In-situ analysis and genetic investigation of Li-bearing minerals in McDermitt clay-type lithium deposit,Nevada,USA

Clay-type Li deposits are poised to play a pivotal role in addressing the surging global demand for Li.The McDermitt clay-type Li deposit,located in Nevada,is the largest Li deposit in the United States,with Li hosted by a clay-rich sequence of smectite-dominated intervals and illite-dominated intervals,respectively.However,the occurrence of Li and the genesis of Li-bearing minerals within smectite-dominated intervals have not been thoroughly investigated in previous research.Here,we studied the mineralogy,the in-situ Li distribution,and the bonding environments of Li within the smectite intervals using a combination of instru-mental techniques including scanning electron microscope,transmission electron microscope,time-of-flight secondary ion mass spectrometry,and nuclear magnetic resonance.Our results indicate that the smectite exhibits low crystallinity characteristics of lacustrine clay authigenesis and is com-monly found tofill the interstices among volcanic minerals or envelop them;Li is mainly hosted by Mg-smectite rather than the volcanic minerals.Within the tuffaceous sediment samples,the volcanic glass has undergone a transformation,resulting in its complete disappearance and alteration into clay minerals.Owing to the octahedral sites of Mg-smectite bounded in Li,it is referred to be hectorite.We interpret that the hectorite’s precipitation occurs in a high saline-alkaline water environment,a result of McDermitt tuffdissolution.This conclusion can be supported by the coexistence of spherulitic calcite and hectorite.Overall,this study confirms hectorite as the main Li-bearing mineral and increases the understanding of the genetic model of hectorite formation in intracontinental caldera basins.

A study on the simulation of carbon and water fluxes of Dangxiong alpine meadow and its response to climate change

The alpine meadow ecosystem accounts for 27%of the total area of the Tibetan Plateau and is also one of the most important vegetation types.The Dangxiong alpine meadow ecosystem,located in the south-central part of the Tibetan Plateau,is a typical example.To understand the carbon and water fluxes,water use efficiency(WUE),and their responses to future climate change for the alpine meadow ecosystem in the Dangxiong area,two parameter estimation methods,the Model-independent Parameter Estimation(PEST)and the Dynamic Dimensions Search(DDS),were used to optimize the Biome-BGC model.Then,the gross primary productivity(GPP)and evapotranspiration(ET)were simulated.The results show that the DDS parameter calibration method has a better performance.The annual GPP and ET show an increasing trend,while the WUE shows a decreasing trend.Meanwhile,ET and GPP reach their peaks in July and August,respectively,and WUE shows a“dual-peak”pattern,reaching peaks in May and November.Furthermore,according to the simulation results for the next nearly 100 years,the ensemble average GPP and ET exhibit a significant increasing trend,and the growth rate under the SSP5–8.5 scenario is greater than that under the SSP2–4.5 scenario.WUE shows an increasing trend under the SSP2–4.5 scenario and a significant increasing trend under the SSP5–8.5 scenario.This study has important scientific significance for carbon and water cycle prediction and vegetation ecological protection on the Tibetan Plateau.

A progress review of black carbon deposition on Arctic snow and ice and its impact on climate change

