The effect of impurity-induced interchain coupling on polaron in halogen-bridged mixed-valence plattinum complexes(HMPGs)[Pt(en)_(2)][Pt(en)_(2)X_(2)](ClO_(4))_(4) are studied by means of the lakayama,Lin-liu and Maki...The effect of impurity-induced interchain coupling on polaron in halogen-bridged mixed-valence plattinum complexes(HMPGs)[Pt(en)_(2)][Pt(en)_(2)X_(2)](ClO_(4))_(4) are studied by means of the lakayama,Lin-liu and Maki continuum model.The Greenfs function is used to calculate the change of polaronic bind-ing energy due to existing impurity.The results were supported by halogen doping experiment in HMPC's.展开更多
基金Supported by the National Natural Science Foundation of China.
文摘The effect of impurity-induced interchain coupling on polaron in halogen-bridged mixed-valence plattinum complexes(HMPGs)[Pt(en)_(2)][Pt(en)_(2)X_(2)](ClO_(4))_(4) are studied by means of the lakayama,Lin-liu and Maki continuum model.The Greenfs function is used to calculate the change of polaronic bind-ing energy due to existing impurity.The results were supported by halogen doping experiment in HMPC's.