The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Never...The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Nevertheless,the self-cleaning process may accelerate membrane aging.Addressing these concerns,we present an innovative design concept for composite self-healing materials based on self-cleaning UF membranes.To begin,TiO_(2)nanoparticles were incorporated into the polymer molecular structure via molecular design,resulting in the synthesis of TiO_(2)/carboxyl-polyether sulfone(PES)hybrid materials.Subsequently,the nonsolvent-induced phase inversion technique was employed to prepare a novel of UF membrane.Lastly,a polyvinyl alcohol(PVA)hydrogel coating was applied to the hybrid UF membrane surface to create PVA@TiO_(2)/carboxyl-PES self-healing reactive UF membranes.By establishing a covalent bond,the TiO_(2)nanoparticles were effectively and uniformly dispersed within the UF membrane,leading to exceptional self-cleaning properties.Furthermore,the water-absorbing and swelling properties of PVA hydrogel,along with its capacity to form hydrogen bonds with water molecules,resulted in UF membranes with improved hydrophilicity and active self-healing abilities.The results demonstrated that the water contact angle of PVA@5%TiO_(2)/carboxyl-PES UF membrane was 43.1°.Following a 1-h exposure to simulated solar exposure,the water flux recovery ratio increased from 48.16%to 81.03%.Moreover,even after undergoing five cycles of 12-h simulated sunlight exposure,the UF membranes exhibited a consistent retention rate of over 97%,thus fully demonstrating their exceptional self-cleaning,antifouling,and selfhealing capabilities.We anticipate that the self-healing reactive UF membrane system will serve as a pioneering and comprehensive solution for the self-cleaning antifouling challenges encountered in UF membranes while also effectively mitigating the aging effects of reactive UF membranes.展开更多
Two new metal-organic complexes,{[Co2(bptc)(DPPZ)2(H2O)2]·H2O}n 1 and {[Co2(ccm)2(DPPZ)2]·2H2O}n 2,were obtained by the hydrothermal reactions of Co(NO3)2·6H2O with chelating ligand dipyrido...Two new metal-organic complexes,{[Co2(bptc)(DPPZ)2(H2O)2]·H2O}n 1 and {[Co2(ccm)2(DPPZ)2]·2H2O}n 2,were obtained by the hydrothermal reactions of Co(NO3)2·6H2O with chelating ligand dipyrido[3,2-a:2',3'-c]phenazine(DPPZ) and the corresponding carboxylic acid,namely,3,3',4,4'-benzophenonetetracarboxylic acid(H4bptc) or 2-carboxycinnamic acid(H2ccm),respectively.The complexes were structurally characterized by single-crystal X-ray diffraction,elemental analyses,IR spectra,and thermal gravimetry.1 presents unique chiral chain structures,which are further consolidated into three-dimensional supramolecular frameworks via noncovalent bonds,such as hydrogen bonding and π-π interactions.2 features infinite double-chain structures,which are connected by strong π-π interactions to result in three-dimensional supramolecular architectures.展开更多
Design and synthesis of low cost and efficacious industrial catalyst for the oxidation of styrene has been an important research project.Herein,ZSM-5 zeolite containing tetrahedral vanadium(V)and Br?nsted acid sites(V...Design and synthesis of low cost and efficacious industrial catalyst for the oxidation of styrene has been an important research project.Herein,ZSM-5 zeolite containing tetrahedral vanadium(V)and Br?nsted acid sites(V-H-ZSM-5)was prepared,and identified by characterizations such as XRD,SEM,UV–vis,NH3-TPD,H2-TPR N2-adsorption/desorption and FTIR.V-H-ZSM-5 performed extremely enhanced catalytic activity for the oxidation of styrene with 30%H2O2 at 40°C.Moreover,in-situ FTIR spectrum was used to investigate the catalytic mechanism.The results demonstrate that Br?nsted acid site could not only increase the adsorption concentration of styrene in the micropores of V-H-ZSM-5 via theπcomplex interaction between double bond of styrene and Br?nsted acid sites,but also increase the oxidation potential of H2O2.The synergetic action of tetrahedral vanadium(V)and Br?nsted acid enhanced the catalytic activity for the oxidation of styrene with 30%H2O2.Impressively,V-H-ZSM-5 performed high reusability within five runs at a low reaction temperature(40°C)for the first time.展开更多
