Microstructure and damping behavior of SiC_p/Gr/2024Al metal matrix composites by squeeze casting technology

SiCp/Gr/2024Al metal matrix composites were processed by squeeze casting technology. The microstructure of composites was observed by SEM and TEM, and the effects of graphite particulates and SiC particulates on the damping behaviors of composites were also investigated. The results show that the microstructure of composites was dense and homogeneous, without any interfacial reactivity among reinforcement/matrix interfaces. Compared with the damping capacity of 2024A1, the damping capacity of composites was enhanced significantly by addition of SiC or graphite particulates. The main damping mechanisms of SiCp/Al composites were ascribed to the dislocation damping, and those of SiCp/Gr/2024Al were attributed to the intrinsic damping and interface damping.

Effect of Weft Binding Structure on Compression Properties of Three-Dimensional Woven Spacer Fabrics and Composites

With the wide use of three-dimensional woven spacer composites(3DWSCs),the market expects greater mechanical properties from this material.By changing the weft fastening method of the traditional I-shape pile yarns,we designed three-dimensional woven spacer fabrics(3DWSFs)and 3DWSCs with the weft V-shape to improve the compression performance of traditional 3DWSFs.The effects of weft binding structures,V-pile densities,and V-shaped angle were investigated in this paper.It is found that the compression resistance of 3DWSFs with the weft V-shape is improved compared to that with the weft I-shape,the fabric height recovery rate is as high as 95.7%,and the average elastic recovery rate is 59.39%.When the interlayer pile yarn density is the same,the weft V-shaped and weft I-shaped 3DWSCs have similar flatwise pressure and edgewise pressure performance.The compression properties of the composite improve as the density of the V-pile yarns increases.The flatwise compression load decreases as the V-shaped angle decreases.When the V-shaped angle is 28°and 42°,the latitudinal V-shaped 3DWSCs perform exceptionally well in terms of anti-compression cushioning.The V-shaped weft binding method offers a novel approach to structural design of 3DWSCs.

Pulsed current-assisted twelve-roll precision rolling deformation of SUS304 ultra-thin strips with exceptional mechanical properties

Innovative pulsed current-assisted multi-pass rolling tests were conducted on a 12-roll mill during the rolling deformation processing of SUS304 ultra-thin strips.The results show that in the first rolling pass,the rolling reduction rate of a conventionally rolled sample(at room temperature)is 33.8%,which can be increased to 41.5%by pulsed current-assisted rolling,enabling the formation of an ultra-thin strip with a size of 67.3μm in only one rolling pass.After three passes of pulsed current-assisted rolling,the thickness of the ultra-thin strip can be further reduced to 51.7μm.To clearly compare the effects of a pulsed current on the microstructure and mechanical response of the ultra-thin strip,ultra-thin strips with nearly the same thickness reduction were analyzed.It was found that pulsed current can reduce the degree of work-hardening of the rolled samples by promoting dislocation detachment,reducing the density of stacking faults,inhibiting martensitic phase transformation,and shortening the total length of grain boundaries.As a result,the ductility of ultra-thin strips can be effectively restored to approximately 16.3%while maintaining a high tensile strength of 1118 MPa.Therefore,pulsed current-assisted rolling deformation shows great potential for the formation of ultra-thin strips with a combination of high strength and ductility.

SiC-Si-ZrSiO_4 Multiphase Oxidation Protective Coating for Carbon/Carbon Composites

In order to improve the anti-oxidation property of carbon/carbon （C/C） composites, a novel SiC-Si-ZrSiO4 multiphase oxidation protective coating was produced on the surface of C/SiC coated carbon/carbon compo ites by a pack cementation technique. The phase composition and microstructure of the as-prepared coatings were characterized by XRD （X-ray diffraction）, SEM （scanning electron microscopy） and EDS （energy dispersive spectroscopy）. Oxidation behavior of the multiphase coated C/C composites was also investigated. It showed that the as-prepared coating characterized by excellent oxidation resistance and thermal shock re- sistance could effectively protect C/C composites from oxidation at 1773 K for 57 h in air and endure the thermal cycle between 1773 K and room temperature for 12 times, whereas the corresponding weight loss is only 1.47%. The excellent oxidation protective ability of the SiC-Si-ZrSiO4 coating could be attributed to the C/SiC gradient inner layer and the multiphase microstructure of the coating.