The rapid warming of the Arctic,accompanied by glacier and sea ice melt,has significant consequences for the Earth’s climate,ecosystems,and economy.Black carbon(BC)deposition on snow and ice can trigger a significant reduction in snow albedo and accelerate melting of snow and ice in the Arctic.By reviewing the published literatures over the past decades,this work provides an overview of the progress in both the measurement and modeling of BC deposition and its impact on Arctic climate change.In summary,the maximum value of BC deposition appears in the western Russian Arctic(26 ng·g^(–1)),and the minimum value appears in Greenland(3 ng·g^(–1)).BC records in the Arctic ice core already peaked in 1920s and 1970s,and shows a regional difference between Greenland and Canadian Arctic.The different temporal variations of Arctic BC ice core records in different regions are closely related to the large variability of BC emissions and transportation processes across the Arctic region.Model simulations usually underestimate the concentration of BC in snow and ice by 2–3 times,and cannot accurately reflect the seasonal and regional changes in BC deposition.Wet deposition is the main removal mechanism of BC in the Arctic,and observations show different seasonal variations in BC wet deposition in Ny-Ålesund and Barrow.This discrepancy may result from varying contributions of anthropogenic and biomass burning(BB)emissions,given the strong influence by BC from BB emissions at Barrow.Arctic BC deposition significantly influences regional climate change in the Arctic,increasing fire activities in the Arctic have made BB source of Arctic BC more crucial.On average,BC in Arctic snow and ice causes an increase of+0.17 W·m^(–2)in radiative forcing and 8 Gt·a^(–1)in runoff in Greenland.As stressed in the latest Arctic Monitoring and Assessment Programme report,reliable source information and long-term and high-resolution observations on Arctic BC deposition will be crucial for a more comprehensive understanding and a better mitigation strategy of Arctic BC.In the future,it is necessary to collect more observations on BC deposition and the corresponding physical processes(e.g.,snow/ice melting,surface energy balance)in the Arctic to provide reliable data for understanding and clarifying the mechanism of the climatic impacts of BC deposition on Arctic snow and ice.

Dynamic response of mountain tunnel,bridge,and embankment along the Sichuan-Tibet transportation corridor to active fault based on model tests

The Sichuan-Tibet transportation corridor is prone to numerous active faults and frequent strong earthquakes.While extensive studies have individually explored the effect of active faults and strong earthquakes on different engineering structures,their combined effect remains unclear.This research employed multiple physical model tests to investigate the dynamic response of various engineering structures,including tunnels,bridges,and embankments,under the simultaneous influence of cumulative earthquakes and stick-slip misalignment of an active fault.The prototype selected for this study was the Kanding No.2 tunnel,which crosses the Yunongxi fault zone within the Sichuan-Tibet transportation corridor.The results demonstrated that the tunnel,bridge,and embankment exhibited amplification in response to the input seismic wave,with the amplification effect gradually decreasing as the input peak ground acceleration(PGA)increased.The PGAs of different engineering structures were weakened by the fault rupture zone.Nevertheless,the misalignment of the active fault may decrease the overall stiffness of the engineering structure,leading to more severe damage,with a small contribution from seismic vibration.Additionally,the seismic vibration effect might be enlarged with the height of the engineering structure,and the tunnel is supposed to have a smaller PGA and lower dynamic earth pressure compared to bridges and embankments in strong earthquake zones crossing active faults.The findings contribute valuable insights for evaluating the dynamic response of various engineering structures crossing an active fault and provide an experimental reference for secure engineering design in the challenging conditions of the Sichuan-Tibet transportation corridor.

Quantitative contributions of climate change and human activities to vegetation dynamics in the Zoige Plateau from 2001 to 2020

Climate change and human activities such as overgrazing and rapid development of tourism simultaneously affected the vegetation of the Zoige Plateau.However,the spatiotemporal variations of vegetation and the relative contributions of climate change and human activities to these vegetation dynamics remain unclear.Therefore,clarifying how and why the vegetation on the Zoige Plateau changed can provide a scientific basis for the sustainable development of the region.Here,we investigate NDVI trends using the Normalized Difference Vegetation Index(NDVI)as an indicator of vegetation greenness and distinguish the relative effects of climate changes and human activities on vegetation changes by utilizing residual trend analysis and the Geodetector.We find a tendency of vegetation greening from 2001 to 2020,with significant greening accounting for 21.44%of the entire region.However,browning area expanded rapidly after 2011.Warmer temperatures are the primary driver of vegetation changes in the Zoige Plateau.Climatic variations and human activities were responsible for 65.57%and 34.43%of vegetation greening,and 39.14%and 60.86%of vegetation browning,respectively,with browning concentrated along the Yellow,Black and White Rivers.Compared to 2001-2010,the inhibitory effect of human activity and climate fluctuations on vegetation grew dramatically between 2011 and 2020.

