A new model of flow over stretching(shrinking)and porous sheet with its numerical solutions

The viscous fluid flow and heat transfer over a stretching(shrinking)and porous sheets of nonuniform thickness are investigated in this paper.The modeled problem is presented by utilizing the stretching(shrinking)and porous velocities and variable thickness of the sheet and they are combined in a relation.Consequently,the new problem reproduces the different available forms of flow motion and heat transfer maintained over a stretching(shrinking)and porous sheet of variable thickness in one go.As a result,the governing equations are embedded in several parameters which can be transformed into classical cases of stretched(shrunk)flows over porous sheets.A set of general,unusual and new variables is formed to simplify the governing partial differential equations and boundary conditions.The final equations are compared with the classical models to get the validity of the current simulations and they are exactly matched with each other for different choices of parameters of the current problem when their values are properly adjusted and manipulated.Moreover,we have recovered the classical results for special and appropriate values of the parameters(δ_(1),δ_(2),δ_(3),c,and B).The individual and combined effects of all inputs from the boundary are seen on flow and heat transfer properties with the help of a numerical method and the results are compared with classical solutions in special cases.It is noteworthy that the problem describes and enhances the behavior of all field quantities in view of the governing parameters.Numerical result shows that the dual solutions can be found for different possible values of the shrinking parameter.A stability analysis is accomplished and apprehended in order to establish a criterion for the determinations of linearly stable and physically compatible solutions.The significant features and diversity of the modeled equations are scrutinized by recovering the previous problems of fluid flow and heat transfer from a uniformly heated sheet of variable(uniform)thickness with variable(uniform)stretching/shrinking and injection/suction velocities.

Effect of heat treatment on microstructure and thermophysical properties of diamond/2024 Al composites

50%diamond particle （5μm） reinforced 2024 aluminum matrix （diamond/2024 Al） composites were prepared by pressure infiltration method. Diamond particles were distributed uniformly without any particle clustering, and no apparent porosities or significant casting defects were observed in the composites. The diamond-Al interfaces of as-cast and annealed diamond/2024 Al composites were clean, smooth and free from interfacial reaction product. However, a large number of Al2Cu precipitates were found at diamond-Al interface after aging treatment. Moreover, needle-shaped Al2MgCu precipitates in Al matrix were observed after aging treatment. The coefficient of thermal expansion （CTE） of diamond/2024 Al composites was about 8.5×10-6 °C-1 between 20 and 100 °C, which was compatible with that with chip materials. Annealing treatment showed little effect on thermal expansion behavior, and aging treatment could further decrease the CTE of the composites. The thermal conductivity of obtained diamond/2024 Al composites was about 100 W/（m？K）, and it was slightly increased after annealing while decreased after aging treatment.

Size control synthesis of sulfur doped titanium dioxide (anatase) nanoparticles,its optical property and its photo catalytic reactivity for CO_2 + H_2O conversion and phenol degradation

Sulfur doped anatase TiO2 nanoparticles （3 nm- 12 nm） were synthesized by the reaction of titanium tetrachloride, water and sulfuric acid with addition of 3 M NaOH at room temperature. The electro-optical and photocatalytic properties of the synthesized sulfur doped TiO2 nanoparticles were studied along with Degussa commercial TiO2 particles （24 nm）. The results show that band gap of TiO2 particles decreases from 3.31 to 3.25 eV and for that of commercial TiO2 to 3.2 eV when the particle sizes increased from 3 nm to 12 nm with increase in sulfur doping. The results of the photocatalytic activity under UV and sun radiation show maximum phenol conversion at the particle size of 4 nm at 4.80% S-doping. Similar results are obtained using UV energy for both phenol conversion and conversion of CO2＋H2O in which formation of methanol, ethanol and proponal is observed. Production of methanol is also achieved on samples with a particle size of 8 and 12 nm and sulfur doping of 4.80% and 5.26%. For TiO2 particle of 4 nm without S doping, the production of methanol, ethanol and proponal was lower as compared to the S-doped particles. This is attributed to the combined electronic effect and band gap change, S dopant, specific surface area and the light source used.

