Effect of petroleum chemical fraction and residual oil content in saline lacustrine organic-rich shale: A case study from the Paleogene Dongpu Depression of North China

Halite and gypsum minerals in saline shale make the retention mechanism and chemical fractionation of residual oil unique. The Dongpu Depression in North China is a typically saline lacustrine basin with developing halite and gypsum. The effect of gypsum minerals on residual oil content and chemical fractionation remains unclear. In this study, shale samples with different gypsum contents were used in organic geochemical experiments, showing that the high total organic matter (TOC) content and type II kerogen leads to a high residual oil content, as shown by high values of volatile hydrocarbon (S1) and extractable organic matter (EOM). XRD and FE-SEM result indicate that the existence of gypsum in saline shale contributes to an enhanced pore space and a higher residual oil content in comparison to non-gypsum shale. Additionally, the increase in the gypsum mineral content leads to an increase in the saturated hydrocarbon percentage and a decrease in polar components percentage (resins and asphaltene). Furthermore, thermal simulation experiments on low-mature saline shale show that the percentage of saturated hydrocarbons in the residual oil is high and remains stable and that the storage space is mainly mesoporous (> 20 nm) in the oil expulsion stage. However, the saturated hydrocarbons percentage decreases rapidly, and oil exists in mesopores (> 20 nm and < 5 nm) in the gas expulsion stage. In general, gypsum is conducive to the development of pore space, the adsorption of hydrocarbons and the occurrence of saturated hydrocarbon, leading to large quantities of residual oil. The data in this paper should prove to be reliable for shale oil exploration in saline lacustrine basins.

Slope Instability Analysis of the Qiongdongnan Basin in the Northern Part of the South China Sea:Implications for the Risk Evaluation of Deepwater Drilling

The instability of continental slopes damages marine engineering equipment,such as submarine pipelines,resulting in the generation of tsunamis,which endangers the safety of nearshore personnel.Therefore,research on the instability of continental slopes where submarine landslides usually occur is crucial to the risk evaluation of deepwater drilling.Previous studies were mainly based on simplified 2D and 3D models,which extend the 2D model applied on submarine slopes with complex topography.In this study,a numerical model with bathymetric data from the Qiongdongnan Basin was established.Furthermore,3D slope stability analysis and static and dynamic analyses were conducted.The static analysis found two discussions where slopes are most likely to occur.Through the analysis of different seismic forces,the dynamic result showed that an instability area is added to the two positions where the static analysis is unstable.Topography scatters and transmits seismic waves and controls the accumulation and diffusion of seismic energy.3D calculations and analysis revealed that the direction of slope instability is closely related to terrain inclination,slope,terrain effect,and terrain curvature.Data showed that instability situations could not be derived from a single direction or profile data.Such situations are an important factor in slope stability analysis and are critical to the prediction and evaluation of marine geological disasters.

深水高温高压气井环空圈闭压力下油管柱安全评价方法

深水高温高压气井普遍存在环空带压现象,而深水井通常采用水下井口,使得B、C环空无法进行泄压操作,从而导致井下油管柱承受高环空圈闭压力载荷,同时附加高温、腐蚀多因素耦合影响,使得油管柱存在失效风险。针对深水高温高压气井环空圈闭压力下油管柱安全问题,基于深水井特性,综合考虑热膨胀和鼓胀效应引起的环空温度、环空体积、流体体积以及环空压力变化的动态耦合作用,建立深水高温高压气井圈闭压力预测模型,同时,考虑高环空圈闭压力载荷,附加高温及腐蚀多因素耦合影响,建立深水高温高压气井油管柱安全评价方法,开展了环空圈闭压力多因素影响下油管柱安全评价,并对模型进行了验证。结果表明:考虑环空圈闭压力影响后,环空圈闭压力随服役时间逐渐降低幅度远小于地层压力降低幅度,管柱抗外挤安全系数随服役时间降低幅度增大。同时,管柱内外流体压差随井深增加而逐渐增大,在井底管柱更易发生失效风险;在井筒高温及腐蚀耦合影响下,管柱抗内压、抗外挤及抗拉安全系数均呈现出不同程度的降低,特别井底段管柱受苛刻高温及腐蚀环境,附加高环空圈闭压力,使其更易发生失效风险,在设计及实际生产过程中,应重点管柱井底管柱安全风险。

