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甲基丙烯酸甲酯聚合动力学和分子量模型及仿真 被引量:5
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作者 单国荣 Gilles Fevotte Yann LE Gorrec 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2002年第11期2182-2187,共6页
考虑甲基丙烯酸甲酯聚合过程中体积收缩 ,反应物和生成物的浓度变化 ,以及由于凝胶、玻璃化和笼闭等效应对各速率常数和物性参数的影响 ,从基元反应和物料平衡出发 ,推导了半间歇、有链转移剂参与情况下的聚合动力学和分子量模型 .用模... 考虑甲基丙烯酸甲酯聚合过程中体积收缩 ,反应物和生成物的浓度变化 ,以及由于凝胶、玻璃化和笼闭等效应对各速率常数和物性参数的影响 ,从基元反应和物料平衡出发 ,推导了半间歇、有链转移剂参与情况下的聚合动力学和分子量模型 .用模型仿真计算了聚合温度、引发剂、溶剂和链转移剂的种类和浓度等对甲基丙烯酸甲酯聚合动力学和聚合过程中分子量变化的影响规律 ,并与实验和文献数据进行比较 . 展开更多
关键词 甲基丙烯酸甲酯 聚合动力学 分子量模型 仿真 聚甲基丙烯酸甲酯
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A Convective Thin Layer Drying Model with Shrinkage for Kent Mango Slices 被引量:1
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作者 Alfa Oumar Dissa Hélène Desmorieux Jean Koulidiati 《Advances in Chemical Engineering and Science》 2016年第1期20-28,共9页
In this work, a model of convective drying of mango slices was developed and validated by experiments. This model was established by considering slices shrinkage in the energy and the mass balances during the thin lay... In this work, a model of convective drying of mango slices was developed and validated by experiments. This model was established by considering slices shrinkage in the energy and the mass balances during the thin layer drying. The drying kinetics and the temperature curves of the product were simulated using the model at various drying temperatures. The simulated curves were then compared to the experimental curves obtained using a convective dryer controlled in temperature and moisture. The results showed that the drying curves were suitably fitted by the thin layer drying model with a correlation coefficient r<sup>2</sup> = 0.997. Thus, taking shrinkage into account, it is possible to predict more effectively the thin layer drying kinetics of mango slices. This study therefore contributed to the mango drying modelling and to the mango dryer setting. 展开更多
关键词 Convective Drying MANGO MODELLING Thin Layer KINETIC
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Carboxymethyl glycoside lactone(CMGL) synthons:Scope of the method and preliminary results on step growth polymerization of α-azide-ω-alkyne glycomonomers 被引量:1
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作者 CHAMBERT Stéphane BERNARD Julien +1 位作者 FLEURY Etienne QUENEAU Yves 《Science China Chemistry》 SCIE EI CAS 2010年第9期1880-1887,共8页
Carboxymethyl glycoside lactones(CMGLs) are bicyclic synthons which open readily for accessing new types of pseudo-glycoconjugates,such as sugar-amino acid hybrids,neoglycolipids,pseudodisaccharides,and membrane imagi... Carboxymethyl glycoside lactones(CMGLs) are bicyclic synthons which open readily for accessing new types of pseudo-glycoconjugates,such as sugar-amino acid hybrids,neoglycolipids,pseudodisaccharides,and membrane imaging systems.After lactone opening,free OH-2 is available for further functionalization,leading to 1,2-bisfunctionalized derivatives.This strategy is illustrated herein with new polymerizable systems of the AB type bearing both azide and alkyne functions prepared from α or β gluco-CMGL synthons.After the reaction of lactones with propargylamine,an azido group was introduced by two different sequences leading to either the 2-manno-azido or the 6-gluco-azido products.The capability of these AB monomers to undergo step growth polymerization through copper(I) catalyzed alkyne-azide cycloaddition(CuAAC) and generate glycopolytriazoles was evidenced. 展开更多
关键词 carbohydrates GLYCOPOLYMERS lactones click chemistry STEP GROWTH POLYMERIZATION GLYCOCONJUGATES azides alkynes Huisgen cycloaddition
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