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eacher Power: A Critical Discourse Perspective Department of Fine Arts,Chongqing University of Education
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作者 Zhou Ting Xu Xi 《International Journal of Technology Management》 2014年第6期67-69,共3页
Power relation can be revealed in discourse. Teacher power, to a large extent, is manifested through teacher talk. This paper attempts to provide an analysis of classroom language from a critical discourse perspective... Power relation can be revealed in discourse. Teacher power, to a large extent, is manifested through teacher talk. This paper attempts to provide an analysis of classroom language from a critical discourse perspective as to uncover the power hidden in teacher talk and of how language contributes to teacher power. 展开更多
关键词 teacher power teacher talk critical discourse analysis
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Challenges and Countermeasures of Youth Moral Education in the Era of Big Data
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作者 Longfeng Yang 《Journal of Contemporary Educational Research》 2024年第3期199-204,共6页
Youth moral education is an extremely important work,which is related to the inheritance of traditional virtues of the Chinese nation,the fundamental plan of“successor,”and the construction of modern Chinese spiritu... Youth moral education is an extremely important work,which is related to the inheritance of traditional virtues of the Chinese nation,the fundamental plan of“successor,”and the construction of modern Chinese spiritual civilization.In the era of big data,the moral education of youth is facing new challenges and opportunities.The wide application of big data technology has brought about an information explosion,exposing young people to more diverse and complex social information.It not only brings opportunities for positive moral education but also many challenges.The main problems of youth moral education in the era of big data are neglected youth subjectivity,insufficient youth moral practice,and utilitarian youth value orientation.We should develop personalized moral education programs,strengthen the integration of moral knowledge and action,and pay more attention to moral practice to improve the pertinence and effectiveness of moral education for young people in the era of big data. 展开更多
关键词 New era YOUTH Moral education
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Analysis on the Causes of Existing Problems of Professional Knowledge of Western Rural Teachers Under the Urban and Rural Educational Planning Background
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作者 Qin Bo 《International Journal of Technology Management》 2014年第1期20-22,共3页
This paper adopts the self-designed questionnaire to make investigations and interviews with the rural middle and primary school teachers in Chengdu and Chongqing districts about the professional development problems ... This paper adopts the self-designed questionnaire to make investigations and interviews with the rural middle and primary school teachers in Chengdu and Chongqing districts about the professional development problems of western rural teachers, and refers to the educational literature materials in western rural areas. Through a comprehensive analysis, it is known that the professional knowledge status of western rural teachers is worrying, and the reason is mainly caused by the location, policy, economy, society, continuing education and teachers' own factors. 展开更多
关键词 urban and rural educational planning western rural area the professional knowledge of teachers problems and causes
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Employment education research integrity of college sports majors
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作者 Yong Sui 《International Journal of Technology Management》 2014年第3期58-60,共3页
With the reform of the education system, the number of graduating students increases every year, and more and more severe graduate' s employment, while more and more companies are unable to recruit talent. Resulting ... With the reform of the education system, the number of graduating students increases every year, and more and more severe graduate' s employment, while more and more companies are unable to recruit talent. Resulting in difficult employment graduates there are many factors, the most important manifestations of contemporary graduates questioned the integrity of most enterprises, improve the status of today' s society difficult employment, increase the employment rate of graduates realize their own values of contemporary college students, meet the vital interests of the family, so that our talents and educational resources are fully utilized, so as to promote the healthy development of social harmony and stability as well as higher education. Social harmony and stability as well as for the healthy development of higher education, the vital interests of the students themselves and their families realize the value and so have certain theoretical and practical significance. 展开更多
关键词 Sports majors honest employment education system
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A Research Review of China's Teacher Education Integration
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作者 Yuewen LI 《International Journal of Technology Management》 2015年第9期68-70,共3页
At the beginning of the 21th century, the integration of teacher education has become a hot issue in the studies of China' s teacher education. In this paper, a discussion is conducted from the change from normal edu... At the beginning of the 21th century, the integration of teacher education has become a hot issue in the studies of China' s teacher education. In this paper, a discussion is conducted from the change from normal education to teacher education, the intension of teacher education integration, and the exploration on China' s teacher education integration, and then the existing problems are analyzed, and finally the future research direction is raised. 展开更多
关键词 Teacher Education Pre-service and In-service INTEGRATION
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Research on the Development and Evolution Mechanism of Chongqing Rural Tourism Activities
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作者 Guodong Sun 《International Journal of Technology Management》 2015年第9期50-52,共3页
In this paper, we conduct research on the development and evolution mechanism of Chongqing rural tourism activities. Rural tourism industry cluster development is the important direction is to promote and enhance the ... In this paper, we conduct research on the development and evolution mechanism of Chongqing rural tourism activities. Rural tourism industry cluster development is the important direction is to promote and enhance the rural tourism the important measures to get long-term vitality. To upgrade the development of rural tourism to the height of the industrial cluster will make the rural tourism development onto a new level. In the future, we will combine more related literature review to polish and modify the proposed methodology which will be meaningful. 展开更多
关键词 Chongqing Rural Tourism Evolution Mechanism Theoretical Analysis.