Risk Assessment of Deep-Water Horizontal X-Tree Installation

Due to the high potential risk and many influencing factors of subsea horizontal X-tree installation,to guarantee the successful completion of sea trials of domestic subsea horizontal X-trees,this paper established a modular risk evaluation model based on a fuzzy fault tree.First,through the analysis of the main process oftree down and combining the Offshore&Onshore Reliability Data(OREDA)failure statistics and the operation procedure and the data provided by the job,the fault tree model of risk analysis of the tree down installation was established.Then,by introducing the natural language of expert comprehensive evaluation and combining fuzzy principles,quantitative analysis was carried out,and the fuzzy number was used to calculate the failure probability of a basic event and the occurrence probability of a top event.Finally,through a sensitivity analysis of basic events,the basic events of top events significantly affected were determined,and risk control and prevention measures for the corresponding high-risk factors were proposed for subsea horizontal X-tree down installation.

A Gel-Based Solidification Technology for Large Fracture Plugging

Fault fractures usually have large openings and considerable extension. Accordingly, cross-linked gel materials aregenerally considered more suitable plugging agents than water-based gels because the latter often undergo contaminationvia formation water, which prevents them from being effective over long times. Hence, in this study, aset of oil-based composite gels based on waste grease and epoxy resin has been developed. These materials havebeen observed to possess high compressive strength and resistance to the aforementioned contamination, therebyleading to notable increase in plugging success rate. The compressive strength, thickening time, and resistance toformation water pollution of these gels have been evaluated indoors. The results show that the compressivestrength of the gel can reach 11 MPa;additionally, the related gelation time can be controlled to be more than3 h, thereby providing a safe construction time;Invasion of formation water has a small effect on the gel strengthand does not shorten the thickening time. All considered performance indicators of the oil-based gel confirm itssuitability as a plugging agent for fault fractures.

海上无人钻井平台专用井口控制盘技术研究

传统井口控制盘远程操作功能不完善,提出无人钻井平台专用井口控制盘实现方案。通过新型推拉阀和多电磁阀系统的设计增强了该井口控制盘在远程操作和安全性上的能力,利用Amesim软件仿真模拟该控制盘的动态特性,验证了设计的可靠性和完整性。通过现场应用测试,验证了该井口控制盘功能稳定可靠。新井口控制盘可远程开启井上安全阀,为无人钻井平台的操作效率和安全性提供了解决思路。

液流空化技术在注采井间储层微改造中的应用--以渤海S油田B1-B2H井组为例

渤海S油田B1井,在注水过程中,注水井B1井注入压力逐渐升高,长期无法达到配注需求,对应生产井B2H#注水见效差,处于低效状态。其原因是距B1井100 m左右有低渗带存在,致使注水井与生产井之间储层连通性变差。因为常规措施处理半径有限,无法对这种低渗带进行改造。因此需要寻找新的工艺措施,既能满足处理半径足够大,同时对低渗带进行微改造。根据液流空化储层改造技术的原理可知,该技术可以满足这个条件。实施液流空化后,无论是注水井吸水能力还是对应生产井生产形势都得到了明显改善。该技术的成功实施,为其他油水井类似问题的解决指明了方向,可以有效改善其注水开发效果。

单作用气动执行器增大扭力方法探究与应用

单作用气动关断阀在失气时,依靠弹簧对阀门进行复位,而对于阀体为球型阀门的气动关断阀,如果扭力不足,很容易出现阀门卡阻现象,起不到应有的安全保护作用,存在很大的风险隐患。通过分析气动关断阀的内部结构,总结阀门卡阻故障原因,本着降本增效的理念,对比分析了3种增大执行器扭力的方法,在不改变原设计基础上,探究增大扭力的创新方案,提高关断阀安全可靠性。