The hydrothermal reaction of Cd(OAc)2.H2O with 1,2-benzenedicarboxylate (1,2-BDC), imidazole and H2O resulted in the formation of a binuclear polymeric Cd( Ⅱ ) complex {[Cd2(1,2-BDC)2(Im)4].(H2O)}n which ...The hydrothermal reaction of Cd(OAc)2.H2O with 1,2-benzenedicarboxylate (1,2-BDC), imidazole and H2O resulted in the formation of a binuclear polymeric Cd( Ⅱ ) complex {[Cd2(1,2-BDC)2(Im)4].(H2O)}n which was then characterized by elemental analyses and single-crystal X-ray diffraction analysis. The crystal is of monoclinic system, space group P21/c with a = 14.6455(3), b = 9.3530(2), c = 23.7838(5)A, β= 106.6290(10)°, Cl12H104CdgN32O36, Mr = 3373.47, V = 3121.64(11)A^3, Dc = 1.795 g/cm^3, F(000) = 1672,μ= 1.428 cm^-1 and Z = 1. The final R = 0.0316 and wR = 0.0687 for 5045 reflections with I 〉 2σ(I). In the title complex, the two Cd( Ⅱ) ions are in different coordination environments with distorted octahedral and pengonal bipyramidal geometries, respectively. Two Cd polyhedra are linked together through one μ2-η^1:η^1 and one μ2-η^1:η^1 carboxylate groups from different 1,2-BDC ligands, giving rise to a binuclear Cd( Ⅱ ) cluster, and such clusters are connected by bridged 1,2-BDC ligands to form a 2-D structure along the c axis. The inter- and intermolecular hydrogen bonds further connect the 2-D structures into a 3-D supramolecular network.展开更多
A novel double ladder-like cadmium coordination polymer with isophthalate as bridging ligands and imidazole as non-chelating capping ligands was obtained by a hydrothermal reaction. The crystal is of triclinic, space ...A novel double ladder-like cadmium coordination polymer with isophthalate as bridging ligands and imidazole as non-chelating capping ligands was obtained by a hydrothermal reaction. The crystal is of triclinic, space group P1 with a = 10.266(2), b = 11.573(2), c = 12.651(3) A, α = 89.95(3), β= 74.64(3),γ = 68.54(3)°, C50H44Cd4N12O18, Mr = 1550.57, V= 1341.1(5)A3, Dc = 1.920 g/cm3, F(000) = 764, p = 1.651 cm-1 and Z = 1. The final refinement gave R = 0.0342 and wR = 0.0738 for 5925 observed reflections with I 〉 2σ(I). The crystal structure involves two different ladder-like chains, which are further connected to form a ladder-like double chain architecture via hydrogen bonding interactions, extending along the b axis. The weak interactions including hydrogen bonds and π-π staking interactions contribute to the alignment of the complex in the crystalline state.展开更多
The protection system of products of geographical origin has become one hot subject with which various countries throughout the world are concerned. Results of element-Pb isotope geochemical mapping indicate that ther...The protection system of products of geographical origin has become one hot subject with which various countries throughout the world are concerned. Results of element-Pb isotope geochemical mapping indicate that there emerge a number of famous-brand high-quality product groups of geographical origin in China. The environment of production of China’s famous-brand white spirits of geographical origin at the Sichuan-Guizhou border is still a mystery to be solved. China has two main communities of white spirits of geographical origin, i.e., the most famous are Moutai and Wuliangye spirits. By element-Pb isotope geochemical tracing, we can establish the natural background geological, geographical and geochemical scientific data mark ers in close relation with source areas. Research on the product of geographical origin, named Kaempferia galangal L. in the Shuangjiao district, Yangchun, Guangdong Province, showed that the trace elements have an excellent heritance between Kaempferia galangal L. and soil in this area, and the trace elements are highly effective for tracing the origin.展开更多
基金supported by the National Natural Science Foundation of China(51978133,52100026,U20A20322,52170151,51978132)the Fundamental Research Funds for the Central Universities of China(2412021QD022)+1 种基金the Key Research and Development Project of Hainan Province(ZDYF2022SHFZ298)the Industrialization Cultivation Project of Jilin Provincial Department of Education(JJKH20221174CY)。
