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A STUDY OF BENT BONDS IN C_4R_4 AND Li_4R_4 MOLECULES 被引量:1
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作者 邱文元 杜奇石 +1 位作者 彭周人 李俊清 《Chinese Science Bulletin》 SCIE EI CAS 1987年第3期171-175,共5页
The C4R4 and Li4R4 type molecules which have come into notice recently have a distinctive tetrahedral configuration (see Fig. 1). Their syntheses and specific properties have been reported by many authors. We were i... The C4R4 and Li4R4 type molecules which have come into notice recently have a distinctive tetrahedral configuration (see Fig. 1). Their syntheses and specific properties have been reported by many authors. We were interested in studying the 展开更多
关键词 INTERESTED TETRAHEDRAL distinctive notice LISTED representing bending HYDROPHILIC bonding melting
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REACTIONS BETWEEN Ce(Ⅳ) COMPLEXES AND SUBSTITUTED CYCLOPENTADIENYL ALKALI METAL DERIVATIVES(Ⅱ) ——REACTION OF (HP(C_2H_5)_3)_2CeCl_6 AND C_5Me_5Li
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作者 沈琪 周朋 《Chinese Science Bulletin》 SCIE EI CAS 1987年第1期28-30,共3页
Study on the chemical properties of Ce (Ⅳ) complexes has been quite limited so far. We have first reported that Ce (Ⅳ) is reduced completely to Ce (Ⅲ) when (C5H6N)2CeCl6 reacts with C5Me5Li. In order to und... Study on the chemical properties of Ce (Ⅳ) complexes has been quite limited so far. We have first reported that Ce (Ⅳ) is reduced completely to Ce (Ⅲ) when (C5H6N)2CeCl6 reacts with C5Me5Li. In order to understand the characteristics of this type of reaction, we have studied the reaction of another Ce (Ⅳ) complex, (HP(C2H5)3)2CeCl6, 展开更多
关键词 COMPLEXES MOLAR C2H5 HP REACTION OF PELLET sealed attach bonded evident
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氢火焰离子化检测器校正因子的理论计算 被引量:31
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作者 范国梁 宋崇林 +5 位作者 周维义 阎颖 刘昌俊 姜东峰 隋静 刘春宇 《分析化学》 SCIE EI CAS CSCD 北大核心 2002年第8期906-910,共5页
根据FID检测器工作原理 ,提出一种相对质量校正因子的计算公式。由该公式出发可以推导出相对摩尔响应值 (RMR)与化合物碳数的线性关系式和有效碳数的近似计算方法 ,并赋予原计算方法中的参数以明确的含意 ,解决了参数之间的矛盾。
关键词 理论计算 氢火焰离子化检测器 校正因子 有效碳数 相对摩尔响应值 色谱 定量分析
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加氢催化剂器外预硫化技术现状 被引量:18
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作者 张喜文 凌凤香 +2 位作者 孙万付 方向晨 李瑞丰 《化工进展》 EI CAS CSCD 北大核心 2006年第4期397-400,410,共5页
介绍了现有加氢催化剂器外预硫化的技术路线、制备器外预硫化催化剂时所使用硫化剂的特点及研究器外预硫化技术时所需要重点考虑的问题。
关键词 器外预硫化 加氢催化剂 硫化剂
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用煤合成碳纳米管新方法 被引量:19
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作者 田亚峻 谢克昌 樊友三 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第9期1456-1458,共3页
A new technique for the synthesis of carbon nanotubes from coal is introduced in this paper. In this process, coal is selected as the raw material to injected into plasma jet directly, nanotubes are formed on the reac... A new technique for the synthesis of carbon nanotubes from coal is introduced in this paper. In this process, coal is selected as the raw material to injected into plasma jet directly, nanotubes are formed on the reactor wall. The metal elements contained in parent coal such as Cu, Al act as the catalyst. This technique is different from the traditional arc discharge process and has the advantages of easy and steady operation and low cost of raw material, so it is an attractive process. 展开更多