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University Organic Chemistry Education Technological innovation
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作者 Lai Han 《International Journal of Technology Management》 2014年第9期7-9,共3页
the paper discusses the advantage and disadvantage of organic chemistry teaching mode of multimedia auxiliary university compared with traditional teaching mode. And combined with the author' s teaching practice the ... the paper discusses the advantage and disadvantage of organic chemistry teaching mode of multimedia auxiliary university compared with traditional teaching mode. And combined with the author' s teaching practice the paper sums up that the multimedia technology shall be used as the auxiliary method of traditional teaching to optimize classroom teaching, improve the classroom efficiency and reflect the true value of the multimedia auxiliary teaching. 展开更多
关键词 University Organic Chemistry Technological multimedia auxiliary
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The Effect of the Retelling on Chinese University Students' English Reading Comprehension
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作者 梁本彬 《海外英语》 2016年第3期238-240,共3页
Retelling is a very efficient means of generative learning; it engages students in meaning reconstruction, and consequently facilitates students' reading comprehension. This study aims to explore how the retelling... Retelling is a very efficient means of generative learning; it engages students in meaning reconstruction, and consequently facilitates students' reading comprehension. This study aims to explore how the retelling technique can affect Chinese tertiary-level students' reading comprehension of narrative and expository texts. 展开更多
关键词 RETELLING READING COMPREHENSION tertiary-level STUDENTS
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Antioxidant effect of Lactobacillus fermentum HFY02-fermented soy milk on D-galactose-induced aging mouse model 被引量:9
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作者 Tiantian Hu Rui Chen +4 位作者 Yu Qian Ke Ye Xingyao Long Kun-Young Park Xin Zhao 《Food Science and Human Wellness》 SCIE 2022年第5期1362-1372,共11页
This study aimed to investigate the antioxidant effect of soybean milk fermented by a new type of Lactobacillus fermentum(LF-HFY02)by using D-galactose induced aging mice model.Firstly,the optimal fermentation conditi... This study aimed to investigate the antioxidant effect of soybean milk fermented by a new type of Lactobacillus fermentum(LF-HFY02)by using D-galactose induced aging mice model.Firstly,the optimal fermentation conditions was screened out by detecting the effects of different fermentation temperature and time on the active components and antioxidant activity of soybean milk in viro.And then unfermented soybean milk and the soybean milk fermented by different Lactobacillus was given by gavage to D-galactose-induced aging mouse.The activities of GSH,GSH-Px,SOD,CAT and T-AOC in serum,brain and liver of soybean milk fermented by LF-HFY02 were significantly increased,while the content of MDA and the level of AGEs in hippocampal were significantly decreased compared with D-galactose induced group.Further more,the mRNA expression of GSH and SOD in mouse liver were obviously up-regulated by soybean milk fermented by LF-HFY02.The skin tissue structure of mice in the LF-HFY02 fermented soybean milk group was more complete,the collagen fibers were increased and arranged orderly and liver inflammation has improved compared with the model group.And Western blot analysis showed that LF-HFY02 effectively upregulated EGFR,SOD and GSH protein expression in mouse liver.These findings suggest that LF-HFY02 can effectively prevent D-galactose-induced oxidation and aging in mice,and the effect was even better than that of the Lactobacillus delbruechii subsp.bulgaricus and vitamin C.Thus,LF-HFY02 may be potentially employed as a probiotic strain.In conclusion,soybean milk fermented by LF-HFY02 can increase the content of antioxidant factors and the activity of antioxidant enzymes by regulating gene and protein expression,and finally inhibit the process of tissue cell peroxidation,and improve the oxidative damage of mouse skin and liver.The results could provide a basis for the research and development and industrial production of probiotic-related fermented soybean milk products. 展开更多
关键词 Lactobacillus fermentum HFY02 Fermented soybean milk D-GALACTOSE ANTIOXIDANT AGING
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A Modification to Vertical Distribution of Tidal Flow Reynolds Stress in Shallow Sea 被引量:4
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作者 倪志辉 宋志尧 +2 位作者 张绪进 吴立春 易静 《China Ocean Engineering》 SCIE EI 2012年第3期431-442,共12页