Si-Al-Ir Oxidation Resistant Coating for Carbon/Carbon Composites by Slurry Dipping

A Si-Al-lr oxidation resistant coating was prepared for SiC coated carbon/carbon composites by slurry dipping. The phase composition, microstructure and oxidation resistance of the as-prepared Si-Al-lr coating were studied by XRD （X-ray diffraction）, SEM （scanning electron microscopy）, and isothermal oxidation test at 1773 K in air, respectively. The surface of the as-prepared Si-Al-lr coating was dense and the thickness was approximately 100 um. Its anti-oxidation property was superior to that of the inner SiC coating. The weight loss of SiC/Si- Al-lr coated carbon/carbon composites was less than 5 wt. pct after oxidation at 1773 K in air for 79 h. The local oxidation defects in the coating may result in the failure of the SiC/Si-Al-Ir coating.

Microstructure and mechanical behavior of Ti/Cu/Ti laminated composites produced by corrugated and flat rolling

Ti/Cu/Ti laminated composites were fabricated by corrugated rolling(CR) and flat rolling(FR) method.Microstructure and mechanical properties of CR and FR laminated composites were investigated by scanning electron microscopy, numerical simulation methods, peel and tensile examinations. The effect of CR and FR was comparatively analyzed. The results showed that the CR and FR laminated composites exhibited different effective plastic strain distributions of the Ti layer and Cu layer at the interface. The recrystallization texture, prismatic texture and pyramidal texture were developed in the Ti layer by CR, while the R-Goss texture and shear texture were developed in the Cu layer by CR. The typical deformation texture components were developed in the Ti layer and Cu layer of FR laminated composites. The CR laminated composites had higher bond strength, tensile strength and ductility.

Effect of porosity on damping behavior of aluminum matrix-fly ash composites

The hollow sphere fly ash/6061Al composite with about 43% porosity in volume fraction (produced by the addition of hollow sphere fly ash particles) was fabricated by squeeze casting technique. Using the same technique, the fly ash/7075Al composite with all the porosity in hollow sphere fly ash infiltrated by molten aluminum was fabricated for partially studying the effect of porosity on the damping behavior of the fly ash/Al composites. The resonant damping capacity of the 'porous' fly ash/6061Al composite reached (20.2-26.9)×10-3 and was about 8 times of the value tested by forced vibration method (in the frequency range 0.2-2 Hz). However, the damping capacity of the as-received 6061Al and the 'dense' fly ash/7075Al composite were consistent by the two testing methods and were in the range of (1.1-7.7)×10-3. The effect of temperature on the damping behavior of the materials was also studied. The related damping mechanisms have also been discussed in light of data from the characterization of microstructure and damping capacity. Due to the inferior mechanical properties of the fly ash particles, the tensile strength of the FA/Al composites was lower than that of the corresponding aluminum alloy matrix and was 70.1 MPa and 180.6 MPa for the 'porous' fly ash/6061Al and 'dense' fly ash/7075Al composite, respectively.