Coupling of the Calculated Freezing and Thawing Front Parameterization in the Earth System Model CAS-ESM

The soil freezing and thawing process affects soil physical properties,such as heat conductivity,heat capacity,and hydraulic conductivity in frozen ground regions,and further affects the processes of soil energy,hydrology,and carbon and nitrogen cycles.In this study,the calculation of freezing and thawing front parameterization was implemented into the earth system model of the Chinese Academy of Sciences(CAS-ESM)and its land component,the Common Land Model(CoLM),to investigate the dynamic change of freezing and thawing fronts and their effects.Our results showed that the developed models could reproduce the soil freezing and thawing process and the dynamic change of freezing and thawing fronts.The regionally averaged value of active layer thickness in the permafrost regions was 1.92 m,and the regionally averaged trend value was 0.35 cm yr–1.The regionally averaged value of maximum freezing depth in the seasonally frozen ground regions was 2.15 m,and the regionally averaged trend value was–0.48 cm yr–1.The active layer thickness increased while the maximum freezing depth decreased year by year.These results contribute to a better understanding of the freezing and thawing cycle process.

Genesis of the Jianbeigou Gold Deposit on the Southern Margin of the North China Craton: Insights from Fluid Inclusions, H-O-S Isotopes, and Pyrite in situ Trace Element Analyses

The Jianbeigou gold deposit is a typical lode gold deposit in the Qinling metallogenic belt, located on the southern margin of the North China Craton. Three stages of the hydrothermal process can be distinguished, including the quartz ± pyrite, quartz-polymetallic sulfide, and quartz-carbonate ± pyrite stages. From the early to late stages, the homogenization temperatures of primary fluid inclusions are 281–362°C, 227–331°C, and 149–261°C, respectively. The corresponding salinities estimated for these fluids are 3.9–9.9 wt%, 0.4–9.4 wt%, and 0.7–7.2 wt% Na Cl equiv. Combined with laser Raman spectroscopy data, the ore-forming fluid belongs to a H_(2)O-CO_(2)-Na Cl ± CH_4 system with medium–low temperature and salinity. The δ~(18)Ofluid and δD values for the quartz veins are-1.0‰ to 6.0‰ and-105‰ to-84‰, respectively, which indicates that the ore-forming fluid is of mixed source, mainly derived from magma, with a contribution from meteoric water. Pyrite has been identified into three generations based on mineral paragenetic sequencing, including Py1, Py2, and Py3. The pyrites have δ~(34)S sulfur isotopic compositions from three stages between 3.7‰ and 8.4‰, indicating that sulfur mainly originated from magma. Te, Bi, Sb, and Cu contents in pyrite were all high and showed a strong correlation with Au concentrations. Native gold and the Au-Ag-Bi telluride minerals were formed concurrently, and the As concentration was low and decoupled from the Au content. Therefore, Te, Bi, Sb and other low-melting point chalcophile elements play an important role for gold mineralization in arsenic-deficient ore-forming fluid. Combined with the geological setting, evolution of pyrite, and ore-fluids geochemistry, we propose that the Jianbeigou deposit can be classified as a magmatic–hydrothermal lode gold deposit. Gold mineralization on the southern margin of the North China Craton is related to Early Cretaceous magmatism and formed in an extensional setting.

Experimental constraints on the formation of oxychlorine species by UV irradiation and mechanical pulverization on the lunar surface

Perchlorate and chlorate are present in various extraterrestrial celestial bodies throughout the solar system,such as Mars,the moon,and asteroids.To date,the origin mechanisms of perchlorate and chlorate on the Martian surface have been well-established;however,relatively little attention has been cast to airless bodies.Here,we experimentally investigated the potential oxidation mechanisms of chloride to chlorate and perchlorate,such as ultraviolet irradiation under H_(2)O-and O_(2)-free conditions and mechanical pulverization processes.Individual minerals,olivine,pyroxene,ilmenite,magnetite,TiO_(2)and anhydrous ferric sulfate,and lunar regolith simulants(low Ti,CLRS-1;high-Ti,CLRS-2)and their metallic iron(Fe^( 0))bearing counterparts were examined.We found that pulverization of dry matrix material-halite mixtures,even in the presence of O_(2),does not necessarily lead to perchlorate and chlorate formation without involving water.Under photocatalytic and H_(2)O and O_(2)-free conditions,olivine and pyroxene can produce oxychlorine(ClO_(x)^(−))species,although the yields were orders of magnitude lower than those under Martian-relevant conditions.Nanophase-Fe^(0)particles in the lunar regolith and the common photocatalyst TiO_(2)can facilitate the ClO_(x)^(−)formation,but their yields were lower than those with olivine.The oxides ilmenite and magnetite did not efficiently contribute to ClO_(x)^(−)production.Our results highlight the critical role of H_(2)O in the oxidation chloride to chlorate and perchlorate,and provide essential insights into the environmental influence on the formation of oxychlorine species on different celestial bodies.