Tidal flow is a periodic movement of unsteady and non-uniform, which has acceleration and deceleration process obviously, especially in coastal shallow waters. Many researches show that vertical distribution of tidal ... Tidal flow is a periodic movement of unsteady and non-uniform, which has acceleration and deceleration process obviously, especially in coastal shallow waters. Many researches show that vertical distribution of tidal flow Reynolds stress deviated from linear distribution. The parabolic distribution of the tidal flow Reynolds stress was proposed by Song et al. (2009). Although the model fills better with field observations and indoor experimental data, it has the lower truncated series expansion of tidal flow Reynolds stress, and the description of the distribution is not very comprehensive By introducing the motion equation of tidal flow and improving the parabolic distribution established by Song et al. (2009), the cubic distribution of the tidal flow Reynolds stress is proposed. The cubic distribution is verified well by field data (Bowden and Fairbairn, 1952; Bowden et al., 1959; Rippeth et al., 2002) and experimental data (Anwar and Atkins, 1980), is consistent with the numerical model results of Kuo et al. (1996), and is compared with the parabolic distribution of the tidal flow Reynolds stress. It is shown that this cubic distribution is not only better than the parabolic distribution, but also can better reflect the basic features of Reynolds stress deviating from linear distribution downward with the tidal flow acceleration and upward with the tidal flow deceleration, for the foundation of further study on the velocity profile of tidal flow. 展开更多
关键词 tidal flow Reynolds stress linear distribution parabolic distribution cubic distribution
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Prophylactic effect of Kudingcha polyphenols on oxazolone induced colitis through its antioxidant capacities 被引量:4
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作者 Xingyao Long Yanni Pan Xin Zhao 《Food Science and Human Wellness》 SCIE 2018年第3期209-214,共6页
This research the preventive effect of Kudingcha polyphenols(Kp)on colitis based on animal experiments.Experimental mice divided into four groups,including normal group,model group,low-concentration Kp(LKP)group and h... This research the preventive effect of Kudingcha polyphenols(Kp)on colitis based on animal experiments.Experimental mice divided into four groups,including normal group,model group,low-concentration Kp(LKP)group and high-concentration Kp(HKP)group,and they all smeared and given 0.15 mL 1%oxazolone solution by lavage to induce BALB/c mice colitis.DAI,colon weight/length ratio,serum levels of cytokines,related antioxidant activities of colon tissues such,and the mRNA expressions.The experimental results show that KP can significantly(p<0.05)reduce DAI in mice with colitis and inhibit shortening of colon caused by colitis,increase colon weight/length ratio.It can also significantly reduce(p<0.05)the activities of MPO,NO,MDA in mice colon tissues with colitis,increase the activity of GSH,and significantly increase(p<0.05)the level of IL-2 and decrease the level of IL-10 in mice serum with colitis.The results of qPCR assay show that Kp can significantly increase(p<0.05)the expression of Cu/Zn-SOD,Mn-SOD,GSH-Px,CAT,c-Kit,SCF and decrease the expression of IL-8,CXCR2 in mice colon tissues with colitis.Kp has a good preventive effect on colitis,and high concentration of PT has better preventive effect. 展开更多
关键词 Kudingcha polyphenols OXAZOLONE ANTIOXIDANT COLITIS mRNA expression
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A novel intrusion detection model for the CAN bus packet of in-vehicle network based on attention mechanism and autoencoder 被引量:2
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作者 Pengcheng Wei Bo Wang +2 位作者 Xiaojun Dai Li Li Fangcheng He 《Digital Communications and Networks》 SCIE CSCD 2023年第1期14-21,共8页
