Both a persulfide crystal of L-L（1）, the oxidative coupling product of l-phenyl-lH-tetrazole-5-thiol（HL）, and a neutral copper（1） complex of Cu6L6（2） were self-assembled and their crystal architectures were ch...Both a persulfide crystal of L-L（1）, the oxidative coupling product of l-phenyl-lH-tetrazole-5-thiol（HL）, and a neutral copper（1） complex of Cu6L6（2） were self-assembled and their crystal architectures were characterized by CCD method. HL was converted into the persulfide L-L（1） over a metalloporphyrin catalyst with enzymatic characters under ambient conditions. Whlie in the crystal architecture of Cu6L6（2）, 6 copper（1） ions were ligated by 6L anions to construct a Cu6 ring, which just resembled the chair configuration of cyclohexane. Notably, both compounds 1 and 2 exhibit strong photoluminescence in solid state.展开更多
基金Supported by the National Natural Science Foundation of China(No.20771073)the Third Project of"211"in Guangdong Province,China.
文摘Both a persulfide crystal of L-L（1）, the oxidative coupling product of l-phenyl-lH-tetrazole-5-thiol（HL）, and a neutral copper（1） complex of Cu6L6（2） were self-assembled and their crystal architectures were characterized by CCD method. HL was converted into the persulfide L-L（1） over a metalloporphyrin catalyst with enzymatic characters under ambient conditions. Whlie in the crystal architecture of Cu6L6（2）, 6 copper（1） ions were ligated by 6L anions to construct a Cu6 ring, which just resembled the chair configuration of cyclohexane. Notably, both compounds 1 and 2 exhibit strong photoluminescence in solid state.
