal crystals, covering the assembly forces and various assembly approaches of latex particles, including self-assembly by gravity sedimentation, vertical deposition, physical confinement, electric field, and magnetic field. Furthermore, some simple methods for assembling latex particles such as spin coating, spray coating, and printing are also summarized.

FeCl3- and GaCl3-Catalyzed Dehydrative Coupling Reaction of Chromone-Derived Morita-Baylis-Hillman Alcohols with Terminal Alkynes

FeCl3- and GaCl3-catalyzed dehydrative coupling reactions of chromone-derived Morita-Baylis-Hillman （MBH） alcohols with terminal alkynes were developed. The reactions provided exclusively a-regioselective and acetylene-substituted products in good yields.