A typical hot concentrated alkaline corrosion environment exists in alumina metallurgical industry, so that steel materials with outstanding alkaline corrosion resistance are strongly demanded for its processing equip...A typical hot concentrated alkaline corrosion environment exists in alumina metallurgical industry, so that steel materials with outstanding alkaline corrosion resistance are strongly demanded for its processing equipment. In this paper, the corrosion resistance of two kinds of martensitic cast steels containing chromium in static 303g/L NaOH alkaline solution at 85℃ was studied through polarization and potential-time curves, corrosion weight loss and corrosion morphology analysis. Experimental results showed that protection effect by passive film of cast steel containing Cr was temporary. The low carbon steel without Cr content also exhibited chemical passivity in the same solution. The corrosion mode of the tested Cr-containing cast steel was composed of active dissolving corrosion and caustic embrittlement cracking. Dissolving corrosion was the primary mechanism for the induced weight loss, while severe caustic embrittlement cracking was secondary. With the increase of chromium content in the cast steel, the tendency of the caustic embrittlement cracking decreased, while the active dissolving corrosion increased.展开更多
A jet type erosion-corrosion tester was developed for the erosion-corrosion investigation of high-chromium cast irons. During tests the size and the shape of particles in the slurry can be maintained stable. The jet v...A jet type erosion-corrosion tester was developed for the erosion-corrosion investigation of high-chromium cast irons. During tests the size and the shape of particles in the slurry can be maintained stable. The jet velocity and attack angle can be accurately controlled. The repeatability and ranking consistency of the test results are satisfactory. The test parameters can be adjusted in a wide range, so that the tester can simulate various practical working conditions. Electrochemical test data can be automatically collected and processed. Dynamic polarization curves can be obtained during erosion-corrosion test, which can be used to study the dynamic corrosion characteristics.Two high chromium cast irons were studied in hot concentrated alkaline slurry. The results show that the erosioncorrosion mass loss rate and dynamic corrosion rate of 295Cr26 iron is lower than that of 185Cr13 under the conditions similar to alumyte processing. The mechanism of erosion-corrosion of 295Cr26 and 185Cr13 was studied by using the tester. The interaction between erosion and corrosion was also quantitatively evaluated.展开更多
The factors affecting storage modulus (Ec') and quantitative characterization of polymer composites filled with inorganic particles were discussed in this paper. On the basis of Eshelby’s method and Mori’s work,...The factors affecting storage modulus (Ec') and quantitative characterization of polymer composites filled with inorganic particles were discussed in this paper. On the basis of Eshelby’s method and Mori’s work, an equation describing the relationship between the Ec' and the filler volume fraction, particle geometry as well as interfacial morphology was proposed. The Ec' of the glass bead filled low-density-polyethylene (LDPE/GB) composites was estimated by means of this equation under experimental conditions with temperature range of –150-100?C, frequency of 1 Hz and the amplitude of 0.6 mm, and compared with other equations proposed in literature. The results showed that the predictions for this equation were close to the measured data from the LDPE/GB composites.展开更多
基金The item is sponsored by the Foundation of China National Nonferrous Metals Industry Corporation (96-124).
文摘A typical hot concentrated alkaline corrosion environment exists in alumina metallurgical industry, so that steel materials with outstanding alkaline corrosion resistance are strongly demanded for its processing equipment. In this paper, the corrosion resistance of two kinds of martensitic cast steels containing chromium in static 303g/L NaOH alkaline solution at 85℃ was studied through polarization and potential-time curves, corrosion weight loss and corrosion morphology analysis. Experimental results showed that protection effect by passive film of cast steel containing Cr was temporary. The low carbon steel without Cr content also exhibited chemical passivity in the same solution. The corrosion mode of the tested Cr-containing cast steel was composed of active dissolving corrosion and caustic embrittlement cracking. Dissolving corrosion was the primary mechanism for the induced weight loss, while severe caustic embrittlement cracking was secondary. With the increase of chromium content in the cast steel, the tendency of the caustic embrittlement cracking decreased, while the active dissolving corrosion increased.
文摘A jet type erosion-corrosion tester was developed for the erosion-corrosion investigation of high-chromium cast irons. During tests the size and the shape of particles in the slurry can be maintained stable. The jet velocity and attack angle can be accurately controlled. The repeatability and ranking consistency of the test results are satisfactory. The test parameters can be adjusted in a wide range, so that the tester can simulate various practical working conditions. Electrochemical test data can be automatically collected and processed. Dynamic polarization curves can be obtained during erosion-corrosion test, which can be used to study the dynamic corrosion characteristics.Two high chromium cast irons were studied in hot concentrated alkaline slurry. The results show that the erosioncorrosion mass loss rate and dynamic corrosion rate of 295Cr26 iron is lower than that of 185Cr13 under the conditions similar to alumyte processing. The mechanism of erosion-corrosion of 295Cr26 and 185Cr13 was studied by using the tester. The interaction between erosion and corrosion was also quantitatively evaluated.
文摘The factors affecting storage modulus (Ec') and quantitative characterization of polymer composites filled with inorganic particles were discussed in this paper. On the basis of Eshelby’s method and Mori’s work, an equation describing the relationship between the Ec' and the filler volume fraction, particle geometry as well as interfacial morphology was proposed. The Ec' of the glass bead filled low-density-polyethylene (LDPE/GB) composites was estimated by means of this equation under experimental conditions with temperature range of –150-100?C, frequency of 1 Hz and the amplitude of 0.6 mm, and compared with other equations proposed in literature. The results showed that the predictions for this equation were close to the measured data from the LDPE/GB composites.
