Multi-Walled carbon nanotubes are used as preconcentrating probes for the quantitative determination of trace cadmium, copper and lead in environmental and biological sample using graphite Furnace Atomic Absorption Sp...Multi-Walled carbon nanotubes are used as preconcentrating probes for the quantitative determination of trace cadmium, copper and lead in environmental and biological sample using graphite Furnace Atomic Absorption Spectrometry and inductively coupled Plasma Optical Emission spectrometry. The method is based on the electrostatic interactions of positively charged Cd+, Cu+ and Pb+ with the negatively charged multi-walled carbon nanotubes (MWCNTs) for the preconcentration and isolation of analytes from sample solutions. Effective preconcentration of trace cadmium, copper and lead was achieved in a pH range of 5 - 7, 5 - 7 and 4 - 7, respectively. The retained cadmium, copper and lead were efficiently eluted with 0.3 mol·L-1 HCl for graphite Furnace Atomic Absorption Spectrometry determination. The multi-walled carbon nanotubes packed micro-column exhibited fairly fast kinetics for the adsorption of cadmium, copper and lead, permitting the use of high sample flow rates up to at least 3 mL·min-1 for the flow injection on micro-column preconcentration without the loss of the retention efficiency. The detection limits (3σ) were 0.03, 0.01 and 0.5 ng·mL-1 for Cd, Cu and Pb, respectively. The relative standard deviation under optimum condition is less than 2.9% (n = 10). The developed method was successfully applied to the determination of trace Cd, Cu and Pb in a variety of environmental and biological samples.展开更多
Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) technique was used to determine the concentrations of titanium (Ti), vanadium (V), Chromium (Cr), Manganese (Mn), iron (Fe), zinc (Zn), arsenic (As), zirconium (Zr...Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) technique was used to determine the concentrations of titanium (Ti), vanadium (V), Chromium (Cr), Manganese (Mn), iron (Fe), zinc (Zn), arsenic (As), zirconium (Zr), cadmium (Cd) and hafnium (Hf) in black sands samples. 18 black sands samples were collected from the Mediterranean coast-Abu Khashabou Rosetta area, Egypt. Alkaline fusion procedure using mixture of Li-meta borate and tetra borate was used for the digestion of black sands samples. The average concentrations of Ti, V, Cr, Mn, Fe, Zn, As, Zr, Cd and Hf were 435.06 ppm, 322.32 ppm, 2515.03 ppm, 596.45 ppm, 185894 ppm, 249.95 ppm,309.32 ppm, 1077.26 ppm, 33.56 ppm and 3520.32 ppm, respectively. The procedure was tested with Basalt Hawaiian Volcanic Observatory (BHVO-2) standard reference material.展开更多
文摘Multi-Walled carbon nanotubes are used as preconcentrating probes for the quantitative determination of trace cadmium, copper and lead in environmental and biological sample using graphite Furnace Atomic Absorption Spectrometry and inductively coupled Plasma Optical Emission spectrometry. The method is based on the electrostatic interactions of positively charged Cd+, Cu+ and Pb+ with the negatively charged multi-walled carbon nanotubes (MWCNTs) for the preconcentration and isolation of analytes from sample solutions. Effective preconcentration of trace cadmium, copper and lead was achieved in a pH range of 5 - 7, 5 - 7 and 4 - 7, respectively. The retained cadmium, copper and lead were efficiently eluted with 0.3 mol·L-1 HCl for graphite Furnace Atomic Absorption Spectrometry determination. The multi-walled carbon nanotubes packed micro-column exhibited fairly fast kinetics for the adsorption of cadmium, copper and lead, permitting the use of high sample flow rates up to at least 3 mL·min-1 for the flow injection on micro-column preconcentration without the loss of the retention efficiency. The detection limits (3σ) were 0.03, 0.01 and 0.5 ng·mL-1 for Cd, Cu and Pb, respectively. The relative standard deviation under optimum condition is less than 2.9% (n = 10). The developed method was successfully applied to the determination of trace Cd, Cu and Pb in a variety of environmental and biological samples.
文摘Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) technique was used to determine the concentrations of titanium (Ti), vanadium (V), Chromium (Cr), Manganese (Mn), iron (Fe), zinc (Zn), arsenic (As), zirconium (Zr), cadmium (Cd) and hafnium (Hf) in black sands samples. 18 black sands samples were collected from the Mediterranean coast-Abu Khashabou Rosetta area, Egypt. Alkaline fusion procedure using mixture of Li-meta borate and tetra borate was used for the digestion of black sands samples. The average concentrations of Ti, V, Cr, Mn, Fe, Zn, As, Zr, Cd and Hf were 435.06 ppm, 322.32 ppm, 2515.03 ppm, 596.45 ppm, 185894 ppm, 249.95 ppm,309.32 ppm, 1077.26 ppm, 33.56 ppm and 3520.32 ppm, respectively. The procedure was tested with Basalt Hawaiian Volcanic Observatory (BHVO-2) standard reference material.