Fungi as chemical industries and genetic engineering for the production of biologically active secondary metabolites

Fungi is somewhere in between the micro and macro organisms which is a good source of producing biologically active secondary metabolites.Fungi have been used as tool for producing different types of secondary metabolites by providing different nutrients at different laboratory conditions.The fungi have been engineered for the desired secondary metabolites by using different laboratory techniques,for example,homologous and heterologous expressions.This review reported how the fungi are used as chemical industry for the production of secondary metabolites and how they are engineered in laboratory for the production of desirable metabolites:also the biosynthetic pathways of the bio-organic-molecules were reported.

Molecular genetic and genomic analysis of wheat milling and end-use traits in China:Progress and perspectives

Wheat is the most widely cultivated staple food crop, and multiple types of food derivatives are processed and consumed globally. Wheat grain quality(WGQ) is central to food processing and nutritional value, and is a decisive factor for consumer acceptance and commercial value of wheat cultivars. Hence, improvement in WGQ traits is top priority for both conventional and molecular wheat breeding. In this review we will focus on two important WGQ traits, grain milling and end-use, and will summarize recent progress in China. Chinese scientists have invested substantial effort in molecular genetic and genomic analysis of these traits and their effects on end-use properties. The insights and resources generated have contributed to the understanding and improvement of these traits. As high-quality genomics information and powerful genome engineering tools are becoming available for wheat, more fundamental breakthroughs in dissecting the molecular and genomic basis of WGQ are expected. China will strive to make further significant contributions to the study and improvement of WGQ in the genomics era.

Effects of partial slip on flow of a third grade fluid

This paper is an analytical study of the rotating flow of a third grade fluid past a porous plate with partial slip effects. It serves as a flow model for the study of polymers. The analytic solution has been determined using homotopy analysis method （HAM）.

Heat transfer analysis in peristaltic flow of MHD Jeffrey fluid with variable thermal conductivity

The effect of an inclined magnetic field in the peristaltic flow of a Jeffrey fluid with variable thermal conductivity is discussed. The temperature dependent thermal conductivity of fluid in an asymmetric channel is taken into account. A dimensionless nonlinear system subject to a long wavelength and a low Reynolds number is solved. The explicit expressions of the stream function, the axial velocity, the pressure gradient, and the temperature are obtained. The effects of all physical parameters on peristaltic transport and heat transfer characteristics are observed from graphical illustrations. The behaviors of θ∈ [0, π/2] and θ∈ [π/2, π] on fluid flow and heat transfer are found to be opposite. Further, the size of trapped bolus is greater for the case of the inclined magnetic field （θ≠ π/2） than that for the case of the transverse magnetic field （θ = π/2）. The heat transfer coefficient decreases when the constant thermal conductivity （Newtonian） fluid is changed to the variable thermal conductivity （Jeffrey） fluid.

On the MHD flow of fractional generalized Burgers' fluid with modified Darcy's law

This work is concerned with applying the fractional calculus approach to the magnetohydrodynamic （MHD） pipe flow of a fractional generalized Burgers＇ fluid in a porous space by using modified Darcy＇s relationship. The fluid is electrically conducting in the presence of a constant applied magnetic field in the transverse direction. Exact solution for the velocity distribution is developed with the help of Fourier transform for fractional calculus. The solutions for a Navier-Stokes, second grade, Maxwell, Oldroyd-B and Burgers＇ fluids appear as the limiting cases of the present analysis.

ON A CLASS OF ANALYTIC FUNCTIONS RELATED TO CONIC DOMAINS AND ASSOCIATED WITH CARLSON-SHAFFER OPERATOR

Making use of the Carlson-Shaffer convolution operator, we introduce and study a new class of analytic functions related to conic domains. The main object of this paper is to investigate inclusion relations, coefficient bound for this class. We also show that this class is closed under convolution with a convex function. Some applications are also discussed.

