Characteristics and applications of gas desorption with excavation disturbances in coal mining

According to the deficiency of experiment system for gas adsorption and desorption in coal mass, a large scale experiment system is developed independently by researchers. This experiment system is composed of primary and auxiliary boxes, power transmission system, mining system, loading system, gas charging system, data monitoring and intelligent acquisition system. The maximum experiment coal consumption is 1200 kg, the mining system is developed to conduct experiment for gas desorption under excavating disturbance, and the plane-charging cribriform ventilation device is developed to realize uniform ventilation for experiment coal sample, which is accord with the actual gas source situation of coal bed. The desorption characteristics of gas in coal are experimentally studied under the conditions of nature and mining using the experiment system. The results show that, compare with nature condition, the permeability of coal and the velocity of gas desorption could significantly increase under the influence of coal pressure relief and destruction caused by mining, and the degree of gas desorption could somewhat increase too. Finally, pressure relief gas extraction of current seam and adjacent seams after mining in a certain coal mine of Yangquan mining area are introduced, and the gas desorption experiment results is verified by analyzing the effect of gas extraction.

GENERATION AND ACCUMULATION OF QUATERNARY SHALLOW GAS IN EASTERN QAIDAM BASIN, NW CHINA

This study presents an overview on the geological setting and geochemical characteristics of Pleistocene shallow gas accumulations in eastern Qaidam Basin, NW China. Five largest gas accumulations discovered in this region have a combined enclosure area of about 87 km2 and {7.9} trillion cubic feet (tcf) of proven plus controlled gas reserves. The dominance of methane ({>99.9%}) and the {δ{}{13}C} and δD values of methane ({-68.51‰} to {-65.00‰} and {-227.55‰} to {-221.94‰}, respectively) suggest that these gases are biogenic, derived from the degradation of sedimentary organic matter by methanogens under relatively low temperatures (<75℃). A sufficient supply and adequate preservation of organic matter in the Pleistocene sediments is made possible by the lake basin’s high altitude (2600-3000 m), high water salinity (>15%) and strong stratification. The deposition and extensive lateral occurrence of shore and shallow lake sands/silts in beach sand sheets and small sand bars provided excellent reservoirs for the biogenic gas generated from adjacent rocks. Effective but dynamic gas seals were provided by such factors as intermittent vertical variations in the sediment lithologies, hydraulic trapping due to mudstone water saturation, the hydrocarbon gradient created as a result of gas generation from potential caprocks, and the presence of a regional caprock consisting of 400-800-m-thick mudstones and evaporites. It appears that the most favorable traps for large gas accumulations occur on structural slopes near the major gas kitchen, and the prolific gas pools are often those large gentle anticlines with little faulting complication.

Research on nonlinear characteristics of strata collapse because of the multi-frequency mining

Based on the complexity of mine stratum and coupling of the multi-frequency for the damage of mine stratum,using the method of on-site inspection and mathematical statistics,the regulation and nonlinear characteristics of strata collapse in mine stratum's multi-frequency mining were put forward and systemically studied.Study result shows that the influence of multi-frequency mining in mine stratum has the feature of multi-frequency incontinuity,multi-characteristic and multi-type nonlinear collapse,strata collapse activa- tion turned worse,presenting an accumulation effect of multi-frequency mining for the strata damage.With the example of multi-frequency mining in the mine,the real characte- ristics of strata collapse by multi-frequency mining and nonlinear characteristics of accu- mulative response damage were analyzed.Research achievements about the surface re- cover and controlling of strata collapse by the multi-frequency mining have instruction meaning.