海上平台金属腐蚀与防护研究

主要讨论了海上石油平台中金属腐蚀的类型、机理、影响因素及防护措施。腐蚀类型包括均匀腐蚀和局部腐蚀(点蚀、缝隙腐蚀、应力腐蚀开裂、腐蚀疲劳),其成因涉及电化学、化学反应以及微生物作用。海水的盐分、湿气、氧气、温度变化和生物侵蚀是腐蚀的主要驱动因素。通过深入分析腐蚀类型和成因,可探索更有效的腐蚀防护策略,以提高平台的安全性和可靠性。

Limit analysis of extended reach drilling in South China Sea

Extended reach wells （ERWs）, especially horizontal extended reach well with a high HD （horizontal displacement） to TVD （true vertical depth） ratio, represent a frontier technology and challenge the drilling limitations. Oil and gas reservoir in beaches or lakes and offshore can be effectively exploited by using extended reach drilling （ERD） technology. This paper focuses on the difficult technological problems encountered during exploiting the Liuhua 11-1 oil field in the South China Sea, China. Emphasis is on investigating the key subjects including prediction and control of open hole limit extension in offshore ERD, prediction of casing wear and its prevention and torque reduction, φ244.5mm casing running with floating collars to control drag force, and steerable drilling modes. The basic concept of limit extension in ERD is presented and the prediction method for open hole limit extension is given in this paper. A set of advanced drilling mechanics and control technology has been established and its practical results are verified by field cases. All those efforts may be significant for further investigating and practicing ERD limit theory and control technology in the future.

Sedimentary hydrodynamic study of sand bodies in the upper subsection of the 4th Member of the Paleogene Shahejie Formation in the eastern Dongying Depression, China

Petroleum is produced from a beach-bar sand reservoir in the upper subsection of the 4th member of the Paleogene Shahejie Formation （Es4s） in the eastern Dongying Depression,penetrated by many wells in the Guangli-Qingnan area and this subsection still has further exploration potential.Using drilling and logging data,we analyzed the sand body types,emphasizing the sedimentary characteristics of the beach-bar sand bodies.Combining these data with the concepts of lacustrine and oceanic hydrodynamics,we explain the formation and distribution of the beach-bar sands in the eastern Dongying Depression.The connectivity between beach-bar sand bodies within each individual hydrodynamic zone is better than that between sand bodies in any two adjacent zones.The tempestite sand bodies developed in this area are characterized by typical storm deposits and are located at the bottoms of the beachbar sand bodies.They grade upward to normal shore and shallow-lacustrine beaches and bars.We also propose a new simple method to estimate the paleo-water depth using the thicknesses of the bar sand bodies in parasequences combined with the principle of hydrodynamic zonation.Based on the distribution of the beach-bar sands in parasequence set 3,we infer that the paleo-wind direction was from the north with an average paleo-wind force of 6 when the major beach-bar sand bodies formed.

Zircon U-Pb Dating on Granitoids from the Northern South China Sea and its Geotectonic Relevance

Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165-100 Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165-150 Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong （148-130 Ma） to the Pearl River Mouth basin （127-112 Ma）, corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108-97 Ma. A tectonic transformation from slab-subduction to extension should occur at -100 Ma.

Detrital K-feldspar^(40)Ar/^(39)Ar Ages:Source Constraints of the Lower Miocene Sandstones in the Pearl River Mouth Basin,South China Sea