关键词 碳纳米管 电弧等离子体 合成 纳米材料
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柴油正构烷烃含量与其低温性质关系研究 被引量:14
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作者 姜少华 周剑鸣 张玉贞 《石油与天然气化工》 CAS CSCD 北大核心 2002年第5期243-245,共3页
以孤岛原油和大庆原油为原料 ,采用实沸点蒸馏工艺得到不同馏分段组成的一系列柴油样品。通过测定柴油的低温性质 (浊点、冷滤点和凝点 )和利用气相色谱测定从C12 到C2 5正构烷烃的含量 ,研究了各正构烷烃含量对柴油低温性质的影响。并... 以孤岛原油和大庆原油为原料 ,采用实沸点蒸馏工艺得到不同馏分段组成的一系列柴油样品。通过测定柴油的低温性质 (浊点、冷滤点和凝点 )和利用气相色谱测定从C12 到C2 5正构烷烃的含量 ,研究了各正构烷烃含量对柴油低温性质的影响。并利用多元回归拟合建立了关于柴油低温性质与其正构烷烃含量之间的数学模型。 展开更多
关键词 柴油 正构烷烃 含量 低温性质 研究 数学模型
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冷等离子体催化甲烷偶联研究进展 被引量:2
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作者 崔锦华 刘昌俊 许根慧 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2001年第1期33-38,共6页
着重介绍了冷等离子体工艺技术用于甲烷偶联工艺、反应装置及反应机理的研究进展。同时 ,也较详细地介绍了冷等离子催化与化学催化剂对甲烷偶联的协同效应的研究进展。
关键词 冷等离子体 甲烷 偶联工艺 催化反应 冷等离子体反应器 天然气加工
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微波辐射下3-烯丙基-5-苯亚甲基-2,4-噻唑烷二酮的合成 被引量:1
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作者 李筱芳 冯亚青 +1 位作者 张卫红 王冬慧 《化学推进剂与高分子材料》 CAS 2003年第1期38-39,共2页
关键词 生物活性 微波辐射 3-烯丙基-5-苯亚甲-2 4-噻唑烷二酮 合成
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HPLC法测定盐酸小檗胺片含量
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作者 钱春梅 陈学敏 +1 位作者 李涛 刘俊儒 《西北药学杂志》 CAS 1996年第1期3-5,共3页
HPLC法测定盐酸小檗胺片含量钱春梅,陈学敏,李涛,刘俊儒(西安医科大学药学系西安710061)摘要用高效液相色谱法(HPLC)测定盐酸小檗胺片含量。色谱条件采用C_8柱,检测波长282nm,25%(V/V)乙腈为流... HPLC法测定盐酸小檗胺片含量钱春梅,陈学敏,李涛,刘俊儒(西安医科大学药学系西安710061)摘要用高效液相色谱法(HPLC)测定盐酸小檗胺片含量。色谱条件采用C_8柱,检测波长282nm,25%(V/V)乙腈为流动相,盐酸小檗碱为内标物。方法回收... 展开更多
关键词 盐酸小檗胺 片剂 高效液相色谱 含量
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天生桥一级水电站大洞室施工
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作者 季月伦 《人民长江》 北大核心 1998年第12期24-25,共2页
天生桥一级水电站放空隧洞工程的工作闸门室为体型复杂的大型地下洞室。在浅层软弱围岩中开挖这样的洞室,国内尚属少见。隧洞施工前,有关单位对其进行了专题研究。施工中采取了“自上而下,化大断面为小断面开挖,及时支护,逐步扩大... 天生桥一级水电站放空隧洞工程的工作闸门室为体型复杂的大型地下洞室。在浅层软弱围岩中开挖这样的洞室,国内尚属少见。隧洞施工前,有关单位对其进行了专题研究。施工中采取了“自上而下,化大断面为小断面开挖,及时支护,逐步扩大,成型一段衬砌一段,以混凝土衬砌增加围岩自稳能力”的施工方案,成功地完成了施工任务,避免了冒顶塌方,超挖量也不大。 展开更多
关键词 水工隧洞 隧洞开挖 隧洞施工 一级水电站
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怎样识别真伪CACHE
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作者 张启刚 《电脑》 1996年第11期49-49,共1页
CACHE称为高速缓存,由处于CPU与主存之间的SRAM(静态存储器)组成.设置CACHE的目的是使CACHE内的指令和数据恰好是CPU近期所需的,这就使主机的速度提高到CACHE的速度的水平,从而接近CPU的速度.CACHE就其所处的位置分为:片内(INTERNAL)CA... CACHE称为高速缓存,由处于CPU与主存之间的SRAM(静态存储器)组成.设置CACHE的目的是使CACHE内的指令和数据恰好是CPU近期所需的,这就使主机的速度提高到CACHE的速度的水平,从而接近CPU的速度.CACHE就其所处的位置分为:片内(INTERNAL)CACHE和片外(EXTERNAL)CACHE;就其工作方式可分为:写通(WRITE THROUGH)CACHE和写回(WRITE BACK)CACHE. 展开更多
关键词 CPU CACHE 高速缓存 识别
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Investigation on High Efficient Catalysts for the Oxidative Dehydrogenation of Ethane
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作者 K.R.Tsai 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1993年第3期269-272,共4页
Since the pioneer work of Thorsteinson fot me ox(?) ethane, a series of V-Mo based catalysts mainly for the oxidative dehydrogenation of ethane have been patented. On the surfaces of these catalysts, a C;H;selectivi... Since the pioneer work of Thorsteinson fot me ox(?) ethane, a series of V-Mo based catalysts mainly for the oxidative dehydrogenation of ethane have been patented. On the surfaces of these catalysts, a C;H;selectivity of 70% was achieved, but the space velocity was only about 340 h;. Lunsford, et al. reported a C;H;conversion of 75% and a C;H;selectivity of 76% over the 展开更多