The 2023 M_(w)6.8 Adassil Earthquake(Chichaoua,Morocco)on a steep reverse fault in the deep crust and its geodynamic implications

The Mw 6.8 Adassil earthquake that occurred in the High Atlas on September 8,2023,was a catastrophic event that provided a rare opportunity to study the mechanics of deep crustal seismicity.This research aimed to decipher the rupture characteristics of the Adassil earthquake by analyzing teleseismic waveform data in conjunction with interferometric synthetic aperture radar(InSAR)observations from both ascending and descending orbits.Our analysis revealed a reverse fault mechanism with a centroid depth of approximately 28 km,exceeding the typical range for crustal earthquakes.This result suggests the presence of cooler temperatures in the lower crust,which facilitates the accumulation of tectonic stress.The earthquake exhibited a steep reverse mechanism,dipping at 70°,accompanied by minor strike-slip motion.Within the geotectonic framework of the High Atlas,known for its volcanic legacy and resulting thermal irregularities,we investigated the potential contributions of these factors to the initiation of the Adassil earthquake.Deep seismicity within the lower crust,away from plate boundaries,calls for extensive research to elucidate its implications for regional seismic hazard assessment.Our findings highlight the critical importance of studying and preparing for significant seismic events in similar geological settings,which would provide valuable insights into regional seismic hazard assessments and geodynamic paradigms.

Response of warm season secondary pollutants to emissions and meteorology in the North China Plain region during 2018-2022

自2013年起中国空气质量虽改善,但华北平原(NCP)重污染仍存在且二次污染加剧,而人们对其成因和变化了解有限.本研究利用2018-2022年数据,借助CMAQ模型探讨此污染响应.结果显示,在2018-2022年间,PM_(2.5)浓度显著下降31%-37%,O_(3)和NO_(2)的年下降速率分别为1%和0.5%SIA和SOA也显著减少,每年分别减少9%和6%PM_(2.5)主要因排放减少而下降,而O_(3)则受气象影响而波动.硫酸盐和铵下降的主因是减排,而硝酸盐对气象变化敏感排放和气象变化对SOA的总体减少同样重要,但人为SOA对排放控制敏感生物SOA易受气象变化影响.研究强调了控制人为排放对缓解NCP地区夏季二次污染的重要性.

Correction:The escape mechanisms of the proto-atmosphere on terrestrial planets:“boil-off”escape,hydrodynamic escape and impact erosion

In the original publication of the article,the affiliation“College of Earth and Planetary Sciences,University of Chinese Academy of Sciences,Beijing,People’s Republic of China”for author Ziqi Wang was missing and included in this correction article.

A comparative study of the land-atmosphere energy and water exchanges over the Tibetan Plateau and the Yangtze River Region

正确认识不同区域能量和水分循环特征是研究局地地气相互作用及准确预测区域天气,气候变化的关键.为了研究属于干旱/半干旱气候的青藏高原(TP)和湿润/半湿润气候的长江流域(YRR)之间地表能量和水分交换的异同,本文对比分析了两个区域8个不同地表类型(包括高山荒漠,高山草地,(平原)城市和(平原)草地等)观测站点的地表辐射和能量通量数据.结果显示:(1)TP由于高原大气层稀薄且空气洁净,年平均入射短波辐射为251.3W m^(-2),是YRR的1.7倍.加之高原地表反照率高导致反射辐射(59.6 W m^(-2))是YRR的2.87倍.入射及出射的长波辐射为231.5和338.0 W m^(-2),分别为YRR的0.64和0.83.而两个区域的净辐射差异不大;(2)草地站更多的潜热释放使得地表总加热效率高于城市和高山荒漠,TP和YRR的草地站的年平均潜热分别为35.0和38.8 W m^(-2),而植被稀疏且土壤干燥的高山荒漠地区感热最大,年平均感热为42.1 W m^(-2);其次是城市下垫面,其年平均感热为37.7 W m^(-2).研究结果揭示了不同气候背景下典型下垫面地气相互作用特征,为地气相互作用过程深入分析奠定了基础.

