Geophysical prediction of organic matter abundance in source rocks based on geochemical analysis:A case study of southwestern Bozhong Sag,Bohai Sea,China

The Bozhong Sag is the largest petroliferous sag in the Bohai Bay Basin,and the source rocks of Paleogene Dongying and Shahejie Formations were buried deeply.Most of the drillings were located at the structural high,and there were few wells that met good quality source rocks,so it is difficult to evaluate the source rocks in the study area precisely by geochemical analysis only.Based on the Rock-Eval pyrolysis,total organic carbon(TOC)testing,the organic matter(OM)abundance of Paleogene source rocks in the southwestern Bozhong Sag were evaluated,including the lower of second member of Dongying Formation(E_(3)d2L),the third member of Dongying Formation(E_(3)d_(3)),the first and second members of Shahejie Formation(E_(2)s_(1+2)),the third member of Shahejie Formation(E_(2)s_(3)).The results indicate that the E_(2)s_(1+2)and E_(2)s_(3)have better hydrocarbon generative potentials with the highest OM abundance,the E_(3)d_(3)are of the second good quality,and the E_(3)d2L have poor to fair hydrocarbon generative potential.Furthermore,the well logs were applied to predict TOC and residual hydrocarbon generation potential(S_(2))based on the sedimentary facies classification,usingΔlogR,generalizedΔlogR,logging multiple linear regression and BP neural network methods.The various methods were compared,and the BP neural network method have relatively better prediction accuracy.Based on the pre-stack simultaneous inversion(P-wave impedance,P-wave velocity and density inversion results)and the post-stack seismic attributes,the three-dimensional(3D)seismic prediction of TOC and S_(2)was carried out.The results show that the seismic near well prediction results of TOC and S_(2)based on seismic multi-attributes analysis correspond well with the results of well logging methods,and the plane prediction results are identical with the sedimentary facies map in the study area.The TOC and S_(2)values of E_(2)s_(1+2)and E_(2)s_(3)are higher than those in E_(3)d_(3)and E_(3)d_(2)L,basically consistent with the geochemical analysis results.This method makes up the deficiency of geochemical methods,establishing the connection between geophysical information and geochemical data,and it is helpful to the 3D quantitative prediction and the evaluation of high-quality source rocks in the areas where the drillings are limited.

Geochemical identification of a source rock affected by migrated hydrocarbons and its geological significance:Fengcheng Formation,southern Mahu Sag,Junggar Basin,NW China

The Fengcheng Formation is a crucial source rock and the primary reservoir for oil accumulation in the Mahu Sag.Crude oils are distributed throughout the Fengcheng Formation,ranging from the edge to the interior of the sag in the southern Mahu Sag.These crude oils originate from in-situ source rocks in shallowly buried areas and the inner deep sag.During migration,the crude oil from the inner deep sag affects the source rocks close to carrier beds,leading to changes in the organic geochemical characteristics of the source rocks.These changes might alter source rock evaluations and oil-source correlation.Based on data such as total organic carbon(TOC),Rock-Eval pyrolysis of source rocks,and gas chromatography-mass spectrometry(GC-MS)of the saturated fraction,and considering the geological characteristics of the study area,we define the identification characteristics of source rock affected by migrated hydrocarbons and establish the various patterns of influence that migrated hydrocarbons have on the source rock of the Fengcheng Formation in the southern Mahu Sag.The source rocks of the Fengcheng Formation are mostly fair to good,containing mainly Type II organic matter and being thermally mature enough to generate oil.Source rocks affected by migrated hydrocarbons exhibit relatively high hydrocarbon contents(S1/TOC>110 mg HC/g TOC,Extract/TOC>30%,HC:hydrocarbon),relatively low Rock-Eval Tmax values,and relatively high tricyclic terpane contents with a descending and mountain-shaped distribution.Furthermore,biomarker composition parameters indicate a higher thermal maturity than in-situ source rocks.Through a comparison of the extract biomarker fingerprints of adjacent reservoirs and mudstones in different boreholes,three types of influence patterns of migrated hydrocarbons are identified:the edge-influence of thin sandstone-thick mudstone,the mixed-influence of sandstone-mudstone interbedded,and the full-influence of thick sandstone-thin mudstone.This finding reminds us that the influence of migrated hydrocarbons must be considered when evaluating source rocks and conducting oil-source correlation.