Structural and optical properties of thermally reduced graphene oxide for energy devices

Natural intercalation of the graphite oxide, obtained as a product of Hummer＇s method, via ultra-sonication of water dispersed graphite oxide has been carried out to obtain graphene oxide（GO） and thermally reduced graphene oxide（RGO）.Here we report the effect of metallic nitrate on the oxidation properties of graphite and then formation of metallic oxide（MO） composites with GO and RGO for the first time. We observed a change in the efficiency of the oxidation process as we replaced the conventionally used sodium nitrate with that of nickel nitrate Ni（NO_3）_2, cadmium nitrate Cd（NO_3）_2,and zinc nitrate Zn（NO_3）_2. The structural properties were investigated by x-ray diffraction and observed the successful formation of composite of MO–GO and MO–RGO（M = Zn, Cd, Ni）. We sought to study the effect on the oxidation process through optical characterization via UV-Vis spectroscopy and Fourier Transform Infrared（FTIR） spectroscopy.Moreover, Thermo Gravimetric Analysis（TGA） was carried out to confirm 〉 90% weight loss in each process thus proving the reliability of the oxidation cycles. We have found that the nature of the oxidation process of graphite powder and its optical and electrochemical characteristics can be tuned by replacing the sodium nitrate（NaNO_3） by other metallic nitrates as Cd（NO_3）_2, Ni（NO_3）_2, and Zn（NO_3）_2. On the basis of obtained results, the synthesized GO and RGO may be expected as a promising material in antibacterial activity and in electrodes fabrication for energy devices such as solar cell, fuel cell,and super capacitors.

Entropy squeezing of an atom with a k-photon in the Jaynes-Cummings model

The entropy squeezing of an atom with a k-photon in the Jaynes Cummings model is investigated. For comparison, we also study the corresponding variance squeezing and atomic inversion. Analytical results show that entropy squeezing is preferable to variance squeezing for zero atomic inversion. Moreover, for initial conditions of the system the relation between squeezing and photon transition number is also discussed. This provides a theoretical approach to finding out the optimal entropy squeezing.

Antibiotic susceptibility profiling and virulence potential of Campylobacter jejuni isolates from different sources in Pakistan

Objective:To determine antibiotic resistance patterns and virulence potential of Campylobacter jejuni(C.jejuni) isolates from clinical human diarrheal infections,cattle and healthy broilers.Methods:Antibiotic sensitivity patterns of C.jejuni isolates were determined by Kirby Bauer Disc Diffusion assay.These isolates were then subjected to virulence profiling for the detection of map A(membrane-associated protein).cadF(fibronectin binding protein).wlaN(beta-1.3-galaclosyltransferase) and neu AB(sialic acid biosynthesis gene).Further C.jejuni isolates were grouped by random amplification of polymorphic DNA(RAPD) profiling.Results:A total of436 samples from poultry(n=88).cattle(n=216) and humans(n=132) from different locations were collected.Results revealed percentage of C.jejuni isolates were 35.2%(31/88).25.0%(54/216) and 11.3%(15/132) among poultry,cattle and clinical human samples respectively.Antibiotic susceptibility results showed that similar resistance patterns to cephalothin was ie.87.0%,87.1%and 89%among humans,poultry and cattle respectively,followed by sulfamethoxazolc+trimcthoprim 40.0%,38.7%and 31.0%in humans,poultry and cattle and Ampicillin 40%,32%and 20%in humans,poultry and cattle respectively.Beta-lactamase activity was detected in 40.00%humans.20.37%cattle and 32.25%in poultry C.jejuni isolates.CadF and mapA were present in all poultry,cattle and human C jejuni isolates.wlauN was not detected in any isolate and neu AB was found in 9/31(36%) poultry isolates.RAPD profiling results suggested high diversity of C.jejuni isolates.Conclusions:Detection of multidrug resistant C.jejuni strains from poultry and cattle is alarming as they can be potential hazard to humans.Moreover,predominant association of virulence factors,cadF and map A(100%each) in C.jejuni isolates from all sources and neuAB(36%) with poultry isolates suggest the potential source of transmission of diverse types of C.jejuni to humans.