Assessment of Groundwater Source of Piedmont Plain Area of China Northwest Arid Region Based On Numerical Modeling

After the middle of 1960s,along with the appearance and extensive utilization of computer featured in large capacity and rapid speed,numerical method(mainly include finite difference method and finite element

Research of Mining STATCOM Based on Hybrid Multilevel H-bridge Inverter

The paper presents a new STATCOM system based on H-bridge inverter. It can be used in mine power network. It has been commonly verified for the positive effects of SVG on the reactive power compensation and voltage fluctuation suppression. This paper focuses on a generalized structure of multilevel power converter where individual voltage sources are not necessarily the same. The cascade H-bridge consists of two cells, high-voltage cell and low-voltage cell. The high-voltage cell is responsible for voltage lifting, while the low-voltage cell is responsible for PWM modulation. If two cells are cascaded with DC voltages in a ratio of 2:1, the single-phase output voltage can reach 7 levels. Increasing voltage levels of output waveform can bring up AC current quality, optimize harmonic spectrum and enhance converter efficiency. The hybrid multilevel is characterized by per-phase series connection of a high-voltage H-bridge converter and a low-voltage H-bridge converter. Due to the different capacitor voltage, it is a key problem as to how to maintain the capacitor’s voltage at a reference level. Independent DC source can effectively ensure the DC voltage. Through the reactive power compensation technology, the three-phase voltage and current can remain at the same phase.

Effects of Coal Rank and High Organic Sulfur on the Structure and Optical Properties of Coal-based Graphene Quantum Dots

Coal-based graphene quantum dots(GQDs) were successfully produced via a one-step chemical synthesis from six different coal ranks, from which two superhigh organic sulfur(SHOS) coals were selected as natural S-doped carbon sources for the preparation of S-doped GQDs. The effects of coal properties on coal-based GQDs were analyzed by means of high-resolution transmission electron microscopy(HRTEM), X-ray diffraction(XRD), Fourier transform infrared(FTIR) spectroscopy, X-ray photoelectron spectroscopy(XPS), ultraviolet-visible(UV-Vis) absorption spectroscopy, and fluorescence emission spectra. It was shown that all coal samples can be used to prepare GQDs, which emit bluegreen and blue fluorescence under ultraviolet light. Anthracite-based GQDs have a hexagonal crystal structure without defects, the largest size, and densely arranged carbon rings in their lamellae; the highrank bituminous coal-based GQDs are relatively reduced in size, with their hexagonal crystal structure being only faintly visible; the low-rank bituminous coal-based GQDs are the smallest, with sparse lattice fringes and visible internal defects. As the metamorphism of raw coals increases, the yield decreases and the fluorescence quantum yield(QY) initially increases and then decreases. Additionally, the surface of GQDs that were prepared using high-rank SHOS coal(high-rank bituminous coal) preserves rich sulfur content even after strong oxidation, which effectively adjusts the bandgap and improves the fluorescence QY. Thus, high-rank bituminous coal with SHOS content can be used as a natural S-doped carbon source to prepare S-doped GQDs, extending the clean utilization of low-grade coal.

An Efficient and Stable Ionic Liquid System for Synthesis of Ethylene Glycol via Hydrolysis of Ethylene Carbonate

An ionic liquid system of [Bmim]X/[Bmim]OH(X Cl,BF4,and PF6,) was developed for the hydroly-sis of ethylene carbonate to ethylene glycol. The important parameters,such as the variety of ionic liquids,molar ratio of [Bmim]X to [Bmim]OH,amount of ionic liquid,molar ratio of water to ethylene carbonate,reaction tem-perature,pressure and reaction time,were investigated systematically. Excellent yield(>93%) and high selectivity(99.5%) of ethylene glycol were achieved. Under the optimum reaction conditions,the ionic liquid system could be reused at least five times and the selectivity of ethylene glycol remained higher than 99.5%.

Full-field mapping of internal strain distribution in red sandstone specimen under compression using digital volumetric speckle photography and X-ray computed tomography

It is always desirable to know the interior deformation pattern when a rock is subjected to mechanicalload. Few experimental techniques exist that can represent full-field three-dimensional （3D） straindistribution inside a rock specimen. And yet it is crucial that this information is available for fully understandingthe failure mechanism of rocks or other geomaterials. In this study, by using the newlydeveloped digital volumetric speckle photography （DVSP） technique in conjunction with X-ray computedtomography （CT） and taking advantage of natural 3D speckles formed inside the rock due to materialimpurities and voids, we can probe the interior of a rock to map its deformation pattern under load andshed light on its failure mechanism. We apply this technique to the analysis of a red sandstone specimenunder increasing uniaxial compressive load applied incrementally. The full-field 3D displacement fieldsare obtained in the specimen as a function of the load, from which both the volumetric and the deviatoricstrain fields are calculated. Strain localization zones which lead to the eventual failure of the rock areidentified. The results indicate that both shear and tension are contributing factors to the failuremechanism. 2015 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Production and hosting byElsevier B.V. All rights reserved.