文摘The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Nevertheless,the self-cleaning process may accelerate membrane aging.Addressing these concerns,we present an innovative design concept for composite self-healing materials based on self-cleaning UF membranes.To begin,TiO_(2)nanoparticles were incorporated into the polymer molecular structure via molecular design,resulting in the synthesis of TiO_(2)/carboxyl-polyether sulfone(PES)hybrid materials.Subsequently,the nonsolvent-induced phase inversion technique was employed to prepare a novel of UF membrane.Lastly,a polyvinyl alcohol(PVA)hydrogel coating was applied to the hybrid UF membrane surface to create PVA@TiO_(2)/carboxyl-PES self-healing reactive UF membranes.By establishing a covalent bond,the TiO_(2)nanoparticles were effectively and uniformly dispersed within the UF membrane,leading to exceptional self-cleaning properties.Furthermore,the water-absorbing and swelling properties of PVA hydrogel,along with its capacity to form hydrogen bonds with water molecules,resulted in UF membranes with improved hydrophilicity and active self-healing abilities.The results demonstrated that the water contact angle of PVA@5%TiO_(2)/carboxyl-PES UF membrane was 43.1°.Following a 1-h exposure to simulated solar exposure,the water flux recovery ratio increased from 48.16%to 81.03%.Moreover,even after undergoing five cycles of 12-h simulated sunlight exposure,the UF membranes exhibited a consistent retention rate of over 97%,thus fully demonstrating their exceptional self-cleaning,antifouling,and selfhealing capabilities.We anticipate that the self-healing reactive UF membrane system will serve as a pioneering and comprehensive solution for the self-cleaning antifouling challenges encountered in UF membranes while also effectively mitigating the aging effects of reactive UF membranes.
基金Supported by the National Natural Science Foundation of China (No. 60978059)Program for New Century Excellent Talents in University (NCET-10-0176)the Natural Science Foundation of Jilin Province (No. 20090527)
文摘Two new metal-organic complexes,{[Co2(bptc)(DPPZ)2(H2O)2]·H2O}n 1 and {[Co2(ccm)2(DPPZ)2]·2H2O}n 2,were obtained by the hydrothermal reactions of Co(NO3)2·6H2O with chelating ligand dipyrido[3,2-a:2',3'-c]phenazine(DPPZ) and the corresponding carboxylic acid,namely,3,3',4,4'-benzophenonetetracarboxylic acid(H4bptc) or 2-carboxycinnamic acid(H2ccm),respectively.The complexes were structurally characterized by single-crystal X-ray diffraction,elemental analyses,IR spectra,and thermal gravimetry.1 presents unique chiral chain structures,which are further consolidated into three-dimensional supramolecular frameworks via noncovalent bonds,such as hydrogen bonding and π-π interactions.2 features infinite double-chain structures,which are connected by strong π-π interactions to result in three-dimensional supramolecular architectures.
基金supported by the National Natural Science Foundation of China(Nos.21476108,21276125,21776129,21706121 and 21908085)Natural Science Foundation of Jiangsu Province(Nos.BK20170995 and BK20190961)+1 种基金General Program for University Natural Science Research of Jiangsu Province(No.16KJB530003)the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘Design and synthesis of low cost and efficacious industrial catalyst for the oxidation of styrene has been an important research project.Herein,ZSM-5 zeolite containing tetrahedral vanadium(V)and Br?nsted acid sites(V-H-ZSM-5)was prepared,and identified by characterizations such as XRD,SEM,UV–vis,NH3-TPD,H2-TPR N2-adsorption/desorption and FTIR.V-H-ZSM-5 performed extremely enhanced catalytic activity for the oxidation of styrene with 30%H2O2 at 40°C.Moreover,in-situ FTIR spectrum was used to investigate the catalytic mechanism.The results demonstrate that Br?nsted acid site could not only increase the adsorption concentration of styrene in the micropores of V-H-ZSM-5 via theπcomplex interaction between double bond of styrene and Br?nsted acid sites,but also increase the oxidation potential of H2O2.The synergetic action of tetrahedral vanadium(V)and Br?nsted acid enhanced the catalytic activity for the oxidation of styrene with 30%H2O2.Impressively,V-H-ZSM-5 performed high reusability within five runs at a low reaction temperature(40°C)for the first time.