An intelligent automatic correlation method of oilbearing strata based on pattern constraints:An example of accretionary stratigraphy of Shishen 100 block in Shinan Oilfield of Bohai Bay Basin,East China

Aiming at the problem that the data-driven automatic correlation methods which are difficult to adapt to the automatic correlation of oil-bearing strata with large changes in lateral sedimentary facies and strata thickness,an intelligent automatic correlation method of oil-bearing strata based on pattern constraints is formed.We propose to introduce knowledge-driven in automatic correlation of oil-bearing strata,constraining the correlation process by stratigraphic sedimentary patterns and improving the similarity measuring machine and conditional constraint dynamic time warping algorithm to automate the correlation of marker layers and the interfaces of each stratum.The application in Shishen 100 block in the Shinan Oilfield of the Bohai Bay Basin shows that the coincidence rate of the marker layers identified by this method is over 95.00%,and the average coincidence rate of identified oil-bearing strata reaches 90.02% compared to artificial correlation results,which is about 17 percentage points higher than that of the existing automatic correlation methods.The accuracy of the automatic correlation of oil-bearing strata has been effectively improved.

Quantitative effect of kerogen type on the hydrocarbon generation potential of Paleogene lacustrine source rocks,Liaohe Western Depression,China

Kerogen types exert a decisive effect on the onset and capacity of hydrocarbon generation of source rocks.Lacustrine source rocks in the Liaohe Western Depression are characterized by thick deposition,high total organic carbon(TOC)content,various kerogen types,and a wide range of thermal maturity.Consequently,their hydrocarbon generation potential and resource estimation can be misinterpreted.In this study,geochemical tests,numerical analysis,hydrocarbon generation kinetics,and basin modeling were integrated to investigate the differential effects of kerogen types on the hydrocarbon generation potential of lacustrine source rocks.Optimized hydrocarbon generation and expulsion(HGE)models of different kerogen types were established quantitatively upon abundant Rock-Eval/TOC/vitrinite reflectance(R_(o))datasets.Three sets of good-excellent source rocks deposited in the fourth(Es4),third(Es3),and first(Es1)members of Paleogene Shahejie Formation,are predominantly types I-II_(1),II_(1)-II_(2),and II-III,respectively.The activation energy of types I-II_(2)kerogen is concentrated(180-230 kcal/mol),whereas that of type III kerogen is widely distributed(150-280 kcal/mol).The original hydrocarbon generation potentials of types I,II_(1),II_(2),and III kerogens are 790,510,270,and 85 mg/g TOC,respectively.The Ro values of the hydrocarbon generation threshold for type I-III source rocks gradually increase from 0.42%to 0.74%,and Ro values of the hydrocarbon expulsion threshold increase from 0.49%to 0.87%.Types I and II_(1)source rocks are characterized by earlier hydrocarbon generation,more rapid hydrocarbon expulsion,and narrower hydrocarbon generation windows than types II_(2)and III source rocks.The kerogen types also affect the HGE history and resource potential.Three types(conventional,tight,and shale oil/gas)and three levels(realistic,expected,and prospective)of hydrocarbon resources of different members in the Liaohe Western Depression are evaluated.Findings suggest that the Es3 member has considerable conventional and unconventional hydrocarbon resources.This study can quantitatively characterize the hydrocarbon generation potential of source rocks with different kerogen types,and facilitate a quick and accurate assessment of hydrocarbon resources,providing strategies for future oil and gas exploration.

Identification and evaluation of shale oil micromigration and its petroleum geological significance

Taking the Lower Permian Fengcheng Formation shale in Mahu Sag of Junggar Basin,NW China,as an example,core observation,test analysis,geological analysis and numerical simulation were applied to identify the shale oil micro-migration phenomenon.The hydrocarbon micro-migration in shale oil was quantitatively evaluated and verified by a self-created hydrocarbon expulsion potential method,and the petroleum geological significance of shale oil micro-migration evaluation was determined.Results show that significant micro-migration can be recognized between the organic-rich lamina and organic-poor lamina.The organic-rich lamina has strong hydrocarbon generation ability.The heavy components of hydrocarbon preferentially retained by kerogen swelling or adsorption,while the light components of hydrocarbon were migrated and accumulated to the interbedded felsic or carbonate organic-poor laminae as free oil.About 69% of the Fengcheng Formation shale samples in Well MY1 exhibit hydrocarbon charging phenomenon,while 31% of those exhibit hydrocarbon expulsion phenomenon.The reliability of the micro-migration evaluation results was verified by combining the group components based on the geochromatography effect,two-dimension nuclear magnetic resonance analysis,and the geochemical behavior of inorganic manganese elements in the process of hydrocarbon migration.Micro-migration is a bridge connecting the hydrocarbon accumulation elements in shale formations,which reflects the whole process of shale oil generation,expulsion and accumulation,and controls the content and composition of shale oil.The identification and evaluation of shale oil micro-migration will provide new perspectives for dynamically differential enrichment mechanism of shale oil and establishing a“multi-peak model in oil generation”of shale.

