of main observation and conclusion An enantioselective deoxygenative cyanation of benzyl alcohols was accomplished for the first time through the synergistic photoredox and copper catalysis.This reaction features the ...of main observation and conclusion An enantioselective deoxygenative cyanation of benzyl alcohols was accomplished for the first time through the synergistic photoredox and copper catalysis.This reaction features the use of organic photosensitizer and low-cost 3d metal catalyst,simple and safe operations,and extremely mild conditions.A variety of chiral benzyl nitriles were produced in generally good yields and high level of enantiocontrols from readily available feedstocks(22 examples,up to 93%yield and 92%ee).展开更多
基金We are grateful to the National Natural Science Foundation ofChina(Nos.21901080,21822103,21820102003 and 91956201)the Program of Introducing Talents of Discipline to Universities ofChina(111 Program,B17019)+1 种基金the Natural Science Foundation ofHubei Province(2017AHB047)the International Joint Re-search Center for intelligent Biosensing Technology and Health forsupport of this research.
文摘of main observation and conclusion An enantioselective deoxygenative cyanation of benzyl alcohols was accomplished for the first time through the synergistic photoredox and copper catalysis.This reaction features the use of organic photosensitizer and low-cost 3d metal catalyst,simple and safe operations,and extremely mild conditions.A variety of chiral benzyl nitriles were produced in generally good yields and high level of enantiocontrols from readily available feedstocks(22 examples,up to 93%yield and 92%ee).
