2004年7月16日至18日'2004地板企业联盟(CFA)高峰会议'(以下简称 CFA 会)在美丽的大连市棒棰岛国宾馆举行。参会者共34人,几乎全部 CFA 创始成员的领导皆参加了峰会,此外国家人造板质量监督检验中心许文,法律顾问郭凤武主任律师...2004年7月16日至18日'2004地板企业联盟(CFA)高峰会议'(以下简称 CFA 会)在美丽的大连市棒棰岛国宾馆举行。参会者共34人,几乎全部 CFA 创始成员的领导皆参加了峰会,此外国家人造板质量监督检验中心许文,法律顾问郭凤武主任律师,以及深圳贝辉木业有限公司,夏特装饰材料(上海)有限公司的领导等嘉宾出席了会议。会议得到了海帝木业(天津)有限公司领导的大力支持,与会代表对海帝木业(天津)有限公司为大会所做的工作和服务皆表示十分满意,并表示衷心的感谢!CFA 本届联盟主席王启富先生向大会作了工作述职报告和财务报告,秘书长高志华教授作了工作报告,均得到大会的肯定。联盟成员对王主席及秘书处的工作表示了肯定,认为在王启富先生的带领下,经过联盟成员的共同努力,CFA 的工作向前迈进了一大步,在会议上联盟主席王启富先生还向联盟创始成员颁发了铜匾。展开更多
In France,the field of lifelong learning has undergone many changes since 2014 according to the laws that have been promulgated[Law No.2014-288 of 5 March 2014 on vocational training,employment and social democracy ht...In France,the field of lifelong learning has undergone many changes since 2014 according to the laws that have been promulgated[Law No.2014-288 of 5 March 2014 on vocational training,employment and social democracy https://www.legifrance.gouv.fr/affichTexte.do?cidTexte=-JORFTEXT000028683576&categorieLien=id;Law n°2018-771 of September 5,2018 for the freedom to choose one's professional future https://www.legifrance.gouv.fr/affichTexte.do?cidTexte=JORFTEXT000037367660&categorieLien=id.].While the reform on vocational training for employment and social democracy finalized the decentralization of vocational training by giving regions the means for a more coherent action and placed them as a pilot for the construction of training policies,the recent law for the freedom to choose one's professional future recentralises the regulation of continuing vocational training and sandwich courses.This development will not fail to impact the governance of the CFA,especially those of Higher Education anchored in the small territories.Faced with this major structural issue in the specific context of a small island economy,the University Center for Apprenticeship Training in the Corsican region strives,for a decade,to contribute to the enhancement of the professional integration of work-study students from the University of Corsica,by the development and the durability of determining factors characteristic of a small territorial area in search of structuration[Specially:increased employability and quality of professional integration of its human capital,demonstrated growth in the level of skills acquisition in line with the needs expressed by local socio-economic actors,transfer of relevant knowledge through the learning process,active incentive to entrepreneurial capacity.].After having highlighted the qualitative results resulting from the activity dynamics of the CFA University in Corsica,this contribution will analyze the perspectives drawn from the exemplary nature of the latter in the context of a new law that is supposed to contribute to the regional structuring of a knowledge and competence economy.展开更多
The COVID-19 pandemic has generated major economic impacts in the vast majority of countries,including falling GDP and global trade,massive job losses,deficits and increased public debt.If quasi-generalized interventi...The COVID-19 pandemic has generated major economic impacts in the vast majority of countries,including falling GDP and global trade,massive job losses,deficits and increased public debt.If quasi-generalized interventionist economic policies have made it possible to cushion the paralysis of the productive devices,the short-term global outlook remains very uncertain.In this gloomy context,what will be the situation on the labour market,and in particular the vocational integration of students?Corsica presents the example of a small island territory in search of a regional development scheme based on the economy of knowledge and competence.In this major structural perspective,the University Apprenticeship Training Centre(CFA UNIV)in the Corsican region has been striving,for a decade,to contribute to the enhancement of studentsapprentices vocational integration from the University of Corsica.Within the scope of its activities,are the monitoring and evaluation of the students-apprentices’professional integration from the University of Corsica.Since 2011,the carrying out the annual surveys on studentsapprentices’future from the University of Corsica has demonstrated the capacity of the sandwich course training in Higher Education simultaneously to boost the employability of skilled human capital and the growth of local business structuring.This contribution will aim to synthesize ten years of CFA UNIV experience and will endeavour to analyse the localized consequences of a global pandemic crisis on the nature of the vocational integration studentapprentices from the University of Corsica in a small territory island.展开更多
