Ammonia borane is widely used in most areas including fuel cell applications.The present paper describes electrochemical behavior of ammonia borane in alkaline media on the poly(p-aminophenol) film modified with Au an...Ammonia borane is widely used in most areas including fuel cell applications.The present paper describes electrochemical behavior of ammonia borane in alkaline media on the poly(p-aminophenol) film modified with Au and Ag bimetallic nanoparticles.The glassy carbon electrode was firstly covered with polymeric film electrochemically and then,Au,Ag,and Au–Ag nanoparticles were deposited on the polymeric film,respectively.The surface morphology and chemical composition of these electrodes were examined by scanning electron microscopy,transmission electron microscopy,electrochemical impedance spectroscopy,X-ray diffraction,and X-ray photoelectron spectroscopy.It was found that alloyed Au–Ag bimetallic nanoparticles are formed.Electrochemical measurements indicate that the developed electrode modified by Au–Ag bimetallic nanoparticles exhibit the highest electrocatalytic activity for ammonia borane oxidation in alkaline media.The rotating disk electrode voltammetry demonstrates that the developed electrode can catalyze almost six-electron oxidation pathway of ammonia borane.Our results may be attractive for anode materials of ammonia borane fuel cells under alkaline conditions.展开更多
In this paper,the dynamical behaviors of a discrete-time fractional-order population model are considered.The stability analysis and the topological classification of the model at the fixed point have been investigate...In this paper,the dynamical behaviors of a discrete-time fractional-order population model are considered.The stability analysis and the topological classification of the model at the fixed point have been investigated.It is shown that the model undergoes flip and Neimark-Sacker bifurcations around the co-existence fixed point by using the bifurcation and the normal form theory.These bifurcations lead to chaos when the parameter changes at critical point.In order to control chaotic behavior in the model result from Neimark-Sacker bifurcation,the OGY feedback method has been used.Furthermore,some numerical simulations,including bifurcation diagrams,phase portraits and maximum Lyapunov exponents of the presented model are plotted to support the correctness of the analytical results.The positive Lyapunov exponents demonstrate that chaotic behavior exists in the considered model.展开更多
基金supported by the Scientific and Technical Research Council of Turkey(TUBITAK) with 110T806 project numberEBILTEM with BIL-012 project numberEge University Research Funds(BAP project,10 FEN/075)
文摘Ammonia borane is widely used in most areas including fuel cell applications.The present paper describes electrochemical behavior of ammonia borane in alkaline media on the poly(p-aminophenol) film modified with Au and Ag bimetallic nanoparticles.The glassy carbon electrode was firstly covered with polymeric film electrochemically and then,Au,Ag,and Au–Ag nanoparticles were deposited on the polymeric film,respectively.The surface morphology and chemical composition of these electrodes were examined by scanning electron microscopy,transmission electron microscopy,electrochemical impedance spectroscopy,X-ray diffraction,and X-ray photoelectron spectroscopy.It was found that alloyed Au–Ag bimetallic nanoparticles are formed.Electrochemical measurements indicate that the developed electrode modified by Au–Ag bimetallic nanoparticles exhibit the highest electrocatalytic activity for ammonia borane oxidation in alkaline media.The rotating disk electrode voltammetry demonstrates that the developed electrode can catalyze almost six-electron oxidation pathway of ammonia borane.Our results may be attractive for anode materials of ammonia borane fuel cells under alkaline conditions.
文摘In this paper,the dynamical behaviors of a discrete-time fractional-order population model are considered.The stability analysis and the topological classification of the model at the fixed point have been investigated.It is shown that the model undergoes flip and Neimark-Sacker bifurcations around the co-existence fixed point by using the bifurcation and the normal form theory.These bifurcations lead to chaos when the parameter changes at critical point.In order to control chaotic behavior in the model result from Neimark-Sacker bifurcation,the OGY feedback method has been used.Furthermore,some numerical simulations,including bifurcation diagrams,phase portraits and maximum Lyapunov exponents of the presented model are plotted to support the correctness of the analytical results.The positive Lyapunov exponents demonstrate that chaotic behavior exists in the considered model.
