Microalgae biomass is an ideal precursor to prepare renewable carbon materials,which has broad application.The bioaccumulation efficiency(lipids,proteins,carbohydrates)and biomass productivity of microalgae are influe...Microalgae biomass is an ideal precursor to prepare renewable carbon materials,which has broad application.The bioaccumulation efficiency(lipids,proteins,carbohydrates)and biomass productivity of microalgae are influenced by spectroscopy during the culture process.In this study,a bilayer plate-type photobioreactor was designed to cultivate Chlorella protothecoides with spectral selectivity by nanofluids.Compared to culture without spectral selectivity,the spectral selectivity of Ag/CoSO_(4)nanofluids increased microalgae biomass by 5.76%,and the spectral selectivity of CoSO_(4)solution increased by 17.14%.In addition,the spectral selectivity of Ag/CoSO_(4)nanofluids was more conducive to the accumulation of nutrients(29.46%lipids,50.66%proteins,and 17.86%carbohydrates)in microalgae.Further cultured chlorella was utilized to prepare bioelectrode materials,it was found that algal based biochar had a good pore structure(micro specific surface area:1627.5314 m^(2)/g,average pore size:0.21294 nm).As the current density was 1 A/g,the specific capacitance reached 230 F/g,appearing good electrochemical performance.展开更多
In this paper,CaO/bio-char was synthesized by directly co-pyrolysis of Ca(OH)_(2) and rice straw,and used as catalyst to catalytic pyrolysis of soybean oil to produce high quality biofuel.In this co-pyrolysis process,...In this paper,CaO/bio-char was synthesized by directly co-pyrolysis of Ca(OH)_(2) and rice straw,and used as catalyst to catalytic pyrolysis of soybean oil to produce high quality biofuel.In this co-pyrolysis process,CaO particles has been successfully embedded on the bio-char surface.During the catalytic pyrolysis process,CaO/biochar showed a good catalytic performance on the deoxygenation of soybean oil.Pyrolysis temperature affected the pyrolysis reactions and pyrolytic products distributions dramatically,higher pyrolysis temperature lead to seriously cracking reactions,lower bio-oil yield and higher gases yield,and lower pyrolysis temperature lead to higher bio-oil yield with higher oxygenated compounds content and lower hydrocarbons contents,the suitable pyrolysis temperature was around 650℃.Under the optimal conditions(650℃ with WHSV at 6.4 h^(−1) and carrier gas flow rate at 100 ml/min),the selectivity(%)of hydrocarbons in the bio-oil was more than 90%.CaO/bio-char catalyst still shows good catalytic deoxygenation activity after 4 cycles.1 g of CaO/bio-char catalyst can catalyze pyrolysis of 32 g of soybean oil to produce high-quality liquid fuel.Bio-char based catalyst has been proved to be a promising catalyst for catalytic conversion of triglyceride-based lipids into high quality liquid biofuel.展开更多
The coconut mite, <i>Aceria</i> <i>guerreronis</i> Keifer (Acari: Eriophyidae), is a major pest of coconut plantations (<i>Cocos</i> <i>nucifera</i> L.) worldwide. Here,...The coconut mite, <i>Aceria</i> <i>guerreronis</i> Keifer (Acari: Eriophyidae), is a major pest of coconut plantations (<i>Cocos</i> <i>nucifera</i> L.) worldwide. Here, we conducted a bioguided<span style="font-family:;" "=""> </span><span style="font-family:;" "="">phytochemical approach using toxicity and repellency bioassays of nonpolar extract and its fractions of <i>Vitex</i> <i>gardneriana</i> Schauer (Lamiaceae) leaves to this pest. Nonpolar crude extract was fractionated by column chromatography using solvents with increased polarity and binary mixtures, resulting in five semipurified groups. The biomonitor</span><span style="font-family:;" "="">ing</span><span style="font-family:;" "=""> bioassay provided active fractions and led to the isolation and characterization of the <span>bioactive compound squalene, a biosynthetic precursor of 20-hydroxyecdysone,</span> which