Potassium-ion batteries(PIBs)have been considered as promising candidates in the post-lithium-ion battery era.Till now,a large number of materials have been used as electrode materials for PIBs,among which vanadium ox...Potassium-ion batteries(PIBs)have been considered as promising candidates in the post-lithium-ion battery era.Till now,a large number of materials have been used as electrode materials for PIBs,among which vanadium oxides exhibit great potentiality.Vanadium oxides can provide multiple electron transfers during electrochemical reactions because vanadium possesses a variety of oxidation states.Meanwhile,their relatively low cost and superior material,structural,and physicochemical properties endow them with strong competitiveness.Although some inspiring research results have been achieved,many issues and challenges remain to be further addressed.Herein,we systematically summarize the research progress of vanadium oxides for PIBs.Then,feasible improvement strategies for the material properties and electrochemical performance are introduced.Finally,the existing challenges and perspectives are discussed with a view to promoting the development of vanadium oxides and accelerating their practical applications.展开更多
Electrochemical capacitors(ECs)with unique merits of fast charge/discharge rate and long cyclability are one of the representative electrochemical energy storage systems,possessing wide applications in power electroni...Electrochemical capacitors(ECs)with unique merits of fast charge/discharge rate and long cyclability are one of the representative electrochemical energy storage systems,possessing wide applications in power electronics and automotive transportation,etc.[1,2].Furthermore.展开更多
Ethyl cellulose(EC),an important biomass-based material,has excellent film-forming properties.Nevertheless,the high interchain hydrogen bond interaction leads to a high glass transition temperature of EC,which makes i...Ethyl cellulose(EC),an important biomass-based material,has excellent film-forming properties.Nevertheless,the high interchain hydrogen bond interaction leads to a high glass transition temperature of EC,which makes it too brittle to be used widely.The hydroxyl group on EC can form a supramolecular system in the form of a non-covalent bond with an effective plasticizer.In this study,an important vegetable-oil-based derivative named dimer fatty acid was used to prepare a novel special plasticizer for EC.Dimer-fatty-acid-based thioether polyol(DATP)was synthesized and used to modify ethyl cellulose films.The supramolecular composite films of DATP and ethyl cellulose were designed using the newly-formed van der Waals force.The thermal stability,morphology,hydrophilicity,and mechanical properties of the composite films were all tested.Pure EC is fragile,and the addition of DATP makes the ethyl cellulose films more flexible.The elongation at the break of EC supramolecular films increased and the tensile strength decreased with the increasing DATP content.The elongation at the break of EC/DATP(60/40)and EC/DATP(50/50)was up to 40.3%and 43.4%,respectively.Noticeably,the thermal initial degradation temperature of the film with 10%DATP is higher than that of pure EC,which may be attributed to the formation of a better supramolecular system in this composite film.The application of bio-based material(EC)is environmentally friendly,and the novel DATP can be used as a special and effective plasticizer to prepare flexible EC films,making it more widely used in energy,chemical industry,materials,agriculture,medicine,and other fields.展开更多
Purpose: The aim of the present study was to investigate whether street basketball organized as 3 v 3 on either a half court(HC) with 1 basket or a full court(FC) with 2 baskets could improve fitness and health profil...Purpose: The aim of the present study was to investigate whether street basketball organized as 3 v 3 on either a half court(HC) with 1 basket or a full court(FC) with 2 baskets could improve fitness and health profiles of untrained men after 3 months of supervised training.Methods: Thirty-five untrained men(aged 20—42 years) completed the pre-and post-intervention testing(FC: n = 13, HC: n = 12, CO(control):n = 10). The training attendance was 2.0 ± 0.4 and 1.9 ± 0.3 times per week in FC and HC, respectively. Mean heart rate(HR) was 83.8 ± 6.0 percent of maximal heart rate(%HR_(max)) and 84.5 ± 2.9 %HR_(max) in FC and HC, respectively.Results: The 3 months of street basketball training on an FC with 2 baskets increased maximal oxygen uptake(2.4 