The South China Sea began to outspread in the Oligocene. A great quantity of terraneous detritus was deposited in the northern continental shelf of the sea, mostly in Pearl River Mouth Basin, which constituted the main paleo-Pearl River Delta. The delta developed for a long geological time and formed a superimposed area. Almost all the oil and gas fields of detrital rock reservoir distribute in this delta. Thirty-three oil sandstone core samples in the Zhujiang Formation, lower Miocene （23-16 Ma）, were collected from nine wells. The illite samples with detrital K feldspar （Kfs） separated from these sandstone cores in four sub-structural belts were analysed by the high-precision 40Ar/39Ar laser stepwise heating technique. All 33 illite 40Ar/39Ar data consistently yielded gradually rising age spectra at the low-temperature steps until reaching age plateaus at mid-high temperature steps. The youngest ages corresponding to the beginning steps were interpreted as the hydrocarbon accumulation ages and the plateau ages in mid-high temperature steps as the contributions of the detrital feldspar representing the ages of the granitic parent rocks in the provenances. The ages of the detrital feldspar from the Zhujiang Formation in the four sub-structural belts were different： （1） the late Cretaceous ages in the Lufeng 13 fault structural belt; （2） the late Cretaceous and early Cretaceous-Jurassic ages in the Huizhou 21 buried hill-fault belt; （3） the Jurassic and Triassic ages in the Xijiang 24 buried hill-fault belt; and （4） the early Cretaceous - late Jurassic ages in the Panyu 4 oil area. These detrital feldspar 4~Ar/39Ar ages become younger and younger from west to east, corresponding to the age distribution of the granites in the adjacent Guangdong Province, Southern China.

The Southward Extension of Cathaysia Block: Evidence from Zircon UPb Dates of Borehole Volcanics in the Northern South China Sea

Five Paleogene volcanics sampled from the northern South China Sea were analyzed via LA-ICP-MS zircon U-Pb dating, including basalt and andesite from Borehole SCSVI and volcanic agglomerate from Borehole SCSV2, respectively. A total of 162 zircon U-Pb dates for them cover an age range from Neoarchean to Eocene, in which the pre-Paleocene data dominate. The Paleogene dates of 62.5±2.2 Ma and 42.1±2.9 Ma are associated with two igneous episodes prior to opening of South China Sea basin. Those pre-Paleocene zircons are inherited zircons mostly with magmatogenic oscillatory zones, and have REE features of crustal zircon. Zircon U-Pb dates of 2518-2481 Ma, 1933- 1724 Ma, and 1094-1040 Ma from the SCSV1 volcanics, and 2810-2718 Ma, 2458-2421 Ma, and 1850-993.4 Ma from the SCSV2 volcanics reveal part of Precambrian evolution of the northern South China Sea, well comparable with age records dated from the Cathaysia block. The data of 927.0±6.9 Ma and 781±38 Ma dated from the SCSV2 coincide with amalgamation between Yangtze and Cathaysia blocks and breakup of the Rodinia, respectively. The age records of Caledonian orogeny from the Cathaysia block are widely found from our volcanic samples with concordant mean ages of 432.0±5.8 Ma from the SCSV1 and of 437±15 Ma from the SCSV2. The part of the northern South China Sea resembling the Cathaysia underwent Indosinian and Yanshannian tectonothermal events. Their age signatures from the SCSV1 cover 266.5±3.5 Ma, 241.1±6.0 Ma, 184.0±4.2 Ma, 160.9±4.2 Ma and 102.8±2.6 Ma, and from the SCSV2 are 244±15 Ma, 158.1±3.5 Ma, 141±13 Ma and 96.3±2.1 Ma. Our pre-Paleogene U-Pb age spectra of zircons from the borehole volcanics indicate that the northern South China Sea underwent an evolution from formation of Precambrian basement, Caledonian orogeny, and Indosinian orogeny to Yanshannian magmatism. This process can be well comparable with the tectonic evolution of South China, largely supporting the areas of the northern South China Sea as part of southward extension of the Cathaysia.

Upper Paleozoic coal measures and unconventional natural gas systems of the Ordos Basin,China

在 Ordos 盆的上面的古生代的煤措施由黑暗 mudstone 和煤床组成并且是为煤气的产生的重要来源岩石。煤气的累积包括煤床甲烷(CBM ) ，在不同结构的区域的紧密的煤气、常规的气体。CBM 累积主要在 Ordos 盆的边缘的区域被散布，并且在 3.5 氠睯爠湡 ? 潣污甠?污祬栠獡氠睯洠瑥慨敮猠牯瑰潩 ? 慣慰楣祴愠摮椠獴瀠牯 ? 湡 ? 業牣景慲瑣牵獥愠敲瀠潯汲 ? 敤敶潬数被估计吗？