Numerical simulation of chemically reactive Powell-Eyring liquid flow with double diffusive Cattaneo-Christov heat and mass flux theories

A numerical study is reported for two-dimensional flow of an incompressible Powell-Eyring fluid by stretching the surface with the Cattaneo-Christov model of heat diffusion. Impacts of heat generation/absorption and destructive/generative chemical reactions are considered. Use of proper variables leads to a system of non-linear dimensionless expressions. Velocity, temperature and concentration profiles are achieved through a finite difference based algorithm with a successive over-relaxation(SOR) method. Emerging dimensionless quantities are described with graphs and tables. The temperature and concentration profiles decay due to enhancement in fluid parameters and Deborah numbers.

Excitation of defect modes from the extended photonic band-gap structures of 1D photonic lattices

This paper stuides numerically the model equation in a one dimensional defective photonic lattice by modifying the potential function to a periodic function. It is found that defect modes （DMs） can be regarded as Bloch modes which are excited from the extended photonie band-gap structure at Bloch wave-numbers with kx = 0. The DMs for both positive and negative defects are considered in this method.

Boundary layer flow of third grade nanofluid with Newtonian heating and viscous dissipation

Two-dimensional boundary layer flow of an incompressible third grade nanofluid over a stretching surface is investigated.Influence of thermophoresis and Brownian motion is considered in the presence of Newtonian heating and viscous dissipation.Governing nonlinear problems of velocity, temperature and nanoparticle concentration are solved via homotopic procedure.Convergence is examined graphically and numerically. Results of temperature and nanoparticle concentration are plotted and discussed for various values of material parameters, Prandtl number, Lewis number, Newtonian heating parameter, Eckert number and thermophoresis and Brownian motion parameters. Numerical computations are performed. The results show that the change in temperature and nanoparticle concentration distribution functions is similar when we use higher values of material parameters β1 andβ2. It is seen that the temperature and thermal boundary layer thickness are increasing functions of Newtonian heating parameter γ.An increase in thermophoresis and Brownian motion parameters tends to an enhancement in the temperature.

Application of the Method of Characteristics to Population Balance Models Considering Growth and Nucleation Phenomena

The population balance modeling is regarded as a universally accepted mathematical framework for dynamic simulation of various particulate processes, such as crystallization, granulation and polymerization. This article is concerned with the application of the method of characteristics (MOC) for solving population balance models describing batch crystallization process. The growth and nucleation are considered as dominant phenomena, while the breakage and aggregation are neglected. The numerical solutions of such PBEs require high order accuracy due to the occurrence of steep moving fronts and narrow peaks in the solutions. The MOC has been found to be a very effective technique for resolving sharp discontinuities. Different case studies are carried out to analyze the accuracy of proposed algorithm. For validation, the results of MOC are compared with the available analytical solutions and the results of finite volume schemes. The results of MOC were found to be in good agreement with analytical solutions and superior than those obtained by finite volume schemes.

Evolution of plasma parameters in an Ar-N2/He inductive plasma source with magnetic pole enhancement

Magnetic pole enhanced inductively coupled plasmas （MaPE-ICPs） are a promising source for plasma-based etching and have a wide range of material processing applications. In the present study Langmuir probe and optical emission spectroscopy were used to monitor the evolution of plasma parameters in a MaPE-ICP Ar-Na/He mixture plasma. Electron density （ne） and temperature （Te）, excitation temperature （Texc）, plasma potential （Vp）, skin depth （6） and the evolution of the electron energy probability function （EEPF） are reported as a function of radiofrequency （RF） power, pressure and argon concentration in the mixture. It is observed that ne increases while Te decreases with increase in RF power and argon concentration in the mixture. The emission intensity of the argon line at 750.4 nm is also used to monitor the variation of the ‘high-energy tail＇ of the EEPF with RF power and gas pressure. The EEPF has a ‘bi-Maxwellian＇ distribution at low RF powers and higher pressure in a pure N2 discharge. However, it evolves into a ‘Maxwellian＇ distribution at RF powers greater than 70 W for pure N2, and at 50 W for higher argon concentrations in the mixture. The effect of argon concentration on the temperatures of two electron groups in the ‘bi-Maxwellian＇ EEPF is examined. The temperature of the low-energy electron group TL shows a decreasing trend with argon addition until the ‘thermalization＇ of the two temperatures occurs, while the temperature of high-energy electrons Ta decreases continuously.