关键词 Oxidative dehydrogenation of ethane Oxygen species XPS RAMAN TPD
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Preliminary age-based life history characteristics of the dogtooth tuna,Gymnosarda unicolor(Ruppell,1838),in the southwest Pacific Ocean
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作者 David J.Welch Adam K.Smith +2 位作者 Kyne Krusic-Golub Sandra Erdmann Stephen J.Newman 《Aquaculture and Fisheries》 CSCD 2023年第3期323-331,共9页
Dogtooth tuna,Gymnosarda unicolor were sampled off the east coast of Australia(southwest Pacific Ocean)from 2007 to 2012.Ages were determined by examining thin transverse sections of their sagittal otoliths and were b... Dogtooth tuna,Gymnosarda unicolor were sampled off the east coast of Australia(southwest Pacific Ocean)from 2007 to 2012.Ages were determined by examining thin transverse sections of their sagittal otoliths and were based on counts of alternating opaque and translucent zones(annual growth increments).Growth was rapid during the first year of life,after which growth in length was much reduced.Parameters of the constrained von Bertalanffy growth function(fork length-at-age)were L∞=1164.77(mm,FL)and K=0.44 year^(-1).Preliminary estimates of longevity indicate a maximum observed age of at least 20 years.There was a high degree of variation in the observed length and age of sexual maturity for G.unicolor.Despite this variation,the size at 50%maturity for female G.unicolor estimated in this study was 713 mm FL(<2 years of age).The diet of G.unicolor is very broad and covers a range of fish species.The life history characteristics of G.unicolor overall,indicate that this species may be somewhat resilient to fishing.However,reports of localised depletions,in association with heavy targeting by sports fishers,low effective population sizes and patchy recruitment indicate that this species is particularly vulnerable to overfishing. 展开更多
关键词 Otoliths Age Life history Pacific ocean DIET Fisheries management
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PETPP/Rh配合物催化剂的原位红外光谱研究 被引量:1
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作者 郑晓来 王艳华 +3 位作者 程昉 金子林 刘崇微 朱起明 《分子催化》 EI CAS CSCD 北大核心 2001年第6期407-409,共3页
利用原位红外光谱 ,考察了 PETPP/Rh催化剂在 CO/H2 气氛下的活化情况 ,并监测 1-十二碳烯氢甲酰化的反应过程 .实验结果表明 ,在 PETPP/Rh配合物催化剂中 ,膦配体主要以配位数少的形式存在 ,因而氢甲酰化反应产物醛的正
关键词 非离子膦配体 原位红外光谱 膦铑配合物 氢甲酰化反应 铑催化剂 催化机理 1-十二碳烯
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A PROBLEM OF EXPONENTIAL STABILITY FOR LINEAR DYNAMICAL SYSTEMS IN HILBERT SPACES 被引量:2
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作者 黄发伦 刘康生 《Chinese Science Bulletin》 SCIE EI CAS 1988年第6期460-462,共3页
Ⅰ. INTRODUCTION AND RESULT Let H be a Hilbert space with its inner product (· , ·) and norm ‖·‖. Let etA be a C0-semigroup on H with the infinitesimal generator A and
关键词 SEMIGROUP generator algebra operators inequality ARGUMENT category ANSWER posed consequently
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DISCOVERY OF NEW MARINE FAMILY——SINAGLASPIDAE(AGLASPIDA) IN SHANXI PROVINCE 被引量:1
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作者 洪友崇 牛绍武 《Chinese Science Bulletin》 SCIE EI CAS 1981年第10期911-914,共4页