A Study on the Assessment and Integration of Multi-Source Evapotranspiration Products over the Tibetan Plateau

Evapotranspiration(ET)is a crucial variable in the terrestrial water,carbon,and energy cycles.At present,a large number of multi source ET products exist.Due to sparse observations,however,great challenges exist in the evaluation and integration of ET products in remote and complex areas such as the Tibetan Plateau(TP).In this paper,the applicability of the multiple collocation(MC)method over the TP is evaluated for the first time,and the uncertainty of multisource ET products(based on reanalysis,remote sensing,and land surface models)is further analyzed,which provides a theoretical basis for ET data fusion.The results show that 1)ET uncertainties quantified via the MC method are lower in RS-based ET products(5.95 vs.7.06 mm month^(-1))than in LSM ET products(10.22 vs.17.97 mm month^(-1))and reanalysis ET estimates(7.27 vs.12.26 mm month-1).2)A multisource evapotranspiration(MET)dataset is generated at a monthly temporal scale with a spatial resolution of 0.25°across the TP during 2005-15.MET has better performance than any individual product.3)Based on the fusion product,the total ET amount over the TP and its patterns of spatiotemporal variability are clearly identified.The annual total ET over the entire TP is approximately 380.60 mm.Additionally,an increasing trend of 1.59±0.85 mm yr^(-1)over the TP is shown during 2005-15.This study provides a basis for future studies on water and energy cycles and water resource management over the TP and surrounding regions.

Theories and applications of earthquake-induced gravity variation:Advances and perspectives

Earthquake-induced gravity variation refers to changes in the earth’s gravity field associated with seismic activities.In recent years,development in the theories has greatly promoted seismic deformation research,laying a solid theoretical foundation for the interpretation and application of seismological gravity monitoring.Traditional terrestrial gravity measurements continue to play a significant role in studies of interseismic,co-seismic,and post-seismic gravity field variations.For instance,superconducting gravimeter networks can detect co-seismic gravity change at the sub-micro Gal level.At the same time,the successful launch of satellite gravity missions(e.g.,the Gravity Recovery and Climate Experiment or GRACE)has also facilitated applied studies of the gravity variation associated with large earthquakes,and several remarkable breakthroughs have been achieved.The progress in gravity observation technologies(e.g.,GRACE and superconducting gravimetry)and advances in the theories have jointly promoted seismic deformation studies and raised many new research topics.For example,superconducting gravimetry has played an important role in analyses of episodic tremor,slow-slip events,and interseismic strain patterns;the monitoring of transient gravity signals and related theories have provided a new perspective on earthquake early warning systems;the mass transport detected by the GRACE satellites several months before an earthquake has brought new insights into earthquake prediction methods;the use of artificial intelligence to automatically identify tiny gravity change signals is a new approach to accurate and rapid determination of earthquake magnitude and location.Overall,many significant breakthroughs have been made in recent years,in terms of the theory,application,and observation measures.This article summarizes the progress,with the aim of providing a reference for seismologists and geodetic researchers studying the phenomenon of gravity variation,advances in related theories and applications,and future research directions in this discipline.

Research status, hot spots, difficulties and future development direction of microbial geoengineering

Microbial geoengineering technology,as a new eco-friendly rock and soil improvement and reinforcement technology,has a wide application prospect.However,this technology still has many deficiencies and is difficult to achieve efficient curing,which has become the bottleneck of large-scale field application.This paper reviews the research status,hot spots,difficulties and future development direction microbial induced calcium carbonate precipitation(MICP)technology.The principle of solidification and the physical and mechanical properties of improved rock and soil are systematically summarized.The solidification efficiency is mainly affected by the reactant itself and the external environment.At present,the MICP technology has been preliminarily applied in the fields of soil solidification,crack repair,anti-seepage treatment,pollution repair and microbial cement.However,the technology is currently mainly limited to the laboratory level due to the difficulty of homogeneous mineralization,uneconomical reactants,short microbial activity period and large environmental interference,incidental toxicity of metabolites and poor field application.Future directions include improving the uniformity of mineralization by improving grouting methods,improving urease persistence by improving urease activity,and improving the adaptability of bacteria to the environment by optimizing bacterial species.Finally,the authors point out the economic advantages of combining soybean peptone,soybean meal and cottonseed as carbon source with phosphogypsum as calcium source to induce CaCO3.