The attacks on in-vehicle Controller Area Network(CAN)bus messages severely disrupt normal communication between vehicles.Therefore,researches on intrusion detection models for CAN have positive business value for veh... The attacks on in-vehicle Controller Area Network(CAN)bus messages severely disrupt normal communication between vehicles.Therefore,researches on intrusion detection models for CAN have positive business value for vehicle security,and the intrusion detection technology for CAN bus messages can effectively protect the invehicle network from unlawful attacks.Previous machine learning-based models are unable to effectively identify intrusive abnormal messages due to their inherent shortcomings.Hence,to address the shortcomings of the previous machine learning-based intrusion detection technique,we propose a novel method using Attention Mechanism and AutoEncoder for Intrusion Detection(AMAEID).The AMAEID model first converts the raw hexadecimal message data into binary format to obtain better input.Then the AMAEID model encodes and decodes the binary message data using a multi-layer denoising autoencoder model to obtain a hidden feature representation that can represent the potential features behind the message data at a deeper level.Finally,the AMAEID model uses the attention mechanism and the fully connected layer network to infer whether the message is an abnormal message or not.The experimental results with three evaluation metrics on a real in-vehicle CAN bus message dataset outperform some traditional machine learning algorithms,demonstrating the effectiveness of the AMAEID model. 展开更多
关键词 Controller area network bus packet In-vehicle network Attention mechanism Autoencoder
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Structure and Luminescent Property of a Tetrahedral Silver(Ⅰ) Cluster Complex Based on Phosphor and Sulphur Mixed-ligand System 被引量:1
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作者 WANG Yue SHI Yong-Fang +3 位作者 LI Xiao-Bo ZOU Xiao-Chuan HE Yu-Cen WANG Xia 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2019年第7期1216-1222,共7页
A tetrahedral silver(I) cluster complex {Ag4[HC(PPh2)3](S2PPh2)3}ClO4(1,HC(PPh2)3 = 1,1,1-tris(triphenylphosphino)methane, S2PPh2 = diphenyldithiophosphinate) was synthesized by assembling silver ion with phosphor and... A tetrahedral silver(I) cluster complex {Ag4[HC(PPh2)3](S2PPh2)3}ClO4(1,HC(PPh2)3 = 1,1,1-tris(triphenylphosphino)methane, S2PPh2 = diphenyldithiophosphinate) was synthesized by assembling silver ion with phosphor and sulphur mixed-ligand system. The complex was characterized by single-crystal X-ray crystallography, high-resolution mass spectroscopy and thermal analysis. In the crystal structure, an inverted tetrahedron was constructed from Ag4 metal skeleton. The Ag4 cage was stabilized by three diphenyldithiophosphinate ligands and one 1,1,1-tris(triphenylphosphino)methane ligand. 1 exhibits luminescent properties in solid state. A bright yellow-green emission centered at 533 nm has been observed in solid state. Large Stokes' shifts with long range of emissive lifetime indicate that the emission likely originates from a triplet state parentage. 展开更多
关键词 SILVER cluster crystal STRUCTURE luminescent property MIXED-LIGAND
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Application of Metabolomics Approach to Study on Chemical Constituents in Cultivated and Wild Pinellia ternate (Thunb.) Breit. and Typhonium flagelliforme (Lodd.) Blume Based on UPLC-ESI-HRMS^n 被引量:1
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作者 Yanfang LI Gang KUANG +4 位作者 Ainuan LI Junke CHEN Hui SUN Rui ZENG Xin LI 《Medicinal Plant》 CAS 2019年第1期19-22,25,共5页
[Objectives] The aim was to study chemical components of cultivated and wild Pinellia ternate(Thunb.) Breit and Typhonium flagelliforme(Lodd.) Blume by metabolomics technology based on UPLC-ESI-HRMS^n. [Methods] Chemi... [Objectives] The aim was to study chemical components of cultivated and wild Pinellia ternate(Thunb.) Breit and Typhonium flagelliforme(Lodd.) Blume by metabolomics technology based on UPLC-ESI-HRMS^n. [Methods] Chemical components of 27 samples of cultivated and wild P. ternate and T. flagelliforme were detected by using UPLC-ESI-HRMS^ntechnology. Differential markers between P. ternate and T. flagelliforme as well as cultivated and wild P. ternate were screened and identified by principal component analysis(PCA) and orthogonal partial least square-discriminate analysis(OPLS-DA). [Results]12 components of P. ternate(cultivated and wild variety) and T.flagelliforme and three components of cultivated and wild P. ternate were screened and identified by OPLS-DA. N-Acetyl-6-hydroxy-L-tryptophan and N-Phenylacetylglutamic were not detected in P. ternate,and these two components can be used as potential markers of P. ternate and T. flagelliforme. [Conclusions]UPLC-ESI-HRMS^n-based metabolomics technology could be used to quickly identify the chemical constituents of P. ternate and effectively distinguish P. ternate and T. flagelliforme,which has reference significance for the quality control of P. ternate. 展开更多
关键词 Pinellia ternate(Thunb.) Breit. Plant metabolomics MARKER UPLC-ESI-HRMSn PCA OPLS-DA
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Analysis on Tourism Economic Spatial Relation of Liaoning Central City Group 被引量:1