A new family, Sinaglaspidae f.n., has been discovered in the greyish-black mudstone of the lower part of the Shanxi Formation (Upper Carboniferous, C3(?)2) in Gancaoshan of Xiangning County, Shanxi Province. The dis... A new family, Sinaglaspidae f.n., has been discovered in the greyish-black mudstone of the lower part of the Shanxi Formation (Upper Carboniferous, C3(?)2) in Gancaoshan of Xiangning County, Shanxi Province. The discovery is of significance in that: (ⅰ) the Aglaspida-bearing deposit 展开更多
关键词 CARBONIFEROUS MUDSTONE SHANXI Upper shallow PERMIAN MARGIN SINAGLASPIDAE Tianjin ARTHROPODA
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ON APPROXIMATION CONSTANT FOR TYPICAL MEANS
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作者 郭竹瑞 《Chinese Science Bulletin》 SCIE EI CAS 1981年第12期1057-1060,共4页
Recently, Sun Yongsheng considered the approximation constant for the Cesàro means. The author gave the approximation constant for the typical means about the subclass of f(x)∈C2π under C norm. Now
关键词 introd 饭心 二甲 INTEGERS noting CONVENIENCE
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CRYSTAL STRUCTURE OF TRIMOLYBDENUM CLUSTER COMPOUND (Et_4N)[Mo_3(μ_3-O)(μ-Cl)_3-(μ-OAc)_3(Cl_(1/2),Br_(1/2))_3]
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作者 庄鸿辉 吴鼎铭 +2 位作者 郑建基 黄建全 黄金陵 《Chinese Science Bulletin》 SCIE EI CAS 1986年第6期387-391,共5页
The crystal structures of two isomorphic cluster compounds, (C5H7S2)[Mo3-(μ3-O)(μ-Cl)3 (μ-OAc)3Cl3] and (C5H2S2)[Mo3 (μ3-O)(μ-Br)3 (μ-OAc)3Cl3] have been investigated. The compounds have been pre... The crystal structures of two isomorphic cluster compounds, (C5H7S2)[Mo3-(μ3-O)(μ-Cl)3 (μ-OAc)3Cl3] and (C5H2S2)[Mo3 (μ3-O)(μ-Br)3 (μ-OAc)3Cl3] have been investigated. The compounds have been prepared by similar procedures, with the exception that the former has used MoCl3 as the starting material, 展开更多
关键词 ISOMORPHIC exception starting BR CL ET4N Mo3 OAC ETOH remaining
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ASYMPTOTICALLY EFFICIENT ESTIMATION IN THE SEMI-PARAMETRIC TRUNCATED FAMILIES
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作者 陈桂景 《Chinese Science Bulletin》 SCIE EI CAS 1992年第11期962-963,共2页
Let X<sub>1</sub>,… X<sub>n</sub> be ⅰ. ⅰ. d. samples drawing from a general truncated familydP<sub>θ</sub>(x) =f(x; θ<sub>1</sub>, θ<sub>2</sub>)... Let X<sub>1</sub>,… X<sub>n</sub> be ⅰ. ⅰ. d. samples drawing from a general truncated familydP<sub>θ</sub>(x) =f(x; θ<sub>1</sub>, θ<sub>2</sub>)I(θ<sub>1</sub>≤x≤θ<sub>2</sub>)dx, -∞【θ<sub>1</sub>【θ<sub>2</sub>【∞, (1)where f is unknown density on [θ<sub>1</sub>, θ<sub>2</sub>]. In order to estimate linear function g(θ)= c<sub>1</sub>θ<sub>1</sub>+c<sub>2</sub>θ<sub>2</sub>, 展开更多
关键词 TRUNCATED DRAWING transformed SIGNS
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ON A PROBLEM OF XIE TINGFAN
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作者 周信龙 《Chinese Science Bulletin》 SCIE EI 1987年第2期73-79,共7页
Ⅰ. INTRODUCTION Let f(x)∈C[-1, 1] and let -1<xn<xx-1<…<x1<1 be the zeros of Legendre polynomial Pn(x) of degree n. It is well known that Hermite-Fejer and quasi Hermite-Fejer interpolation polyno... Ⅰ. INTRODUCTION Let f(x)∈C[-1, 1] and let -1<xn<xx-1<…<x1<1 be the zeros of Legendre polynomial Pn(x) of degree n. It is well known that Hermite-Fejer and quasi Hermite-Fejer interpolation polynomials based on {xk}kn=1 are, 展开更多
关键词 INTERPOLATION LEGENDRE POLYNOMIAL QUASI nearest assume QUADRATURE ANSWER 二业 三尸
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