Recovery of the Erosion Thickness and Characterization of the Paleogeomorphology in the Southern Lishui Sag, East China Sea Shelf Basin

The restoration of the denudation thickness is the basis for quantitatively analyzing the basin burial history,thermal evolution history and hydrocarbon accumulation conditions.The well data is not sufficient to do this in the southern Lishui Sag with only 5 wells,so the new,high-quality three-dimensional(3D)seismic data is essential.The methods employed to determine the eroded thicknesses of key unconformities in the study area are the mudstone acoustic time difference(AC)method,vitrinite reflectance(Ro%)method and stratigraphic trend comparison method.On the basis of the structural evolution,the restoration of the paleogeomorphology is carried out.The results show that the Wenzhou formation(E2 w)in the entire study area has been all denuded.The denudation thickness is in the range of 0–550 m,and decreases gradually from west,thicker than 200 m,to east.The erosion of the upper Lingfeng formation(E1l)are mainly occurred in the N-P-1 structural trap(N-P-1),the N-P-2 structural trap(N-P-2)and the N-P-3 structural trap(N-P-3).Among them,the eroded area in N-P-1(near well S-1)and N-P-2 is 200–230 km^2,and the denudation thickness is 0–600 m,which increases from south to north,even up to 200–400 m in the region around well S-1.In N-P-3,the extent of denudation is 30–50 km^2,and the denudation thickness is 0–400 m.In the early stage of the upper E1 l,one north-south strike slip fault began to develop in the southern study area.Affected by this fault,the southern Lingfeng bulge was offset,forming a gorge,and the eastern and western sides of the concave belt connected to each other.On the basis of the paleo-geomorphological characteristics,it is shown that the sedimentary center of the west subsag began to migrate to the south.

Peat formation and accumulation mechanism in northern marginal basin of South China Sea

In the present study,the coal-rock organic facies of Oligocene Yacheng Formation of the marginal basin in the South China Sea were classified and divided.In addition,through the correlations of the large-scale coal-bearing basins between the epicontinental sea and the South China Sea,it was concluded that the coal forming activities in the South China Sea presented particularity and complexity.Furthermore,the coal forming mechanisms also presented distinctiveness.The marginal basins in the South China Sea consist of several large and complex rift or depression basins,which are distributed at different tectonic positions in the South China Sea.Therefore,the marginal basins in the South China Sea are not simple traditional units with onshore continental slopes extending toward the deep sea.The marginal basins are known to consist of multi-level structures and distinctive types of basins which differ from the continental regions to the sea.During the Oligocene,the existing luxuriant plants and beneficial conditions assisted in the development of peat.Therefore,the Oligocene was the significant period for the formation and aggregation of the peat.However,the peat did not form in unified sedimentary dynamic fields,but instead displayed multi-level geographical units,multiple provenance areas,instability,and nonevent characteristics.As a result,the marginal basins in the South China Sea are characterized by non-uniform peat aggregation stages.In another words,the majority of the peat had entered the marine system in a dispersive manner and acted as part of the marine deposits,rather than during one or several suitable coal-forming stages.These peat deposits then became the main material source for hydrocarbon generation in all of the marginal basins of the South China Sea.The study will be of much significance for the hydrocarbon exploration in the marginal basins of the South China Sea.

Formation conditions and exploration direction of large natural gas reservoirs in the oil-prone Bohai Bay Basin, East China