plays an important role in plant defense against arthropods. The LC<sub>50</sub> of the crude extract of <i>V</i>. <i>gardneriana</i> for <i>A</i>. <i>guerreronis</i> was estimated to be 0.185 mg·mL<sup>-1</sup> and LC<sub>80</sub> = 4.123 mg·mL<sup>-1</sup>. Also, the extract was highly repellent to this pest for up to 24 h. The fractions of <i>V</i>. <i>gardneriana</i>, and also squalene, caused mortality to <i>A</i>. <i>guerreronis</i>. The potential of <i>V</i>. <i>gardneriana</i> fractions/squalene as biopesticides for controlling <i>A</i>. <i>guerreronis</i> in coconut plantations </span><span style="font-family:;" "="">is</span><span style="font-family:;" "=""> discussed herein.</span>展开更多
Peat remains the primary constituent of horticultural growing media in professional use.However,use of peat in horticultural growing media results in greenhouse gas emissions and biodiversity loss due to excavation of...Peat remains the primary constituent of horticultural growing media in professional use.However,use of peat in horticultural growing media results in greenhouse gas emissions and biodiversity loss due to excavation of natural peatlands.Biochar is gaining attention as a sustainable alternative to peat use in horticulture.This study examined the potential of biochar produced from a particular type of sawmill residue,as a partial replacement for peat in horticultural growing media.Five treatments including peat only,biochar only,biochar and peat in 1:1,1:3,and 3:1(V/V)ratios were assessed.The addition of biochar into growing media increased the pH and EC of the medium.However,physical properties(air-filled porosity and water holding capacity)were negatively affected with the increase in biochar content in the medium.According to the germination test results,biochar significantly improved germination and the shoot and root length of germinated seeds of cress,lettuce and tomato when compared to peat-only and biochar-only treatments.The inclusion of biochar in 25-50%volume ratio improved plant growth parameters compared to peat-only and biochar-only media.Results obtained from this study suggest that sawmill residue offers great potential as a feedstock for biochar production and inclusion of biochar has positive effects on seed germination and plant growth that might compete with modified peat.展开更多
基金This work was supported by the Key Research and Development Project of Jiangsu Province(BE2019009-4)the National Natural Science Foundation of China(52106091)the Qing Lan Project of Jiangsu Province。
文摘Microalgae biomass is an ideal precursor to prepare renewable carbon materials,which has broad application.The bioaccumulation efficiency(lipids,proteins,carbohydrates)and biomass productivity of microalgae are influenced by spectroscopy during the culture process.In this study,a bilayer plate-type photobioreactor was designed to cultivate Chlorella protothecoides with spectral selectivity by nanofluids.Compared to culture without spectral selectivity,the spectral selectivity of Ag/CoSO_(4)nanofluids increased microalgae biomass by 5.76%,and the spectral selectivity of CoSO_(4)solution increased by 17.14%.In addition,the spectral selectivity of Ag/CoSO_(4)nanofluids was more conducive to the accumulation of nutrients(29.46%lipids,50.66%proteins,and 17.86%carbohydrates)in microalgae.Further cultured chlorella was utilized to prepare bioelectrode materials,it was found that algal based biochar had a good pore structure(micro specific surface area:1627.5314 m^(2)/g,average pore size:0.21294 nm).As the current density was 1 A/g,the specific capacitance reached 230 F/g,appearing good electrochemical performance.
基金The paper was supported by the Natural Science Foundation of China(No.51906112)Natural Science Foundation of Jiangsu Province(No.BK20180548)+1 种基金China Postdoctoral Science Foundation(2019M651852)“Innovation&Entrepreneurship Talents”Introduction Plan of Jiangsu Province.