Upper Paleozoic total petroleum system and geological model of natural gas enrichment in Ordos Basin, NW China

Based on the analysis of Upper Paleozoic source rocks, source-reservoir-caprock assemblage, and gas accumulation characteristics in the Ordos Basin, the gas accumulation geological model of total petroleum system is determined. Then, taking the Carboniferous Benxi Formation and the Permian Taiyuan Formation and Shanxi Formation as examples, the main controlling factors of gas accumulation and enrichment are discussed, and the gas enrichment models of total petroleum system are established. The results show that the source rocks, faults and tight reservoirs and their mutual coupling relations control the distribution and enrichment of gas. Specifically, the distribution and hydrocarbon generation capacity of source rocks control the enrichment degree and distribution range of retained shale gas and tight gas in the source. The coupling between the hydrocarbon generation capacity of source rocks and the physical properties of tight reservoirs controls the distribution and sweet spot development of near-source tight gas in the basin center. The far-source tight gas in the basin margin is mainly controlled by the distribution of faults, and the distribution of inner-source, near-source and far-source gas is adjusted and reformed by faults. Generally, the Upper Paleozoic gas in the Ordos Basin is recognized in four enrichment models: inner-source coalbed gas and shale gas, inner-source tight sandstone gas, near-source tight gas, and far-source fault-transported gas. In the Ordos Basin, inner-source tight gas and near-source tight gas are the current focuses of exploration, and inner-source coalbed gas and shale gas and far-source gas will be important potential targets in the future.

Effect of petroleum chemical fraction and residual oil content in saline lacustrine organic-rich shale: A case study from the Paleogene Dongpu Depression of North China

Halite and gypsum minerals in saline shale make the retention mechanism and chemical fractionation of residual oil unique. The Dongpu Depression in North China is a typically saline lacustrine basin with developing halite and gypsum. The effect of gypsum minerals on residual oil content and chemical fractionation remains unclear. In this study, shale samples with different gypsum contents were used in organic geochemical experiments, showing that the high total organic matter (TOC) content and type II kerogen leads to a high residual oil content, as shown by high values of volatile hydrocarbon (S1) and extractable organic matter (EOM). XRD and FE-SEM result indicate that the existence of gypsum in saline shale contributes to an enhanced pore space and a higher residual oil content in comparison to non-gypsum shale. Additionally, the increase in the gypsum mineral content leads to an increase in the saturated hydrocarbon percentage and a decrease in polar components percentage (resins and asphaltene). Furthermore, thermal simulation experiments on low-mature saline shale show that the percentage of saturated hydrocarbons in the residual oil is high and remains stable and that the storage space is mainly mesoporous (> 20 nm) in the oil expulsion stage. However, the saturated hydrocarbons percentage decreases rapidly, and oil exists in mesopores (> 20 nm and < 5 nm) in the gas expulsion stage. In general, gypsum is conducive to the development of pore space, the adsorption of hydrocarbons and the occurrence of saturated hydrocarbon, leading to large quantities of residual oil. The data in this paper should prove to be reliable for shale oil exploration in saline lacustrine basins.