The Bohai Bay Basin is a typical oil-prone basin, in which natural gas geological reserves have a small proportion. In this basin, the gas source rock is largely medium-deep lake mudstone with oil-prone type Ⅱ2-Ⅱ1 kerogens, and natural gas preservation conditions are poor due to active late tectonic movements. The formation conditions of large natural gas fields in the Bohai Bay Basin have been elusive. Based on the exploration results of Bohai Bay Basin and comparison with large gas fields in China and abroad, the formation conditions of conventional large-scale natural gas reservoirs in the Bohai Bay Basin were examined from accumulation dynamics, structure and sedimentation. The results show that the formation conditions of conventional large natural gas reservoirs in Bohai Bay Basin mainly include one core element and two key elements. The core factor is the strong sealing of Paleogene "quilt-like" overpressure mudstone. The two key factors include the rapid maturation and high-intensity gas generation of source rock in the late stage and large scale reservoir. On this basis, large-scale nature gas accumulation models in the Bohai Bay Basin have been worked out, including regional overpressure mudstone enriching model, local overpressure mudstone depleting model, sand-rich sedimentary subsag depleting model and late strongly-developed fault depleting model. It is found that Bozhong sag, northern Liaozhong sag and Banqiao sag have favorable conditions for the formation of large-scale natural gas reservoirs, and are worth exploring. The study results have important guidance for exploration of large scale natural gas reservoirs in the Bohai Bay Basin.

Diagenesis-porosity evolution and“sweet spot”distribution of low permeability reservoirs:A case study from Oligocene Zhuhai Formation in Wenchang A sag,Pear River Mouth Basin,northern South China Sea

The characteristics of low permeability reservoirs and distribution of sweet spots in the Oligocene Zhuhai Formation of Wenchang A sag, Pearl River Basin were investigated by core observation and thin section analysis. The study results show that there develop the fine, medium and coarse sandstone reservoirs of tidal flat–fan delta facies, which are of mostly low permeability and locally medium permeability. There are two kinds of pore evolution patterns: oil charging first and densification later, the reservoirs featuring this pattern are mainly in the third member of Zhuhai Formation between the south fault zone and the sixth fault zone, and the pattern of densification first and gas charging later is widespread across the study area. Strong compaction and local calcium cementation are the key factors causing low permeability of the reservoirs in the Zhuhai Formation. Thick and coarse grain sand sedimentary body is the precondition to form "sweet spot" reservoirs. Weak compaction and cementation, dissolution, early hydrocarbon filling and authigenic chlorite coating are the main factors controlling formation of "sweet spot" reservoir. It is predicted that there develop between the south fault and sixth fault zones the Class Ⅰ "sweet spot" in medium compaction zone, Class Ⅱ "sweet spot" in nearly strong compaction zone, Class Ⅲ "sweet spot" reservoir in the nearly strong to strong compaction zone with oil charging at early stage, and Class IV "sweet spot" reservoir in the strong compaction and authigenic chlorite coating protection zone in the sixth fault zone.

Factors controlling the development of tight sandstone reservoirs in the Huagang Formation of the central inverted structural belt in Xihu sag, East China Sea Basin

By means of thin section analysis, zircon U-Pb dating, scanning electron microscopy, electron probe, laser micro carbon and oxygen isotope analysis, the lithologic features, diagenetic environment evolution and controlling factors of the tight sandstone reservoirs in the Huagang Formation of Xihu sag, East China Sea Basin were comprehensively studied. The results show that: the sandstones of the Huagang Formation in the central inverted structural belt are poor in physical properties, dominated by feldspathic lithic quartz sandstone, high in quartz content, low in matrix, kaolinite and cement contents, and coarse in clastic grains;the acidic diagenetic environment formed by organic acids and meteoric water is vital for the formation of secondary pores in the reservoirs;and the development and distribution of the higher quality reservoirs in the tight sandstones of the Huagang Formation are controlled by sediment source, sedimentary facies belt, abnormal overpressure and diagenetic environment evolution. Sediment provenance and dominant sedimentary facies led to favorable initial physical properties of the sandstones in the Huagang Formation, which is the prerequisite for development of reservoirs with better quality later. Abnormal high pressure protected the primary pores, thus improving physical properties of the reservoirs in the Huagang Formation. Longitudinally, due to the difference in diagenetic environment evolution, the high-quality reservoirs in the Huagang Formation are concentrated in the sections formed in acidic diagenetic environment. Laterally, the high-quality reservoirs are concentrated in the lower section of the Huagang Formation with abnormal high pressure in the middle-northern part;but concentrated in the upper section of Huagang Formation shallower in burial depth in the middle-southern part.