基金the National Natural Science Foundation of China(No.20774011)the Excellent Young Scholars Research Fund of Shanghai(No.YQ307007)
文摘The hydrothermal reaction of Cd(OAc)2.H2O with 1,2-benzenedicarboxylate (1,2-BDC), imidazole and H2O resulted in the formation of a binuclear polymeric Cd( Ⅱ ) complex {[Cd2(1,2-BDC)2(Im)4].(H2O)}n which was then characterized by elemental analyses and single-crystal X-ray diffraction analysis. The crystal is of monoclinic system, space group P21/c with a = 14.6455(3), b = 9.3530(2), c = 23.7838(5)A, β= 106.6290(10)°, Cl12H104CdgN32O36, Mr = 3373.47, V = 3121.64(11)A^3, Dc = 1.795 g/cm^3, F(000) = 1672,μ= 1.428 cm^-1 and Z = 1. The final R = 0.0316 and wR = 0.0687 for 5045 reflections with I 〉 2σ(I). In the title complex, the two Cd( Ⅱ) ions are in different coordination environments with distorted octahedral and pengonal bipyramidal geometries, respectively. Two Cd polyhedra are linked together through one μ2-η^1:η^1 and one μ2-η^1:η^1 carboxylate groups from different 1,2-BDC ligands, giving rise to a binuclear Cd( Ⅱ ) cluster, and such clusters are connected by bridged 1,2-BDC ligands to form a 2-D structure along the c axis. The inter- and intermolecular hydrogen bonds further connect the 2-D structures into a 3-D supramolecular network.
基金supported by the Natural Science Foundation of Shagdong Province (No. Y2007F68)the Excellent Young Scholars Research Fund of Shanghai (No. YQ307007)
文摘A novel double ladder-like cadmium coordination polymer with isophthalate as bridging ligands and imidazole as non-chelating capping ligands was obtained by a hydrothermal reaction. The crystal is of triclinic, space group P1 with a = 10.266(2), b = 11.573(2), c = 12.651(3) A, α = 89.95(3), β= 74.64(3),γ = 68.54(3)°, C50H44Cd4N12O18, Mr = 1550.57, V= 1341.1(5)A3, Dc = 1.920 g/cm3, F(000) = 764, p = 1.651 cm-1 and Z = 1. The final refinement gave R = 0.0342 and wR = 0.0738 for 5925 observed reflections with I 〉 2σ(I). The crystal structure involves two different ladder-like chains, which are further connected to form a ladder-like double chain architecture via hydrogen bonding interactions, extending along the b axis. The weak interactions including hydrogen bonds and π-π staking interactions contribute to the alignment of the complex in the crystalline state.
基金supported jointly by the National Scienctific Foundation of China (40772201)the Pgro-gam of Supporting New Centuary Excellent Talents in University, Ministry of Eduction (NCEL-070219)the Key Projects of Chinese Ministry of Education (207083)
文摘The protection system of products of geographical origin has become one hot subject with which various countries throughout the world are concerned. Results of element-Pb isotope geochemical mapping indicate that there emerge a number of famous-brand high-quality product groups of geographical origin in China. The environment of production of China’s famous-brand white spirits of geographical origin at the Sichuan-Guizhou border is still a mystery to be solved. China has two main communities of white spirits of geographical origin, i.e., the most famous are Moutai and Wuliangye spirits. By element-Pb isotope geochemical tracing, we can establish the natural background geological, geographical and geochemical scientific data mark ers in close relation with source areas. Research on the product of geographical origin, named Kaempferia galangal L. in the Shuangjiao district, Yangchun, Guangdong Province, showed that the trace elements have an excellent heritance between Kaempferia galangal L. and soil in this area, and the trace elements are highly effective for tracing the origin.