Petroleum geochemistry and origin of shallow-buried saline lacustrine oils in the slope zone of the Mahu sag, Junggar Basin, NW China

Recently, significant oil discoveries have been made in the shallower pay zones of the Jurassic Badaowan Formation (J_(1)b) in the Mahu Sag, Junggar Basin, Northwest China. However, little work has been done on the geochemical characteristics and origins of the oil in the J_(1)b reservoir. This study analyzes 44 oil and 14 source rock samples from the area in order to reveal their organic geochemical characteristics and the origins of the oils. The J_(1)b oils are characterized by a low Pr/Ph ratio and high β-carotene and gammacerane indices, which indicate that they were mainly generated from source rocks deposited in a hypersaline environment. The oils are also extremely enhanced in C_(29) regular steranes, possibly derived from halophilic algae. Oil-source correlation shows that the oils were derived from the Lower Permian Fengcheng Formation (P_(1)f) source rocks, which were deposited in a strongly stratified and highly saline water column with a predominance of algal/bacterial input in the organic matter. The source rocks of the Middle Permian lower-Wuerhe Formation (P_(2)w), which were deposited in fresh to slightly saline water conditions with a greater input of terrigenous organic matter, make only a minor contribution to the J_(1)b oils. The reconstruction of the oil accumulation process shows that the J_(1)b oil reservoir may have been twice charged during Late Jurassic–Early Cretaceous and the Paleogene–Neogene, respectively. A large amount volume of hydrocarbons generated in the P_(1)f source rock and leaked from T_(1)b oil reservoirs migrated along faults connecting source beds and shallow-buried secondary faults into Jurassic traps, resulting in large-scale accumulations in J_(1)b. These results are crucial for understanding the petroleum system of the Mahu Sag and will provide valuable guidance for petroleum exploration in the shallower formations in the slope area of the sag.

Controlling factors and models of shale oil enrichment in Lower Permian Fengcheng Formation,Mahu Sag,Junggar Basin,NW China

Based on the combination of core observation,experimental analysis and testingand geological analysis,the main controlling factors of shale oil enrichment in the Lower Permian Fengcheng Formation in the Mahu Sag of the Junggar Basin are clarified,and a shale oil enrichment model is established.The results show that the enrichment of shale oil in the Fengcheng Formation in the Mahu Sag is controlled by the organic abundance,organic type,reservoir capacity and the amount of migration hydrocarbon in shale.The abundance of organic matter provides the material basis for shale oil enrichment,and the shales containing typesⅠandⅡorganic matters have good oil content.The reservoir capacity controls shale oil enrichment.Macropores are the main space for shale oil enrichment in the Fengcheng Formation,and pore size and fracture scale directly control the degree of shale oil enrichment.The migration of hydrocarbons in shale affects shale oil enrichment.The shale that has expelled hydrocarbons has poor oil content,while the shale that has received hydrocarbons migrated from other strata has good oil content.Lithofacies reflect the hydrocarbon generation and storage capacity comprehensively.The laminated felsic shale,laminated lime-dolomitic shale and thick-layered felsic shale have good oil content,and they are favorable lithofacies for shale oil enrichment.Under the control of these factors,relative migration of hydrocarbons occurred within the Fengcheng shale,which leads to the the difference in the enrichment process of shale oil.Accordingly,the enrichment mode of shale oil in Fengcheng Formation is established as"in-situ enrichment"and"migration enrichment".By superimposing favorable lithofacies and main controlling factors of enrichment,the sweet spot of shale oil in the Fengcheng Formation can be selected which has great significance for the exploration and development of shale oil.

Heterogeneity and differential hydrocarbon accumulation model of deep reservoirs in foreland thrust belts: A case study of deep Cretaceous Qingshuihe Formation clastic reservoirs in southern Junggar Basin, NW China

Using the data of drilling, logging, core, experiments and production, the heterogeneity and differential hydrocarbon accumulation model of deep reservoirs in Cretaceous Qingshuihe Formation(K1q) in the western section of the foreland thrust belt in southern Junggar Basin are investigated. The target reservoirs are characterized by superimposition of conglomerates, sandy conglomerates and sandstones, with high content of plastic clasts. The reservoir space is mainly composed of intergranular pores. The reservoirs are overall tight, and the sandy conglomerate has the best physical properties. The coupling of short deep burial period with low paleotemperature gradient and formation overpressure led to the relatively weak diagenetic strength of the reservoirs. Specifically, the sandy conglomerates show relatively low carbonate cementation, low compaction rate and high dissolution porosity. The special stress-strain mechanism of the anticline makes the reservoirs at the top of the anticline turning point more reformed by fractures than those at the limbs, and the formation overpressure makes the fractures in open state. Moreover, the sandy conglomerates have the highest oil saturation. Typical anticline reservoirs are developed in deep part of the thrust belt, but characterized by "big trap with small reservoir". Significantly, the sandy conglomerates at the top of anticline turning point have better quality, lower in-situ stress and higher structural position than those at the limbs,with the internal hydrocarbons most enriched, making them high-yield oil/gas layers. The exponential decline of fractures makes hydrocarbon accumulation difficult in the reservoirs at the limbs. Nonetheless, plane hydrocarbon distribution is more extensive at the gentle limb than the steep limb.

