Poly[bis(phenoxyphosphazene)](PBPP) and magnesium hydroxide(MH) are used as a flame retardant blend with low-density polyethylene(LDPE) for the nuclear cable. This study aims to investigate the effects of PBPP in MH-L...Poly[bis(phenoxyphosphazene)](PBPP) and magnesium hydroxide(MH) are used as a flame retardant blend with low-density polyethylene(LDPE) for the nuclear cable. This study aims to investigate the effects of PBPP in MH-LDPE blend composites on flame retardance and electron beam irradiation. The structure, morphology,and properties of the blend composites irradiated by an electron beam to different absorbed doses were characterized. The results indicated that PBPP provides lubrication during processing. As the PBPP content in the blend increases the melt flow rate at 20 phr MH, meaning the material is easier to process. The higher the PBPP content, the higher the limiting-oxygen index. The elongation at the break of the PBPP containing composites(at 50 phr MH) was evidently higher than the non-PBPP ones at different absorbed doses by electron beam irradiation. The thermogravimetric analysis results indicated that the improved mechanical property, resulting from electron-beam irradiation, could be attributed to the consumption of PBPP.展开更多
Gamma-ray irradiation technique is an effective method for preparing graphene aerogel(GA).The effective reduction and self-assembly of graphene oxide(GO) sheets into 3D porous GA in ethylenediamine(EDA) aqueous soluti...Gamma-ray irradiation technique is an effective method for preparing graphene aerogel(GA).The effective reduction and self-assembly of graphene oxide(GO) sheets into 3D porous GA in ethylenediamine(EDA) aqueous solution under the protection of nitrogen have been achieved via γ-ray irradiation.The reduction degree and self-assembly process,which can be controlled by varying EDA dose and irradiation dose,are investigated by X-ray photoelectron spectroscopy,Fourier transform infrared spectroscopy,X-ray diffractometer,and thermogravimetric analysis.A reduction mechanism is proposed for interactions among EDA molecules,active radicals from the radiolysis of water,and oxygen-containing groups on GO sheets.展开更多
基金Supported by the"Strategic Priority Research Program"of the Chinese Academy of Sciences(No.XDA02040300)
文摘Poly[bis(phenoxyphosphazene)](PBPP) and magnesium hydroxide(MH) are used as a flame retardant blend with low-density polyethylene(LDPE) for the nuclear cable. This study aims to investigate the effects of PBPP in MH-LDPE blend composites on flame retardance and electron beam irradiation. The structure, morphology,and properties of the blend composites irradiated by an electron beam to different absorbed doses were characterized. The results indicated that PBPP provides lubrication during processing. As the PBPP content in the blend increases the melt flow rate at 20 phr MH, meaning the material is easier to process. The higher the PBPP content, the higher the limiting-oxygen index. The elongation at the break of the PBPP containing composites(at 50 phr MH) was evidently higher than the non-PBPP ones at different absorbed doses by electron beam irradiation. The thermogravimetric analysis results indicated that the improved mechanical property, resulting from electron-beam irradiation, could be attributed to the consumption of PBPP.
基金supported by the National Natural Science Foundation of China(No.11505270)Shanghai Municipal Commission for Science and Technology(No.15ZR1448300)
文摘Gamma-ray irradiation technique is an effective method for preparing graphene aerogel(GA).The effective reduction and self-assembly of graphene oxide(GO) sheets into 3D porous GA in ethylenediamine(EDA) aqueous solution under the protection of nitrogen have been achieved via γ-ray irradiation.The reduction degree and self-assembly process,which can be controlled by varying EDA dose and irradiation dose,are investigated by X-ray photoelectron spectroscopy,Fourier transform infrared spectroscopy,X-ray diffractometer,and thermogravimetric analysis.A reduction mechanism is proposed for interactions among EDA molecules,active radicals from the radiolysis of water,and oxygen-containing groups on GO sheets.