mL/min/kg(95% confidence interval(CI): 1.0—3.9)), time to exhaustion(47 s(95%CI: 26—67)), lean body mass(0.8 kg(95%CI: 0.1—1.5)), and bone mineral density(0.021 g/cm^2(95%CI: 0.011—0.031)), whereas mean arterial pressure(—5.6 mm Hg(95%CI: —7.5 to 3.7)), body fat percentage(—1.6%,(95%CI: —2.5 to —0.7)), heart rate(—18 bpm(95%CI: —24 to —12)), and blood lactate(median: —1.4 mmol/L(interquartile range: —1.5 to —0.6)) during submaximal running were lowered. The changes were less pronounced after the training period when playing on an HC with 1 basket, but increases in maximal oxygen uptake(1.6 mL/min/kg(95%CI: —0.1 to 3.3)), time to exhaustion(28 s(95%CI: 9—47)), lean body mass(1.3 kg(95%CI: 0.3—2.4)), and lower body fat percentage(—0.9%(95%CI: —1.9 to —0.1)) were observed in this group.Conclusion: Three months of 3 v 3 street basketball training improved fitness and led to broad-spectrum improvements in variables related to overall health profile, with the most marked effects observed when playing on an FC with 2 baskets.展开更多
With the increasing demand for large-scale battery systems in electric vehicles（EVs） and smart renewable energy grids, organic materials including small molecules and polymers utilized as electrodes in rechargeable ...With the increasing demand for large-scale battery systems in electric vehicles（EVs） and smart renewable energy grids, organic materials including small molecules and polymers utilized as electrodes in rechargeable batteries have received increasing attraction. In recent years, two-dimensional（2D） organic materials possessing planar layered architecture exhibit optional chemical modification, high specific surface area as well as unique electrical/magnetic properties, which have been emerging as the promising functional materials for wide applications in optoelectronics, catalysis, sensing, etc. Integrating with high-density redox-active sites and hierarchical porous structure, significant achievements in 2D organic materials as cathode materials for alkali-metal-ion batteries have been witnessed. In this review, the recent progress in synthetic approaches, structure analyses, electrochemical characterizations of 2D organic materials as well as their application in alkali-metal-ion batteries containing lithium ion battery（LIB）, lithium sulfur battery（LSB）, lithium air battery（LAB） and sodium ion battery（SIB） are summarized systematically,and their current challenges including cycling stability and electron conductivity for cathode materials in battery fields are also discussed.展开更多
Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in m...Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in materials with limited diversity and complexity in architecture as well as microstructure.Here,we develop a novel coordination polymerization-driven hierarchical assembly of micelle strategy,using phytic acid-based natural compounds as an example,for the spatially controlled fabrication of metal coordination bio-derived polymers.The resultant ferric phytate polymer nanospheres feature hollow architecture,ordered meso-channels of^12 nm,high surface area of 401 m2 g−1,and large pore volume of 0.53 cm3 g−1.As an advanced anode material,this bio-derivative polymer delivers a remarkable reversible capacity of 540 mAh g−1 at 50 mA g−1,good rate capability,and cycling stability for sodium-ion batteries.This study holds great potential of the design of new complex bio-materials with supramolecular chemistry.展开更多
Catalytic reduction of molecular dinitrogen(N_(2))to ammonia(NH_(3))is one of the most important and challenging industrial reactions.Electrochemical reduction is considered as an energy-saving technology for artifici...Catalytic reduction of molecular dinitrogen(N_(2))to ammonia(NH_(3))is one of the most important and challenging industrial reactions.Electrochemical reduction is considered as an energy-saving technology for artificial ambient nitrogen fixation,which is emerging as an optimal potential sustainable strategy to substitute for the Haber–Bosch process.However,this process demands efficient catalysts for the N_(2)reduction reaction(NRR).Here,by means of first-principles calculations,we systematically explored the potential electrocatalytic performance of single transition metal atoms(Pd,Ag,Rh,Cu,Ti,Mo,Mn,Zn,Fe,Co,Ru,and Pt)embedded in monolayer defective boron phosphide(TMs/BP)monolayer with a phosphorus monovacancy for ambient NH_(3)production.Among them,the Mo/BP exhibits the best catalytic performance for ambient reduction of N_(2)through the typical enzymatic and consecutive reaction pathways with an activation barrier of 0.68 e V,indicating that Mo/BP is an efficient catalyst for N_(2)fixation.We believe that this work could provide a new avenue of ambient NH_(3)synthesis by using the designed single-atom electrocatalysts.展开更多