Characteristics and exploration targets of Chang 7 shale oil in Triassic Yanchang Formation, Ordos Basin, NW China

The geological characteristics and enrichment laws of the shale oil in the third submember of the seventh member of Triassic Yanchang Formation(Chang 7_(3)) in the Ordos Basin were analyzed by using the information of core observations, experiments and logging, and then the exploration potential and orientation of the Chang 7_(3) shale oil were discussed. The research findings are obtained in three aspects. First, two types of shale oil, i.e. migratory-retained and retained, are recognized in Chang 7_(3). The former is slightly better than the latter in quality. The migratory-retained shale oil reservoir is featured with the frequent interbedding and overlapping of silty-sandy laminae caused by sandy debris flow and low-density turbidity current and semi-deep-deep lacustrine organic-rich shale laminae. The retained shale oil reservoir is composed of black shale with frequent occurrence of bedding and micro-laminae. Second, high-quality source rocks provide a large quantity of hydrocarbon-rich high-quality fluids with high potential energy. The source-reservoir pressure difference provides power for oil accumulation in thin interbeds of organic-poor sandstones with good seepage conditions and in felsic lamina, tuffaceous lamina and bedding fractures in shales. Hydrocarbon generation-induced fractures, bedding fractures and microfractures provide high-speed pathways for oil micro-migration. Frequent sandstone interlayers and felsic laminae provide a good space for large-scale hydrocarbon accumulation, and also effectively improve the hydrocarbon movability. Third, sand-rich areas around the depression are the main targets for exploring migratory-retained shale oil. Mature deep depression areas are the main targets for exploring retained oil with medium to high maturity. Theoretical research and field application of in-situ conversion in low-mature deep depression areas are the main technical orientations for exploring retained shale oil with low to medium maturity.

Salt-Lake Basin Bedrock Weathered Crust Gas Reservoir in the Altun Mountains Front of the Qaidam Basin,Western China

The bedrock weathered crust in front of the Altun Mountains in the Qaidam Basin,western China,is different from others because this is a salt-lake basin,where saline water fluid infiltrates and is deposited in the overlying strata.A large amount of gypsum infills the bedrock weathered crust,and this has changed the pore structure.Using core observation,polarized light microscopy,electron probe,physical property analysis and field emission scanning electron microscopy experiments,the characteristics of the weathered bedrock have been studied.There are cracks and a small number of dissolved pores in the interior of the weathered crust.Matrix micropores are widely developed,especially the various matrix cracks formed by tectonics and weathering,as well as the stress characteristics of small dissolved pores,and physical properties such as porosity and permeability.This‘dual structure’developed in the bedrock is important for guiding the exploration of the lake basin bedrock for natural gas.

Factors Controlling Organic Matter Enrichment in Alkaline Lacustrine Source Rocks:A Case Study of the Late Paleozoic Fengcheng Formation in the Junggar Basin,NW China

The late Paleozoic Fengcheng Formation shale(LPF shale)in the Junggar Basin,NW China,is the oldest alkaline source rock discovered in the world,providing a unique perspective with which to explore organic matter(OM)enrichment in alkaline lake environments.Combined with the organic carbon isotope profile and paleoenvironmental proxies,this study reveals that the LPF shale was deposited in an arid climate with high salinity and a strong reducing environment,accompanied by frequent volcanic activity.High TOC values are concentrated in two intervals with frequent fluctuations in OM types.A negative excursion due to changes in sedimentary OM source is found in the δ^(13)C_(org) profile.The excursion corresponds to the OM enrichment interval and is accompanied by abnormally high values of Sr/Ba and Sr/Cu.This implies that the extreme arid climate has led to high salinity,resulting in strong reducibility and changes in paleontological assemblages,which in turn controlled the differential enrichment of OM.The Fengcheng Fm.high-quality source rocks are the result of the combined action of climatic events,volcanism,high-salinity water environment and superior hydrocarbon-generating organisms.The results provide new insights into the formation conditions of terrestrial alkaline high-quality source rocks and the factors controlling alkaline OM enrichment.