Assimilation of the FY-4A AGRI Clear-Sky Radiance Data in a Regional Numerical Model and Its Impact on the Forecast of the“21·7”Henan Extremely Persistent Heavy Rainfall

Assimilation of the Advanced Geostationary Radiance Imager(AGRI)clear-sky radiance in a regional model is performed.The forecasting effectiveness of the assimilation of two water vapor(WV)channels with conventional observations for the“21·7”Henan extremely heavy rainfall is analyzed and compared with a baseline test that assimilates only conventional observations in this study.The results show that the 24-h cumulative precipitation forecast by the assimilation experiment with the addition of the AGRI exceeds 500 mm,compared to a maximum value of 532.6 mm measured by the national meteorological stations,and that the location of the maximum precipitation is consistent with the observations.The results for the short periods of intense precipitation processes are that the simulation of the location and intensity of the 3-h cumulative precipitation is also relatively accurate.The analysis increment shows that the main difference between the two sets of assimilation experiments is over the ocean due to the additional ocean observations provided by FY-4A,which compensates for the lack of ocean observations.The assimilation of satellite data adjusts the vertical and horizontal wind fields over the ocean by adjusting the atmospheric temperature and humidity,which ultimately results in a narrower and stronger WV transport path to the center of heavy precipitation in Zhengzhou in the lower troposphere.Conversely,the WV convergence and upward motion in the control experiment are more dispersed;therefore,the precipitation centers are also correspondingly more dispersed.

GRACE time-variable gravity and its application to geoscience:Quantitative analysis of relevant literature

The Gravity Recovery and Climate Experiment(GRACE)is the most important gravity satellite to date in human history.Since its launch in 2002,GRACE time-varying gravity has had an unprecedented impact on earth science and has generated revolutionary changes.Because of natural phenomena such as climate warming,glacial melting,sea level rise,and earthquakes,earth science research has become an increasingly popular discipline in recent years.This article summarizes the importance of GRACE time-varying gravity,its application to geoscience,and its development.We analyzed the historical development and current status of GRACE time-varying gravity as well as research hotspots by searching the literature in the core collection databases of the China National Knowledge Infrastructure and the Web of Science over the past 20 years.The CiteSpace and VOSviewer software packages were applied with reference to the principle of literature metrology.Our investigation and analysis of characteristic indexes,such as the numbers of publications,co-occurrence of keywords,and co-citation of documents,uncovered the wide application and promotion of gravity satellites,especially GRACE time-varying gravity,in earth science.The results showed that the number of publications addressing GRACE data and time-varying gravity theory is increasing annually and that the USA,China,and Germany are the main producers.The Chinese Academy of Sciences,the National Aeronautics and Space Administration of the United States,and the Helmholtz Association of German Research Centres rank among the top three institutions in the world in terms of producing the most publications on this topic.We found that GRACE time-varying gravity plays unique roles in measuring changes in terrestrial water storage changes,ice and snow melting and sea level changes,and(co)seismic gravity changes,as well as in promoting other disciplines.