文摘2004年7月16日至18日'2004地板企业联盟(CFA)高峰会议'(以下简称 CFA 会)在美丽的大连市棒棰岛国宾馆举行。参会者共34人,几乎全部 CFA 创始成员的领导皆参加了峰会,此外国家人造板质量监督检验中心许文,法律顾问郭凤武主任律师,以及深圳贝辉木业有限公司,夏特装饰材料(上海)有限公司的领导等嘉宾出席了会议。会议得到了海帝木业(天津)有限公司领导的大力支持,与会代表对海帝木业(天津)有限公司为大会所做的工作和服务皆表示十分满意,并表示衷心的感谢!CFA 本届联盟主席王启富先生向大会作了工作述职报告和财务报告,秘书长高志华教授作了工作报告,均得到大会的肯定。联盟成员对王主席及秘书处的工作表示了肯定,认为在王启富先生的带领下,经过联盟成员的共同努力,CFA 的工作向前迈进了一大步,在会议上联盟主席王启富先生还向联盟创始成员颁发了铜匾。
文摘In France,the field of lifelong learning has undergone many changes since 2014 according to the laws that have been promulgated[Law No.2014-288 of 5 March 2014 on vocational training,employment and social democracy https://www.legifrance.gouv.fr/affichTexte.do?cidTexte=-JORFTEXT000028683576&categorieLien=id;Law n°2018-771 of September 5,2018 for the freedom to choose one's professional future https://www.legifrance.gouv.fr/affichTexte.do?cidTexte=JORFTEXT000037367660&categorieLien=id.].While the reform on vocational training for employment and social democracy finalized the decentralization of vocational training by giving regions the means for a more coherent action and placed them as a pilot for the construction of training policies,the recent law for the freedom to choose one's professional future recentralises the regulation of continuing vocational training and sandwich courses.This development will not fail to impact the governance of the CFA,especially those of Higher Education anchored in the small territories.Faced with this major structural issue in the specific context of a small island economy,the University Center for Apprenticeship Training in the Corsican region strives,for a decade,to contribute to the enhancement of the professional integration of work-study students from the University of Corsica,by the development and the durability of determining factors characteristic of a small territorial area in search of structuration[Specially:increased employability and quality of professional integration of its human capital,demonstrated growth in the level of skills acquisition in line with the needs expressed by local socio-economic actors,transfer of relevant knowledge through the learning process,active incentive to entrepreneurial capacity.].After having highlighted the qualitative results resulting from the activity dynamics of the CFA University in Corsica,this contribution will analyze the perspectives drawn from the exemplary nature of the latter in the context of a new law that is supposed to contribute to the regional structuring of a knowledge and competence economy.
文摘The COVID-19 pandemic has generated major economic impacts in the vast majority of countries,including falling GDP and global trade,massive job losses,deficits and increased public debt.If quasi-generalized interventionist economic policies have made it possible to cushion the paralysis of the productive devices,the short-term global outlook remains very uncertain.In this gloomy context,what will be the situation on the labour market,and in particular the vocational integration of students?Corsica presents the example of a small island territory in search of a regional development scheme based on the economy of knowledge and competence.In this major structural perspective,the University Apprenticeship Training Centre(CFA UNIV)in the Corsican region has been striving,for a decade,to contribute to the enhancement of studentsapprentices vocational integration from the University of Corsica.Within the scope of its activities,are the monitoring and evaluation of the students-apprentices’professional integration from the University of Corsica.Since 2011,the carrying out the annual surveys on studentsapprentices’future from the University of Corsica has demonstrated the capacity of the sandwich course training in Higher Education simultaneously to boost the employability of skilled human capital and the growth of local business structuring.This contribution will aim to synthesize ten years of CFA UNIV experience and will endeavour to analyse the localized consequences of a global pandemic crisis on the nature of the vocational integration studentapprentices from the University of Corsica in a small territory island.
基金the Shenyang University of Technology(QNPY202209-4)the Key R&D project of Liaoning Province of China(2020JH2/10300079)+2 种基金the“Liaoning BaiQianWan Talents Program”(2018921006)the Liaoning Revitalization Talents Program(XLYC1908034)the National Natural Science Foundation of China(21571132).