Diversity of depositional architecture and sandbody distribution of sublacustrine fans during forced regression: A case study of Paleogene Middle Sha 3 Member in Dongying Sag, Bohai Bay Basin, East China

Currently, the differences in gravity flow deposits within different systems tracts in continental lacustrine basins are not clear. Taking the middle submember of the third member of Paleogene Shahejie Formation(Sha 3 Member) in the Shishen 100 area of the Dongying Sag in the Bohai Bay Basin as an example, the depositional architecture of sublacustrine fans during forced regression and the impact of the fourth-order base-level changes on their growth were investigated using cores, well logs and 3D seismic data. Sublacustrine fans were mainly caused by hyperpycnal flow during the fourth-order base-level rise, while the proportion of slump-induced sublacustrine fans gradually increased during the late fourth-order base-level fall. From rising to falling of the fourth-order base-level, the extension distance of channels inside hyperpycnal-fed sublacustrine fans reduced progressively, resulting in the transformation in their morphology from a significantly channelized fan to a skirt-like fan. Furthermore, the depositional architecture of distributary channel complexes in sublacustrine fans changed from vertical aggradation to lateral migration, and the lateral size of individual channel steadily decreased. The lobe complex's architectural patterns evolved from compensational stacking of lateral migration to aggradational stacking, and the lateral size of individual lobe steadily grew. This study deepens the understanding of depositional features of gravity flow in high-frequency sequence stratigraphy and provides a geological foundation for the fine development of sublacustrine fan reservoirs.

Action mechanisms of abnormal fluid pressure on physical properties of deep reservoirs: A case study on Jurassic Toutunhe Formation in the southern margin of Junggar Basin, NW China

Considering the action mechanisms of overpressure on physical changes in skeleton particles of deep reservoir rocks and the differences in physical changes of skeleton particles under overpressure and hydrostatic pressure, the sandstone of the Jurassic Toutunhe Formation in the southern margin of Junggar Basin was taken as an example for physical modeling experiment to analyze the action mechanisms of overpressure on the physical properties of deep reservoirs. (1) In the simulated ultra-deep layer with a burial depth of 6000-8000 m, the mechanical compaction under overpressure reduces the remaining primary pores by about a half that under hydrostatic pressure. Overpressure can effectively suppress the mechanical compaction to allow the preservation of intergranular primary pores. (2) The linear contact length ratio under overpressure is always smaller than the linear contact length ratio under hydrostatic pressure at the same depth. In deep reservoirs, the difference between the mechanical compaction degree under overpressure and hydrostatic pressure shows a decreasing trend, the effect of abnormally high pressure to resist the increase of effective stress is weakened, and the degree of mechanical compaction is gradually close to that under hydrostatic pressure. (3) The microfractures in skeleton particles of deep reservoirs under overpressure are thin and long, while the microfractures in skeleton particles of deep reservoirs under hydrostatic pressure are short and wide. This difference is attributed to the probable presence of tension fractures in the rocks containing abnormally high pressure fluid. (4) The microfractures in skeleton particles under overpressure were mainly formed later than that under hydrostatic pressure, and the development degree and length of microfractures both extend deeper. (5) The development stages of microfractures under overpressure are mainly controlled by the development stages of abnormally high pressure and the magnitude of effective stress acting on the skeleton particles. Moreover, the development stages of microfractures in skeleton particles are more than those under hydrostatic pressure in deep reservoir. The multi-stage abnormally high pressure plays an important role in improving the physical properties of deep reservoirs.