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作者 Guodong SUN Liang ZHAO 《Asian Agricultural Research》 2014年第12期66-68,共3页
Through the calculation and analysis of the tourism economic spatial relation,it found that Liaoning central urban agglomeration tourism economic spatial relation has many problems,such as the central city is insuffic... Through the calculation and analysis of the tourism economic spatial relation,it found that Liaoning central urban agglomeration tourism economic spatial relation has many problems,such as the central city is insufficient,and the low degree of spatial relations. Therefore,this article puts forward the countermeasures,which can provide theoretical and practical reference for Liaoning central urban agglomeration tourism industry layout. 展开更多
关键词 URBAN AGGLOMERATION TOURISM ECONOMIC space Liaonin
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Simultaneous determination of ten nucleosides and bases in Ganoderma by micellar electrokinetic chromatography 被引量:1
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作者 Feiya Sheng Songsong Wang +3 位作者 Xiao Luo Jianbo Xiao Linfeng Hu Peng Li 《Food Science and Human Wellness》 SCIE 2022年第2期263-268,共6页
Ganoderma(lingzhi)is a famous herbal medicine and edible supplement in oriental countries for a long history.In this study,a simple micellar electrokinetic chromatography(MEKC)method was established for the analysis o... Ganoderma(lingzhi)is a famous herbal medicine and edible supplement in oriental countries for a long history.In this study,a simple micellar electrokinetic chromatography(MEKC)method was established for the analysis of nucleosides and bases,the major bioactive components in Ganoderma for the first time.By optimizing the borate concentration,the sodium dodecyl sulfate(SDS)concentration and the pH value of running buffer,10 nucleosides and bases achieved an ideal separation.In real sample analysis,the developed method was successfully used to determine the 10 target analytes in 23 batches of Ganoderma samples from different regions.Results indicated that contents of 10 investigated analytes in each sample showed obvious variation.The principal components analysis(PCA)and hierarchical cluster analysis(HCA)analysis classified the samples into three groups,and the HCA tree visualized the relationships which was mainly contributed by geographical partition.The results indicated geographical origin to be an important factor that affect the accumulation of nucleosides and bases in Ganoderma.In summary,this study provides a simple and practical strategy for quality assessment and cultivation reference of Ganoderma. 展开更多
关键词 GANODERMA NUCLEOSIDES BASES Micellar electrokinetic chromatography Quality assessment
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Inhibitory effect of Cyrtomium falcatum on melanogenesis in α-MSH-stimulated B16F10 murine melanoma cells 被引量:1
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作者 Xian-Rong Zhou Jung Hwan Oh +5 位作者 Fatih Karadeniz Hyunjung Lee Hyo Eun Kim Migeon Jo Youngwan Seo Chang-Suk Kong 《Asian Pacific Journal of Tropical Biomedicine》 SCIE CAS 2023年第9期403-410,共8页
Objective:To explore the anti-melanogenic potential of Cyrtomium falcatum.Methods:The effects of Cyrtomium falcatum crude extract and its solvent fractions on tyrosinase activity,melanin content,and the expressions of... Objective:To explore the anti-melanogenic potential of Cyrtomium falcatum.Methods:The effects of Cyrtomium falcatum crude extract and its solvent fractions on tyrosinase activity,melanin content,and the expressions of melanogenesis-related genes and proteins were analyzed inα-melanocyte-stimulating hormone(α-MSH)-stimulated B16F10 cells.Results:α-MSH treatment significantly increased tyrosinase activity,and extracellular and intracellular melanin content,as well as the expression levels of tyrosinase,microphthalmia-associated transcription factor(MITF),tyrosinase-related protein(TRP)-1,and TRP-2 in B16F10 cells.Treatment with Cyrtomium falcatum crude extract and its solvent fractions reduced tyrosinase activity and extracellular and intracellular melanin content and downregulated the expression levels of tyrosinase,MITF,TRP-1,and TRP-2 in a dose-dependent manner.Conclusions:Cyrtomium falcatum has potential anti-melanogenesis effects and can be used as a potential source material in cosmeceutical industry for the research and development of novel lead molecules with whitening properties. 展开更多
关键词 Cyrtomium falcatum MELANOGENESIS Α-MSH B16F10 melanoma cells
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Optimization of Fermentation Process for the Production of Bacteriocins from Lactic Acid Bacteria 被引量:2