Advanced oxidation technology for H_2S odor gas using non-thermal plasma

Non-thermal plasma technology is a new type of odor treatment processing.We deal with H2Sfrom waste gas emission using non-thermal plasma generated by dielectric barrier discharge.On the basis of two criteria,removal efficiency and absolute removal amount,we deeply investigate the changes in electrical parameters and process parameters,and the reaction process of the influence of ozone on H2S gas removal.The experimental results show that H2S removal efficiency is proportional to the voltage,frequency,power,residence time and energy efficiency,while it is inversely proportional to the initial concentration of H2S gas,and ozone concentration.This study lays the foundations of non-thermal plasma technology for further commercial application.

Global sensitivity analysis of the AquaCrop model for winter wheat under different water treatments based on the extended Fourier amplitude sensitivity test

Sensitivity analysis （SA） is an effective tool for studying crop models; it is an important link in model localization and plays an important role in crop model calibration and application. The objectives were to （i） determine influential and non-influential parameters with respect to above ground biomass （AGB）, canopy cover （CC）, and grain yield of winter wheat in the Beijing area based on the AquaCrop model under different water treatments （rainfall, normal irrigation, and over-irrigation）; and （ii） generate an AquaCrop model that can be used in the Beijing area by setting non-influential parameters to fixed values and adjusting influential parameters according to the SA results. In this study, field experiments were conducted during the 2012-2013,2013-2014, and 2014-2015 winter wheat growing seasons at the National Precision Agriculture Demonstration Research Base in Beijing, China. The extended Fourier amplitude sensitivity test （EFAST） method was used to perform SA of the AquaCrop model using 42 crop parameters, in order to verify the SA results, data from the 2013-2014 growing season were used to calibrate the AquaCrop model, and data from 2012-2013 and 2014-2015 growing seasons were val- idated. For AGB and yield of winter wheat, the total order sensitivity analysis had more sensitive parameters than the first order sensitivity analysis. For the AGB time-series, parameter sensitivity was changed under different water treatments; in comparison with the non-stressful conditions （normal irrigation and over-irrigation）, there were more sensitive parameters under water stress （rainfall）, while root development parameters were more sensitive. For CC with time-series and yield, there were more sensitive parameters under water stress than under no water stress. Two parameters sets were selected to calibrate the AquaCrop model, one group of parameters were under water stress, and the others were under no water stress, there were two more sensitive parameters （growing degree-days （GDD） from sowing to the maximum rooting depth （root） and the maximum effective rooting depth （rtx）） under water stress than under no water stress. The results showed that there was higher accuracy under water stress than under no water stress. This study provides guidelines for AquaCrop model calibration and application in Beijing, China, as well providing guidance to simplify the AquaCrop model and improve its precision, especially when many parameters are used.

Composite active control system of roof and side truss cable for large section coal roadway in fold coal pillar area

In order to solve the surrounding rock control problem of large section gangue replacement roadway under complicated conditions, this paper analyzed the impact to the roadway controlling produced by the geological conditions such as high ground stress, folded structure tilted roof asymmetry and soft wall rock, and built the tilt layered roof structural mechanics model to clarify the increase span mechanism of the weak coal instability. Then, we proposed the combined control system including roof inclined truss cable, coal-side cable-channel steel and intensive bolt support. And then by building the structural mechanics model of roof inclined truss cable system, the support principle was described. Besides, according to this model, we deduced the calculation formula of cable anchoring force and its tensile stress. Finally surrounding rock control technology of large section roadway in fold coal pillar area was formed. Field practice shows that the greatest roof convergence of gangue replacement roadway is 158 mm and coal-side deformation is 243 mm. Roadway deformation is controlled effectively and technical support is provided for replacement mining.