Fluid Charging and Paleo-pressure Evolution in the Ledong Slope Zone of the Yinggehai Basin,South China Sea

Large numbers of gas reservoirs have been discovered in overpressure basins.Fluid charging has a close relationship with paleo-pressure evolution,affecting the migration of gas reservoirs.To study fluid charging and the related pressure system,we analyzed burial histories and fluid inclusion(PVTx)simulations and conducted basin modeling of the Ledong Slope Zone in the Yinggehai Basin as an example.On the basis of fluid-inclusion assemblages(FIAs),homogenization temperature(Th),final melting temperature(Tm,ice)and Raman spectroscopy in fluid inclusions,there are three stages of fluid charging:during the first and second stage,methane-dominated fluid was charged at 2.2–1.7 Ma and 1.7–0.9 Ma,respectively.In the third stage,CO_(2)-rich hydrothermal fluid was charged since 0.9 Ma.It could be concluded from the well-logging data that the disequilibrium compaction in the Yinggehai Fm.,along with the fluid expansion and clay diagenesis in the Huangliu and Meishan formations,resulted in the overpressure in the Ledong slope zone.The evolution of paleo-pressure was affected by the sedimentation rate of the Yinggehai Fm.,as well as the hydrocarbon generation rate.Additionally,the Ledong Slope Zone is less affected by diapir activity than the nearby diapir area.Based on fluid inclusions,paleo-pressure,basin modeling and geological background,the gas migration history of the Ledong Slope Zone can be divided into four stages:in the first stage,excess pressure was formed around 5 Ma;from 2.2 to 1.7 Ma,there was a reduction in the charging of hydrocarbon fluid and steadily increasing excess pressure;during the 1.7–0.9 Ma period a large amount of hydrocarbon was generated,excess pressure increasing significantly and hydraulic fractures forming in mudstones,With gas reservoirs developing in structural highs;since 0.9 Ma,CO_(2)-rich hydrothermal fluid accumulated in reservoirs adjacent to faults and the pressure coefficient remained stable.The research results are helpful in the study of fluid migration and accumulation mechanisms in overpressure basins.

Organic matter transformation ratio, hydrocarbon expulsion efficiency and shale oil enrichment type in Chang 7_(3) shale of Upper Triassic Yanchang Formation in Ordos Basin, NW China

The major enrichment type of shale oil in the Chang 7_(3) shale of Upper Triassic Yanchang Formation in the Ordos Basin is unknown.This paper analyzes the organic matter transformation ratio,hydrocarbon expulsion efficiency and roof/floor sealing conditions of the Chang 7_(3) shale,and evaluates the major enrichment type of shale oil in this interval.The average organic matter transformation ratio of the Chang 7_(3) shale is about 45%;in other words,more than 50%of the organic matters have not transformed to hydrocarbons,and the lower the maturity,the greater the proportion of untransformed organic matters.The cumulative hydrocarbon expulsion efficiency of the transformed hydrocarbon is 27.5% on average,and the total proportion of untransformed organic matters plus retained hydrocarbons is greater than 70%.The relative hydrocarbon expulsion efficiency of the Chang 7_(3) shale is 60%on average,that is,about 40% of hydrocarbons retain in the shale.The Chang 7_(3) shale corresponds to Chang 7_(1+2) and Chang 8 sandstones as the roof and floor,respectively,and is further overlaid by Chang 6 shale,where extensive low porosity and low permeability–tight oil reservoirs have formed in the parts with relatively good porosity and permeability.Moreover,the Chang 7_(3) shale is tested to be in a negative pressure system(the pressure coefficient of 0.80–0.85).Therefore,the roof/floor sealing conditions of the Chang 7_(3) shale are poor.The retained hydrocarbons appear mostly in absorbed status,with low mobility.It is concluded that the medium–high mature shale oil is not the major enrichment type of shale oil in the Chang 7_(3) shale,but there may be enrichment opportunity for shale oil with good mobility in the areas where the sealing conditions are good without faults and fractures and oil reservoirs are formed off Chang 7_(1+2),Chang 6 and Chang 8.Furthermore,low–medium mature shale oil is believed to have great potential and is the major enrichment type of shale oil in the Chang 7_(3) shale.It is recommended to prepare relevant in-situ conversion technologies by pilot test and figure out the resource availability and distribution.

Petroleum Migration Characteristics in the Northeastern Part of the Baiyun Depression,Pearl River Mouth Basin,South China Sea

