One new sandwich-type tetra-nickel substituted polyoxotungsate,[Ni(trien)]4-[Ni4(H2O)2(HPW9O34)2]·4H2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental a...One new sandwich-type tetra-nickel substituted polyoxotungsate,[Ni(trien)]4-[Ni4(H2O)2(HPW9O34)2]·4H2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental analysis,TGA,and single-crystal X-ray diffraction analysis.Crystal data for 1:triclinic,space group P with a=13.279(3),b=13.816(3),c=14.494(4),α=95.403(1),β=113.173(4),γ=93.809(3)o,V=2418.0(10)3,Z=1 and Dc=3.861 g/cm3.X-ray crystallographic study shows that compound 1 is a relatively rare inorganic-organic hybrid polyoxo tungstate constructed from sandwich Ni-substituted polyoxo-anions and nickel complexes.展开更多
One new arsenic-vanadium cluster, [Zn(dien)(Hdien)]2[As6V15O42(H2O)]·4H2O (1, dien = diethylenetriamine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic pro...One new arsenic-vanadium cluster, [Zn(dien)(Hdien)]2[As6V15O42(H2O)]·4H2O (1, dien = diethylenetriamine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, a = 13.959(3), b = 22.428(5), c = 22.831(5) A^°, β = 90.733(4)°, Z = 4. X-ray crystallographic study showed that compound 1 is constructed from [As6V15O42(H2O)]^6- polyoxoanions linked together by novel [Zn(dien)(Hdien)]^3+ complex fragments via hydrogen bonds into a three-dimensional network. Variable temperature susceptibility measurement demonstrates the presence of antiferromagnetic interaction between V^IV cations in 1.展开更多
基金supported by the National Natural Science Fund for Distinguished Young Scholars of China (No 20725101)the 973 Program (No 2006CB932904)+2 种基金the NSF of Fujian Province (No E0510030)the NNSFC (No 20521101)the Research Foundation of Education Bureau of Fujian Province (No JA08053)
文摘One new sandwich-type tetra-nickel substituted polyoxotungsate,[Ni(trien)]4-[Ni4(H2O)2(HPW9O34)2]·4H2O(1,trien=triethylenetetramine),has been hydrothermally synthesized and characterized by IR,elemental analysis,TGA,and single-crystal X-ray diffraction analysis.Crystal data for 1:triclinic,space group P with a=13.279(3),b=13.816(3),c=14.494(4),α=95.403(1),β=113.173(4),γ=93.809(3)o,V=2418.0(10)3,Z=1 and Dc=3.861 g/cm3.X-ray crystallographic study shows that compound 1 is a relatively rare inorganic-organic hybrid polyoxo tungstate constructed from sandwich Ni-substituted polyoxo-anions and nickel complexes.
基金Supported by the National Natural Science Fund for Distinguished Young Scholars of China (No. 20725101)the 973 Program (No. 2006CB932904)+2 种基金the NSF of Fujian Province (No. E0510030)the Knowledge Innovation Program of CAS (No. KJCX2.YW.H01)the NNSFC (No. 20821061)
文摘One new arsenic-vanadium cluster, [Zn(dien)(Hdien)]2[As6V15O42(H2O)]·4H2O (1, dien = diethylenetriamine), has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, a = 13.959(3), b = 22.428(5), c = 22.831(5) A^°, β = 90.733(4)°, Z = 4. X-ray crystallographic study showed that compound 1 is constructed from [As6V15O42(H2O)]^6- polyoxoanions linked together by novel [Zn(dien)(Hdien)]^3+ complex fragments via hydrogen bonds into a three-dimensional network. Variable temperature susceptibility measurement demonstrates the presence of antiferromagnetic interaction between V^IV cations in 1.