Seismic Hazard Assessment of District Mansehra,Khyber Pakhtoonkhawa,Pakistan

The site of Mansehra is located seismically in an active regime, known as the Crystalline Nappe Zone and Hazara-Kashmir Syntaxis in NW Himalayas, Pakistan. Seismic Hazard Assessment （SHA） for the site has been carried out by considering the earthquake source zones, selection of appropriate attenuation equations, near fault effects and maximum potential magnitude estimation. The Mansehra Thrust, Oghi Fault, Banna Thrust, Balakot Shear Zone, Main Boundary Thrust, Panjal Thrust, Jhelum Fault and Muzaffarabad Fault and, further to the south, the Sanghargali, Nathiagali, and Thandiani Thrusts are the most critical tectonic features within the 50 km radius of Mansehra. Using the available instrumental seismological data from 1904 to 2007, SHA has been carried out. Other reactivated critical tectonic features in the area have been investigated. Among them the Balakot-Bagh fault, with the fault length of 120 km from Balakot to Poonch, has been considered as the most critical tectonic feature on the basis of geological/structural/seismological data. The potential earthquake of maximum magnitude 7.8 has been assigned to the Balakot-Bagh fault using four regression relations. The peak ground acceleration value of 0.25 g （10% probability of exceedance for 50 years） and 0.5 g has been calculated with the help of the attenuation equation using probabilistic and deterministic approaches.

Evaluation of Ordinary Least Square(OLS) and Geographically Weighted Regression(GWR) for Water Quality Monitoring:A Case Study for the Estimation of Salinity

Landsat-5 Thematic Mapper(TM) dataset have been used to estimate salinity in the coastal area of Hong Kong. Four adjacent Landsat TM images were used in this study, which was atmospherically corrected using the Second Simulation of the Satellite Signal in the Solar Spectrum(6S) radiative transfer code. The atmospherically corrected images were further used to develop models for salinity using Ordinary Least Square(OLS) regression and Geographically Weighted Regression(GWR) based on in situ data of October 2009. Results show that the coefficient of determination(R^2) of 0.42 between the OLS estimated and in situ measured salinity is much lower than that of the GWR model, which is two times higher(R^2 = 0.86). It indicates that the GWR model has more ability than the OLS regression model to predict salinity and show its spatial heterogeneity better. It was observed that the salinity was high in Deep Bay(north-western part of Hong Kong) which might be due to the industrial waste disposal, whereas the salinity was estimated to be constant(32 practical salinity units) towards the open sea.

Flow-injection Determination of Cysteine,N-Acetyl Cysteine and Glutathione in Pharmaceuticals via Potassium Ferricyanide-Fe(Ⅲ) Spectrophotometric System

A simple flow injection spectrophotometric method is reported for the determination of cysteine,N-acetyl cysteine and glutathione based on the reduction of Fe（Ⅲ）/ferricyanide,the in situ reduced ions are reacted with unreduced portion of ferricyanide/Fe（Ⅲ） to form soluble Prussian blue,which is monitored at 735 nm.The calibration graphs are linear in the concentration ranges of（1―100）×10-6 mol/L for cysteine and N-acetyl cysteine,and（1―50）×10-6 mol/L for glutathione.The relative standard deviations of 1.8%,2.5% and 1.9% were found for eleven replicate analyses of 5×10-6 mol/L cysteine,N-acetyl cysteine and glutathione.The limits of detection（3σ blank） at 5×10-7 mol/L for cysteine,and 3×10-7 mol/L for N-acetyl cysteine and glutathione were obtained.The proposed method allowed 60 injections/h.The effects of common substances present in pharmaceuticals and human physiological fluids were examined.The method was applied to determining cysteine in pharmaceutical formulations with the recoveries in a range of 97% to 106% and the results obtained are agreed well with labeled values.