This paper investigates the origin and migration characteristics of petroleum in the northeastern part of the Baiyun Depression,Pearl River Mouth Basin(PRMB).The discovered petroleum in the study area is mainly located in the Lower Zhujiang Member(N_(1)z^(2))and mainly originated from the Enping Formation source rocks in the eastern sag.Active faults(vertical migration)and N_(1)z^(2)sandstones(lateral migration)acted as the petroleum migration systems.The fault activities in the Dongsha event controlled the episodic petroleum migration.Fractures in the fault zones provided effective conduits,and overpressure was the driving force.The vertical migration could not cross the fault zones laterally.The petroleum injection areas in the carrier beds were the contact zones of petroleum-migration faults and carrier beds.The lateral migration was steady-state migration,and buoyancy was the driving force.The migration pathways in the carrier beds were controlled by the structural morphology.Secondary petroleum migration in the study area could be divided into two parts:vertical migration along the fractures in the fault zones and lateral migration through preferential petroleum migration pathways(PPMPs)in the carrier beds.The petroleum migration behaviors,including migrating direction,driving force,and migration pattern,in the faults and sandstone carrier beds were quite different.This study provides a typical example for comprehending secondary migration processes and has great importance for determining future exploration targets in the deep-water area of the PRMB.

Supply of terrigenous organic matter from tidal flat to the marine environment:An example of neritic source rocks in the Eocene Pinghu Formation,Xihu Depression,East China Sea Shelf Basin

The terrigenously-dominated marine shales which were deposited in the lower Eocene Pinghu Formation were thought to be a potential source rock in the Xihu Depression of the East China Sea Shelf Basin.However,the exceptionally high total organic carbon content(TOC,>6%on average)of the tidal sand ridge samples was not compatible with their sedimentary environment,indicating coal-bearing sedimentary debris may have been transferred from the coast to the ocean.In this study,new sights into the origins and supply of organic materials in the coastal environment were proposed in the neritic organic matter of the Eocene Pinghu Formation.A discriminant model was developed using plynofacies analysis data to pinpoint the source of organic materials in marine source rocks.The discrimination results suggested that marine mudstones were associated with tidal flat mudstones rather than deltaic ones.The biomarker characteristics of mudstones deposited in various environments support this assertion,indicating that the supply of plant materials in tidal flats is the primary organic matter source for the marine environment.The organic matter abundance was elevated in tidal flats due to their superior preservation conditions.Additionally,the lithological assemblage of tidal flats suggests that tidal currents can scour marshes and then transport dispersed terrigenous organic materials to neritic areas.These findings indicate that coal-bearing sedimentary debris was likely transferred from the coast to the ocean,and tidal currents are thought to be the dominant mechanism driving organic matter from the tidal to the marine environment.

Grading Evaluation and Ranking of CO_(2) Sequestration Capacity in Place(CSCIP) in China’s Major Oil Basins:Theoretical,Effective,Practical and CCUS-EOR

Because it is necessary to focus on differences in regional oil reservoirs and determine the priority of the CCUSEOR(Carbon capture,utilization,and storage-enhanced oil recovery) deployment under China’s net-zero CO_(2) emission target,systematic and regional evaluations of CO_(2) sequestration capacity in major oil basins are needed considering the geofluid properties―carbon sequestration capacity in place(CSCIP)―where the ’in place’ indicates actual geological formation conditions underground,e.g.,formation temperature and pressure.Therefore,physical properties of geofluids at different depths with different geologic temperatures and pressure conditions are considered for the CO_(2) sequestration capacity evaluation in place,including shallow(800–2000 m),medium(2000–3500 m),deep(3500–4500 m) and ultra-deep(4500–8000 m) depth intervals.A modified evaluation model with four grading levels is proposed,combining the P-V-T equations of state(EOS) and evaluation equations of the Carbon Sequestration Leadership Forum(CSLF),including theoretical,effective,practical,and CCUS-EOR CSCIP,which is more consistent with geofluid physical properties underground,to make the grading evaluation and ranking of the CSCIP in China’s major oil basins.Then,the grading CSCIP of 29 major oil basins in China was evaluated based on the petroleum resources evaluation results of the Ministry of Natural Resources of China(MNRC) during China’s 13th Five-Year Plan period.According to the grading evaluation results,suggestions for China’s CCUS-EOR prospective regions are given as follows:shallow oil fields of the Songliao Basin in Northeast China,shallow–medium oil fields of the Bohai Bay Basin in East China,medium oil fields of the Zhungeer Basin in West China,and medium oil fields of the Ordos Basin in Central China;all are potential areas for the CCUS-EOR geological sequestration in China’s onshore oil basins.In addition,in China’s offshore oil basins,shallow–medium oil fields of the Bohai Sea and shallow oil fields of the Pearl River Mouth Basin have potential for CCUS-EOR geological sequestration.