Application of well log normalization in coalfield seismic inversion

During the process of coal prospecting and exploration, different measurement time, different logging instruments and series can lead to systematic errors in well logs. Accordingly, all logging curves need to be normalized in the mining area. By studying well-logging normalization methods, and focusing on the characteristics of the coalfield, the frequency histogram method was used in accordance with the condition of the Guqiao Coal Mine. In this way, the density and sonic velocity at marker bed in the non-key well were made to close to those in the key well, and were eventually equal. Well log normalization was completed when this method was applied to the entire logging curves. The results show that the scales of logging data were unified by normalizing coal logging curves, and the logging data were consistent with wave impedance inversion data. A satisfactory inversion effect was obtained.

Simulation of goaf heating law and the fire cooling effect during methane drainage in high level laneway

For spontaneous combustion possibilities under large flux methane drainage in the goal, dynamic permeability in combination with the Forchheimer nonlinear equation was used to solve the problem of 3D oxygen distribution, heating law in goaf and to forecast the effects of fire protection by taking the fifth section face of the No. 18 coal seam in Nanshan Coal Mine as the basis for this study. The results demonstrate that if the vertical position of the drainage laneway is so low as to cause serious air leakage, a high oxygen concentration area exists in the return side of the goaf, and there is also a high temperature region which has faster heating rate than in the other areas. The effect of methane drainage on goal heating can be alleviated dramatically by simultaneous plugging and nitrogen injection. The results show that gas data in the return side of the goaf must be detected carefully in the work face, which is of similar drainage arrangement. Therefore, comprehensive fire protection measures should be carried out if conditions permit.

Research on hydraulic slotting technology controlling coal-gas outbursts

Measured to control serious coal-gas outburst in coal seam were analyzed by theory and experimented in test site.A new technique to distress the coal-bed and drain methane,called hydraulic slotting,was described in detail,and the mechanism of hydrau- lic slotting was put forward and analyzed.The characteristic parameter of hydraulic slotting was given in Jiaozuo mining area and the characteristic of validity,adaptability and secu- rity was evaluated.The results show that the stress surrounding the strata and the gas in coal seam is released efficiently and thoroughly while new techniques are taken,as slot- ting at heading face by high pressure large diameter jet.The resistance to coal and gas outbursts is increased dramatically once the area of slotting is increased to a certain size. In the process of driving 2 000 m tunnel by hydraulic slotting excavation,coal and gas outburst never occurre.The technique could be used to prevent and control potential coal-gas outburst in the proceeding of tunnel driving,and the speed tunneling could be as high as more than 2 times.

Improved Method and Application of EMD Endpoint Continuation Processing for Blasting Vibration Signals

In order to deal with the non-stationary characteristics of blasting vibration signals and the end issue in the empirical mode decomposition(EMD), an improved endpoint continuation method is proposed. First, the linear continuation method of extreme points is used to determine the extremum of the signal endpoint fast. Secondly, the extreme points of transition section outside the signal ends are obtained by a mirror continuation method of extreme points, and then the envelope and continuation curve of the transition section of the signal are constructed. Lastly, the sinusoid of the stationary section outside the signal is constructed to achieve the continuation curve from the transition section to the stationary section. Based on the "singular extreme points" phenomenon of blasting vibration signal, the negative maxima and positive minimum are eliminated, then the maximum and minimum are guaranteed to appear at intervals. Thus,the number of iterations is reduced and the instability of EMD decomposition is improved. The calculation formula of amplitude, cycle and initial phase are given for the transition section and stationary section outside the signal. The endpoint processing effect of the simulated signal and the measured blasting vibration signal show that the improved endpoint continuation method can suppress the signal endpoint effect well.