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作者 Zhiping ZHAO Li ZHANG +2 位作者 Yanrong REN Xia ZHANG Xin NIE 《Agricultural Biotechnology》 CAS 2015年第2期50-53,共4页
[Objective]This study aimed to improve the yield of bacteriocins from lactic acid bacteria by optimizing the fermentation process for production of bacteriocins from lactic acid bacteria.[Method]By single-factor analy... [Objective]This study aimed to improve the yield of bacteriocins from lactic acid bacteria by optimizing the fermentation process for production of bacteriocins from lactic acid bacteria.[Method]By single-factor analysis,fermentation temperature,seed age,inoculation volume,fermentation duration and fermentation media p H were optimized to determine the best fermentation process.The inhibitory zone of bacteriocins from lactic acid bacteria was analyzed with oxford cup method,based on which the fermentation process was evaluated.[Result]The optimal fermentation process was optimized:fermentation temperature 37℃,seed age 14 h,inoculation volume 2%,fermentation duration 48 h,fermentation media p H 5.0.[Conclusion]Under the optimized fermentation conditions,the yield of bacteriocins from lactic acid bacteria was improved significantly. 展开更多
关键词 fermentation Bacteria lactic inoculation optimizing inoculated contained ammonium antibacterial dissolved
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A Facile Controllable Synthesis, Growth Mechanism, and Photocatalytic Properties of Nanoscale BiOCl
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作者 王跃 石永芳 吴立明 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第3期458-468,共11页
Nanoscale tetragonal BiOCl samples have been synthesized using Bi[SC12H25]3 and CHCl3 as bismuth and chlorine sources by solvothermal reactions. The structure, morphology, and formation process have been investigated ... Nanoscale tetragonal BiOCl samples have been synthesized using Bi[SC12H25]3 and CHCl3 as bismuth and chlorine sources by solvothermal reactions. The structure, morphology, and formation process have been investigated by SEM, TEM, HRTEM, XRD, and EDX analyses. The layered crystal structure feature of BiOCl may induce the growth of nano plates, which can subsequently aggregate into 3D spherical or flower-like microstructures under the presence of ethanol. The reaction temperature and the identity of secondary solvent influence the morphology. The yield of BiOCl depends on the completeness of the reaction and the degree of a competition reduction of BiOCl to Bi by ethanol. The as-synthesized 3D quasi-spherical BiOCl sample has an optical band gap of 3.15 eV, and shows much better photocatalytic performance on the degradation of methyl orange than that of commercial P25. 展开更多
关键词 SYNTHESIS MECHANISM PHOTOCATALYTIC NANO BiOCl
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Effects of π-conjugation-substitution on ESIPT process for oxazoline-substituted hydroxyfluorenes
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作者 汪迪 周悄 +1 位作者 魏强 宋朋 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第2期499-503,共5页
Excited-state intramolecular proton transfer(ESIPT) molecules are broadly applied to UV absorbers, fluorescence sensing, and lighting materials. In previous work, the fluorescence colors of oxazoline-substituted hydro... Excited-state intramolecular proton transfer(ESIPT) molecules are broadly applied to UV absorbers, fluorescence sensing, and lighting materials. In previous work, the fluorescence colors of oxazoline-substituted hydroxyfluorenes and hydroxylated benzoxazole were diversified by adding the π-conjugation. There is intriguing that the mechanism of diversified fluorescence colors induced by ESIPT. Here, the density functional theory(DFT) and time-dependent DFT(TDDFT)are advised to identify the effects of π-conjugation on ESIPT and photophysical properties. The stabilized geometrical configurations, frontier molecular orbitals(FMOs) isosurfaces, and O–H stretching vibration frequency analysis demonstrate that PT processes are more active in S1state. Constructing the minimum energy pathways of ESIPT processes, we find that the calculated peak of enol and keto fluorescence of naphthoxazole(NO–OH) is distinctly bathochromic-shift relative to the oxazoline-substituted hydroxyfluorenes(Oxa–OH) configuration when adding π-conjugation-substitution, and it means that π-conjugation-substitution can diversify the fluorescence color. We hope our studies can establish new channels to devise the ESIPT-based molecules. 展开更多
关键词 density functional theory(DFT)and time-dependent DFT(TDDFT) excited-state proton transfer intramolecular hydrogen bonding π-conjugation-substitution
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