文摘Potassium-ion batteries(PIBs)have been considered as promising candidates in the post-lithium-ion battery era.Till now,a large number of materials have been used as electrode materials for PIBs,among which vanadium oxides exhibit great potentiality.Vanadium oxides can provide multiple electron transfers during electrochemical reactions because vanadium possesses a variety of oxidation states.Meanwhile,their relatively low cost and superior material,structural,and physicochemical properties endow them with strong competitiveness.Although some inspiring research results have been achieved,many issues and challenges remain to be further addressed.Herein,we systematically summarize the research progress of vanadium oxides for PIBs.Then,feasible improvement strategies for the material properties and electrochemical performance are introduced.Finally,the existing challenges and perspectives are discussed with a view to promoting the development of vanadium oxides and accelerating their practical applications.
基金financially supported by the National Natural Science Foundation of China(22125903,51872283,22005298)。
文摘Electrochemical capacitors(ECs)with unique merits of fast charge/discharge rate and long cyclability are one of the representative electrochemical energy storage systems,possessing wide applications in power electronics and automotive transportation,etc.[1,2].Furthermore.
基金supported by Jiangsu Province Biomass Energy and Materials Laboratory,China(Grant No.JSBEM-S-202007).
文摘Ethyl cellulose(EC),an important biomass-based material,has excellent film-forming properties.Nevertheless,the high interchain hydrogen bond interaction leads to a high glass transition temperature of EC,which makes it too brittle to be used widely.The hydroxyl group on EC can form a supramolecular system in the form of a non-covalent bond with an effective plasticizer.In this study,an important vegetable-oil-based derivative named dimer fatty acid was used to prepare a novel special plasticizer for EC.Dimer-fatty-acid-based thioether polyol(DATP)was synthesized and used to modify ethyl cellulose films.The supramolecular composite films of DATP and ethyl cellulose were designed using the newly-formed van der Waals force.The thermal stability,morphology,hydrophilicity,and mechanical properties of the composite films were all tested.Pure EC is fragile,and the addition of DATP makes the ethyl cellulose films more flexible.The elongation at the break of EC supramolecular films increased and the tensile strength decreased with the increasing DATP content.The elongation at the break of EC/DATP(60/40)and EC/DATP(50/50)was up to 40.3%and 43.4%,respectively.Noticeably,the thermal initial degradation temperature of the film with 10%DATP is higher than that of pure EC,which may be attributed to the formation of a better supramolecular system in this composite film.The application of bio-based material(EC)is environmentally friendly,and the novel DATP can be used as a special and effective plasticizer to prepare flexible EC films,making it more widely used in energy,chemical industry,materials,agriculture,medicine,and other fields.
文摘Purpose: The aim of the present study was to investigate whether street basketball organized as 3 v 3 on either a half court(HC) with 1 basket or a full court(FC) with 2 baskets could improve fitness and health profiles of untrained men after 3 months of supervised training.Methods: Thirty-five untrained men(aged 20—42 years) completed the pre-and post-intervention testing(FC: n = 13, HC: n = 12, CO(control):n = 10). The training attendance was 2.0 ± 0.4 and 1.9 ± 0.3 times per week in FC and HC, respectively. Mean heart rate(HR) was 83.8 ± 6.0 percent of maximal heart rate(%HR_(max)) and 84.5 ± 2.9 %HR_(max) in FC and HC, respectively.Results: The 3 months of street basketball training on an FC with 2 baskets increased maximal oxygen uptake(2.4 mL/min/kg(95% confidence interval(CI): 1.0—3.9)), time to exhaustion(47 s(95%CI: 26—67)), lean body mass(0.8 kg(95%CI: 0.1—1.5)), and bone mineral density(0.021 g/cm^2(95%CI: 0.011—0.031)), whereas mean arterial pressure(—5.6 mm Hg(95%CI: —7.5 to 3.7)), body fat percentage(—1.6%,(95%CI: —2.5 to —0.7)), heart rate(—18 bpm(95%CI: —24 to —12)), and blood lactate(median: —1.4 mmol/L(interquartile range: —1.5 to —0.6)) during submaximal running were lowered. The changes were less pronounced after the training period when playing on an HC with 1 basket, but increases in maximal oxygen uptake(1.6 mL/min/kg(95%CI: —0.1 to 3.3)), time to exhaustion(28 s(95%CI: 9—47)), lean body mass(1.3 kg(95%CI: 0.3—2.4)), and lower body fat percentage(—0.9%(95%CI: —1.9 to —0.1)) were observed in this group.Conclusion: Three months of 3 v 3 street basketball training improved fitness and led to broad-spectrum improvements in variables related to overall health profile, with the most marked effects observed when playing on an FC with 2 baskets.