Analysis of the mechanical property of mudstone/shale in paralic coal measures and its influence factors

The mechanical property of mudstone/shale in coal measures is a key factor of engineering mechanics that influences the development of shale gas. A rock mechanics test was performed in order to analyze the complete stress-strain mechanic characteristics and influence factors of mudstone/shale in paralic coal measures, from the Carboniferous-Permian periods in a coal field of Northern China. The relationship between the mechanical properties of mudstone/shale in coal measures, and its chemical component, water content are established, and their models are constructed. Research results show that mud- stone/shale has low mechanical strength, low elastic modulus and a high Poisson＇s ratio. The complete stress-strain curve has apparent elastoplastic deformation characteristics, and after reaching peak strength, it exhibits obvious strain softening characteristics. The uniaxial compressive strength of mudstone/shale and its elastic modulus increases exponentially with the increase of SiO2 content, and as the ignition loss increases, the uniaxial compressive strength and elastic modulus of mudstone/shale will decrease according to the law of power function. The compressive strength of mudstone/shale and its elastic modulus will decrease with the increase of water content in mudstone/shale.

Minimum secure speed of fully mechanized coal face based on critical temperature of coal spontaneous combustion

The critical temperature theory of spontaneous combustion of coal and the numerical simulation method are used to explore the minimum secure speed of fully mechanized coal face to prevent the spontaneous combustion in goaf. Combined with the actual situation of workface 31005 in a coal mine, the highest temperatures in goal at different advancing speeds were obtained by the numerical simulation of spontaneous combustion in goal, and then a power function equation between the highest temperature and the advancing speed was achieved by regression analysis. The advancing speed corresponding to the critical temperature value was taken as the minimum safe speed of workface based on the equation. Finally, the accuracy and reliability of the speed were verified by the actual advancing process of workface 31005. The results of this research show that the new judgment method of the minimum safety speed has a higher value to be applied in the field.

Numerical simulation of nitrogen injection of goaf in fire prevention based on Finite Volume Method

The numerical simulation is used to research the influence of nitrogen injection on spontaneous combustion in goaf. The spontaneous combustion mathematical model on the coupling of air flow field, oxygen concentration field, and residual coal temperature field was established with nitrogen injection in goat＇. Then the software of numerical computation was pro- grammed by Finite Volume Method. Combined with the example, the distributions of air flow field, oxygen concentration field and residual coal temperature field at different nitrogen injection volume were obtained by the software. The results show that the nitrogen injection could effectively prevent the spontaneous combustion fire in goaf and the highest temperature in goaf decreased with the nitrogen injection volume increasing. Finally, the accuracy of the numerical simulation was verified by the temperature observation in field. The achievement of this research is of theoretical and practical significance for the prevention of coal spontaneous combustion in goaf.

Coal matrix deformation characteristics in the process of carbon dioxide displacing different gas saturation coal-bed methane

It is fundamental that changes in coal reservoir permeability are researched, in particular, the accurate determination of variations in the coal matrix caused by CO2 replacing CH4 at different gas saturation conditions. Based on the surface free energy, the extended Langmuir isothermal adsorption model, combined with CO2 replacing CH4 in experimental trials, and calling on the more general principles and characteristics of the field, mathematical models describing the coal matrix as it undergoes different processes such as CO2 injection and desorption were established. Combined with laboratory data about CO2 replacement under different methane saturation conditions, a law governing the variations in coal matrix CO2 replacement under different methane gas saturation conditions was obtained. The results showed that： in the injection process, the coal matrix expansion rate caused by CO2 or CH4 was exponentially increased with the CO2 pressure increase, the expansion caused by CO2 was far greater than the expansion caused by CH4 in the desorption process, the coal matrix shrinkage caused by CO2 or CH4 was exponentially increased with the pressure decrease, the shrinkage caused by CO2 was larger than the shrinkage caused by CH4 under the same pressure and different gas saturation, the total shrinkage in the desorption process in the coal matrix was greater than the total expansion in the injection process. At higher gas saturations, the total coal matrix shrinkage volume exceeded the total expansion corresponding to pressure points higher in the desorption process.

Development of belt conveyor driving system

A short review for the existing various driving methods for belt conveyor was given, which include the analysis and comparison about the advantages, disadvantages and suitable application range of these methods. Based on this the vari-able-frequency-control(VFC) method for belt conveyor drive was fully discussed with focus on its application in medium-high voltage range. The principle of Neutral Point Clamped (NPC) Three-Level Inverter using high-voltage IGBTs together with the control strategy of rotor field-oriented vector control for induction motor drive were illustrated.