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AMA254汞分析仪测定颗粒物中痕量总汞的研究 被引量:7
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作者 何灿 高良敏 +3 位作者 汪桂林 程学丰 张明旭 Wei-Ping Pan 《中国环境监测》 CAS CSCD 北大核心 2009年第4期26-29,共4页
采用AMA254汞分析仪测定大气颗粒物和煤中的痕量总汞,建立了直接测定颗粒物中痕量总汞的分析方法。测定结果表明,在汞绝对含量为0~35ng范围内线性良好,测定大气颗粒物和煤中的痕量总汞的检出限分别为0.06ng/m^3和0.02ng/g,标... 采用AMA254汞分析仪测定大气颗粒物和煤中的痕量总汞,建立了直接测定颗粒物中痕量总汞的分析方法。测定结果表明,在汞绝对含量为0~35ng范围内线性良好,测定大气颗粒物和煤中的痕量总汞的检出限分别为0.06ng/m^3和0.02ng/g,标准样品测定的RSD≤0.78%,加标回收率为92%~108%。该方法具有无需消解直接进样测定、极其简便、省时等特点,适合多种固体样品中痕量汞的测定。 展开更多
关键词 AMA254 大气颗粒物
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Prediction of coal ash fusion temperatures using computational intelligence based models 被引量:3
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作者 Sanjeev S.Tambe Makarand Naniwadekar +2 位作者 Shishir Tivvary Ashis Mukherjee Tarit Baran Das 《International Journal of Coal Science & Technology》 EI 2018年第4期486-507,共22页
In the coal-based combustion and gasification processes, the mineral matter contained in the coal (predominantly oxides), is left as an incombustible residue, termed ash. Commonly, ash deposits are formed on the heat ... In the coal-based combustion and gasification processes, the mineral matter contained in the coal (predominantly oxides), is left as an incombustible residue, termed ash. Commonly, ash deposits are formed on the heat absorbing surfaces of the exposed equipment of the combustion/gasification processes. These deposits lead to the occurrence of slagging or fouling and. consequently, reduced process efficiency. The ash fusion temperatures (AFTs) signify the temperature range over which the ash deposits are formed on the heat absorbing surfaces of the process equipment. Thus, for designing and operating the coal-based processes, it is important to have mathematical models predicting accurately the four types of AFTs namely initial deformation temperature, softening temperature, hemispherical temperature, and flow temperature. Several linear/nonlinear models with varying prediction accuracies and complexities are available for the AFT prediction. Their principal drawback is their applicability to the coals originating from a limited number of geographical regions. Accordingly, this study presents computational intelligenee (CI) based nonlinear models to predict the four AFTs using the oxide composition of the coal ash as the model input. The CI methods used in the modeling are genetic programming (GP), artificial neural networks, and support vector regression. The no table features of this study are that the models with a better AFT prediction and generalization performanee, a wider application potential, and reduced complexity, have been developed. Among the Ci-based models, GP and MLP based models have yielded overall improved performanee in predicting all four AFTs. 展开更多
关键词 ASH fusion temperature Artificial neural networks Support VECTOR regression GENETIC PROGRAMMING DATA-DRIVEN modeling
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