Distribution of lightning spatial modes and climatic causes in China

本文利用中国气象局国家雷电监测网(CNLDN)的地闪观测数据集,分析了2010-2020年中国陆地区域地闪空间模态分布特征及其可能的气候成因.研究发现,夏季地闪第一模态的方差贡献率为32.86%,其分布从北到南呈现出“-+-”的经向跷跷板模式,当东太平洋和印度洋的海温异常增暖,西北太平洋的海温异常变冷时,在中国黄海,东海及热带西太平洋地区激发出气旋性环流,随着水汽南下至华南地区,与来自孟加拉湾的水汽汇合,上升运动在此加强,从而使得该地区的雷电活动增强.表明厄尔尼诺-南方涛动(ENSO)现象,是发生在中国陆地区域的地闪活动的气候驱动因子。

Diagenetic evolution and effects on reservoir development of the Dengying and Longwangmiao formations,Central Sichuan Basin,Southwestern China

The deeply buried Lower Cambrian Longwangmiao Formation and Upper Ediacaran Dengying Formation from the Sichuan Basin,China,have a total natural gas reserve up to 3×10^(12)m^(3).The complex diagenetic evolution and their impacts on the present-day reservoir quality have not been systematically elucidated,hampering the current exploration.Crucially,the integration and comparation diagenetic study on these two formations,which may be able to shed new lights on reservoir formation mechanism,are yet to be systemically evaluated.By compiling geochemistry data,including carbonate U-Pb ages and petrophysics data,coupled with new petrology,trace elements,and strontium isotope data,of various types of diagenetic carbonates,this study aims to decipher the potential links between diagenesis and reservoir development of both formations.Intriguingly,similar diagenetic sequence,which contains five distinctive dolomite phases,is established in both formations.The matrix dolomite(D1)and early dolomite cement(D2)were likely formed by reflux dolomitization,as inferred by their nearly syn-depositional U-Pb ages and elevatedδ^(18)O caused by seawater evaporation.The subsequent moderate burial dolomite cement(D3)was most plausibly the product of burial compaction as indicated by its lighterδ^(18)O and slightly younger U-Pb ages compared with D1 and D2.Whereas deep burial dolomite cements(D4 and D5)yield markedly depletedδ^(18)O,elevated ^(87)Sr/^(86)Sr,along with much younger U-Pb ages and higher precipitation temperatures,suggesting that they were likely linked to hydrothermal fluids.Despite the wide occurrence of meteoric and organic acids leaching and thermochemical sulfate reduction,they may have only played a subsidiary role on these reservoirs development.Instead,superior reservoir quality is tightly linked to tectonics as inferred by higher reservoir quality closely related to the well-developed fractures and faults filled with abundant hydrothermal minerals.Notably,good reservoirs in both formations are mainly attributed to high permeability caused by tectonics.Hence,this new contribution emphasizes the crucial role of tectonics on spatially explicit reservoir prediction of deep to ultra-deep(up to>8000 m)carbonates in the Sichuan Basin,as well as other sedimentary basin analogues in China.

Multiscale Combined Action and Disturbance Characteristics of Pre-summer Extreme Precipitation Events over South China

The dominant frequency modes of pre-summer extreme precipitation events(EPEs)over South China(SC)between1998 and 2018 were investigated.The 67 identified EPEs were all characterized by the 3-8-d(synoptic)frequency band.However,multiscale combined modes of the synoptic and three low-frequency bands[10-20-d(quasi-biweekly,QBW);15-40-d(quasi-monthly,QM);and 20-60-d(intraseasonal)]accounted for the majority(63%)of the EPEs,and the precipitation intensity on the peak wet day was larger than that of the single synoptic mode.It was found that EPEs form within strong southwesterly anomalous flows characterized by either lower-level cyclonic circulation over SC or a deep trough over eastern China.Bandpass-filtered disturbances revealed the direct precipitating systems and their life cycles.Synoptic-scale disturbances are dominated by mid-high latitude troughs,and the cyclonic anomalies originate from downstream of the Tibetan Plateau(TP).Given the warm and moist climate state,synoptic-scale northeasterly flows can even induce EPEs.At the QBW and QM scales,the disturbances originate from the tropical Pacific,downstream of the TP,or mid-high latitudes(QBW only).Each is characterized by cyclonic-anticyclonic wave trains and intense southwesterly flows between them within a region of large horizontal pressure gradient.The intraseasonal disturbances are confined to tropical regions and influence SC by marginal southwesterly flows.It is concluded that low-frequency disturbances provide favorable background conditions for EPEs over SC and synoptic-scale disturbances ultimately induce EPEs on the peak wet days.Both should be simultaneously considered for EPE predictions over SC.