基金the financial support from the 973 Programs of China(2013CBA01602)NSFC for Excellent Youth Scholars(51722304)+4 种基金NSFC(21720102002,21574080 and 61306018)Shanghai Committee of Science and Technology(15JC1490500,16JC1400703)and Open Project Program of the State Key Laboratory of Supramolecular Structure and Materials(sklssm201732,Jilin University)State Key Laboratory of Inorganic Synthesis and Preparative Chemistry(2016-08,Jilin University)State Key Laboratory for Mechanical Behavior of Materials(20161803,Xi’an Jiaotong University)
文摘With the increasing demand for large-scale battery systems in electric vehicles（EVs） and smart renewable energy grids, organic materials including small molecules and polymers utilized as electrodes in rechargeable batteries have received increasing attraction. In recent years, two-dimensional（2D） organic materials possessing planar layered architecture exhibit optional chemical modification, high specific surface area as well as unique electrical/magnetic properties, which have been emerging as the promising functional materials for wide applications in optoelectronics, catalysis, sensing, etc. Integrating with high-density redox-active sites and hierarchical porous structure, significant achievements in 2D organic materials as cathode materials for alkali-metal-ion batteries have been witnessed. In this review, the recent progress in synthetic approaches, structure analyses, electrochemical characterizations of 2D organic materials as well as their application in alkali-metal-ion batteries containing lithium ion battery（LIB）, lithium sulfur battery（LSB）, lithium air battery（LAB） and sodium ion battery（SIB） are summarized systematically,and their current challenges including cycling stability and electron conductivity for cathode materials in battery fields are also discussed.
基金financially supported by the Natural Science Foundation of China (Grant Nos.51773062 and 61831021)
文摘Bio-inspired hierarchical self-assembly provides elegant and powerful bottom-up strategies for the creation of complex materials.However,the current self-assembly approaches for natural bio-compounds often result in materials with limited diversity and complexity in architecture as well as microstructure.Here,we develop a novel coordination polymerization-driven hierarchical assembly of micelle strategy,using phytic acid-based natural compounds as an example,for the spatially controlled fabrication of metal coordination bio-derived polymers.The resultant ferric phytate polymer nanospheres feature hollow architecture,ordered meso-channels of^12 nm,high surface area of 401 m2 g−1,and large pore volume of 0.53 cm3 g−1.As an advanced anode material,this bio-derivative polymer delivers a remarkable reversible capacity of 540 mAh g−1 at 50 mA g−1,good rate capability,and cycling stability for sodium-ion batteries.This study holds great potential of the design of new complex bio-materials with supramolecular chemistry.
基金supported by the National Natural Science Foundation of China(51425301,U1601214,51573013,51773092 and 51772147,21475041,21675050,20405142,21305041)Research Foundation of State Key Lab(ZK201805)the Hunan Provincial Innovation Foundation for Postgraduate(Grant No.CX2018B294)
文摘Catalytic reduction of molecular dinitrogen(N_(2))to ammonia(NH_(3))is one of the most important and challenging industrial reactions.Electrochemical reduction is considered as an energy-saving technology for artificial ambient nitrogen fixation,which is emerging as an optimal potential sustainable strategy to substitute for the Haber–Bosch process.However,this process demands efficient catalysts for the N_(2)reduction reaction(NRR).Here,by means of first-principles calculations,we systematically explored the potential electrocatalytic performance of single transition metal atoms(Pd,Ag,Rh,Cu,Ti,Mo,Mn,Zn,Fe,Co,Ru,and Pt)embedded in monolayer defective boron phosphide(TMs/BP)monolayer with a phosphorus monovacancy for ambient NH_(3)production.Among them,the Mo/BP exhibits the best catalytic performance for ambient reduction of N_(2)through the typical enzymatic and consecutive reaction pathways with an activation barrier of 0.68 e V,indicating that Mo/BP is an efficient catalyst for N_(2)fixation.We believe that this work could provide a new avenue of ambient NH_(3)synthesis by using the designed single-atom electrocatalysts.