文摘In this paper,CaO/bio-char was synthesized by directly co-pyrolysis of Ca(OH)_(2) and rice straw,and used as catalyst to catalytic pyrolysis of soybean oil to produce high quality biofuel.In this co-pyrolysis process,CaO particles has been successfully embedded on the bio-char surface.During the catalytic pyrolysis process,CaO/biochar showed a good catalytic performance on the deoxygenation of soybean oil.Pyrolysis temperature affected the pyrolysis reactions and pyrolytic products distributions dramatically,higher pyrolysis temperature lead to seriously cracking reactions,lower bio-oil yield and higher gases yield,and lower pyrolysis temperature lead to higher bio-oil yield with higher oxygenated compounds content and lower hydrocarbons contents,the suitable pyrolysis temperature was around 650℃.Under the optimal conditions(650℃ with WHSV at 6.4 h^(−1) and carrier gas flow rate at 100 ml/min),the selectivity(%)of hydrocarbons in the bio-oil was more than 90%.CaO/bio-char catalyst still shows good catalytic deoxygenation activity after 4 cycles.1 g of CaO/bio-char catalyst can catalyze pyrolysis of 32 g of soybean oil to produce high-quality liquid fuel.Bio-char based catalyst has been proved to be a promising catalyst for catalytic conversion of triglyceride-based lipids into high quality liquid biofuel.
文摘The coconut mite, <i>Aceria</i> <i>guerreronis</i> Keifer (Acari: Eriophyidae), is a major pest of coconut plantations (<i>Cocos</i> <i>nucifera</i> L.) worldwide. Here, we conducted a bioguided<span style="font-family:;" "=""> </span><span style="font-family:;" "="">phytochemical approach using toxicity and repellency bioassays of nonpolar extract and its fractions of <i>Vitex</i> <i>gardneriana</i> Schauer (Lamiaceae) leaves to this pest. Nonpolar crude extract was fractionated by column chromatography using solvents with increased polarity and binary mixtures, resulting in five semipurified groups. The biomonitor</span><span style="font-family:;" "="">ing</span><span style="font-family:;" "=""> bioassay provided active fractions and led to the isolation and characterization of the <span>bioactive compound squalene, a biosynthetic precursor of 20-hydroxyecdysone,</span> which plays an important role in plant defense against arthropods. The LC<sub>50</sub> of the crude extract of <i>V</i>. <i>gardneriana</i> for <i>A</i>. <i>guerreronis</i> was estimated to be 0.185 mg·mL<sup>-1</sup> and LC<sub>80</sub> = 4.123 mg·mL<sup>-1</sup>. Also, the extract was highly repellent to this pest for up to 24 h. The fractions of <i>V</i>. <i>gardneriana</i>, and also squalene, caused mortality to <i>A</i>. <i>guerreronis</i>. The potential of <i>V</i>. <i>gardneriana</i> fractions/squalene as biopesticides for controlling <i>A</i>. <i>guerreronis</i> in coconut plantations </span><span style="font-family:;" "="">is</span><span style="font-family:;" "=""> discussed herein.</span>
基金support from the European Union Horizon 2020 Research and Innovative Training Network program under the Marie Sklodowska-Curie grant agreement No 721991In the UK,H.Creber received financial support from the E4 Doctoral Training Partnership of the Natural Environment Research Council and from Forest Research。
文摘Peat remains the primary constituent of horticultural growing media in professional use.However,use of peat in horticultural growing media results in greenhouse gas emissions and biodiversity loss due to excavation of natural peatlands.Biochar is gaining attention as a sustainable alternative to peat use in horticulture.This study examined the potential of biochar produced from a particular type of sawmill residue,as a partial replacement for peat in horticultural growing media.Five treatments including peat only,biochar only,biochar and peat in 1:1,1:3,and 3:1(V/V)ratios were assessed.The addition of biochar into growing media increased the pH and EC of the medium.However,physical properties(air-filled porosity and water holding capacity)were negatively affected with the increase in biochar content in the medium.According to the germination test results,biochar significantly improved germination and the shoot and root length of germinated seeds of cress,lettuce and tomato when compared to peat-only and biochar-only treatments.The inclusion of biochar in 25-50%volume ratio improved plant growth parameters compared to peat-only and biochar-only media.Results obtained from this study suggest that sawmill residue offers great potential as a feedstock for biochar production and inclusion of biochar has positive effects on seed germination and plant growth that might compete with modified peat.