Analysis on the Bonding Failure Mechanism of High Modulus Carbon Fiber Composites

In order to explore the bonding failure mechanism of high modulus carbon fiber composite materials,the tensile experiment and finite element numerical simulation for single-lap and bevel-lap joints of unidirectional laminates are carried out,and the stress distributions,the failure modes,and the damage contours are analyzed. The analysis shows that the main reason for the failure of the single-lap joint is that the stress concentration of the ply adjacent to the adhesive layer is serious owing to the modulus difference,and the stress cannot be effectively transmitted along the thickness direction of the laminate. When the tensile stress of the ply exceeds its ultimate strength in the loading process,the surface fiber will fail. Compared with the single-lap joint,the bevel-lap joint optimizes the stress transfer path along the thickness direction,allows each layer of the laminate to share the load,avoids the stress concentration of the surface layer,and improves the bearing capacity of the bevel-lap joint. The improved bearing capacity of the bevellap joint is twice as much as that of the single-lap joint. The research in this paper provides a new idea for the subsequent study of mechanical properties of adhesively bonded composite materials.

Recent Advances on Challenges and Strategies of Manganese Dioxide Cathodes for Aqueous Zinc-Ion Batteries

Aqueous zinc-ion batteries(AZIBs)are regarded as promising electrochemical energy storage devices owing to its low cost,intrinsic safety,abundant zinc reserves,and ideal specific capacity.Compared with other cathode materials,manganese dioxide with high voltage,environmental protection,and high theoretical specific capacity receives considerable attention.However,the problems of structural instability,manganese dissolution,and poor electrical conductivity make the exploration of high-performance manganese dioxide still a great challenge and impede its practical applications.Besides,zinc storage mechanisms involved are complex and somewhat controversial.To address these issues,tremendous efforts,such as surface engineering,heteroatoms doping,defect engineering,electrolyte modification,and some advanced characterization technologies,have been devoted to improving its electrochemical performance and illustrating zinc storage mechanism.In this review,we particularly focus on the classification of manganese dioxide based on crystal structures,zinc ions storage mechanisms,the existing challenges,and corresponding optimization strategies as well as structure-performance relationship.In the final section,the application perspectives of manganese oxide cathode materials in AZIBs are prospected.

Long-range electron synergy over Pt_(1)-Co_(1)/CN bimetallic single-atom catalyst in enhancing charge separation for photocatalytic hydrogen production

The development of novel single-atom catalysts with optimal electron configuration and economical noble-metal cocatalyst for efficient photocatalytic hydrogen production is of great importance,but still challenging.Herein,we fabricate Pt and Co single-atom sites successively on polymeric carbon nitride(CN).In this Pt_(1)-Co_(1)/CN bimetallic single-atom catalyst,the noble-metal active sites are maximized,and the single-atomic Co_(1)N_4sites are tuned to Co_(1)N_3sites by photogenerated electrons arising from the introduced single-atomic Pt_(1)N_4sites.Mechanism studies and density functional theory(DFT)calculations reveal that the 3d orbitals of Co_(1)N_3single sites are filled with unpaired d-electrons,which lead to the improved visible-light response,carrier separation and charge migration for CN photocatalysts.Thereafter,the protons adsorption and activation are promoted.Taking this advantage of long-range electron synergy in bimetallic single atomic sites,the photocatalytic hydrogen evolution activity over Pt_(1)-Co_(1)/CN achieves 915.8 mmol g^(-1)Pt h^(-1),which is 19.8 times higher than Co_(1)/CN and 3.5 times higher to Pt_(1)/CN.While this electron-synergistic effect is not so efficient for Pt nanoclusters.These results demonstrate the synergistic effect at electron-level and provide electron-level guidance for the design of efficient photocatalysts.

Low-cost biodegradable lead sequestration film for perovskite solar cells

Despite the high efficiency that has been achieved for the perovskite solar cells(PSCs),the hazardous lead leakage from the perovskite absorber layer is one of the crucial barriers still hindering its penetration into the commercial market for a large-scale installation.Herein,we report a novel low-cost and biodegradable lead sequestration layer with high compatibility for up-scalable encapsulation of PSCs.Through a precisely designed cross-linking reaction of chemical agents,the as-made biodegradable chitosan composite film shows enhanced mechanical strength,chemical stability,and lead adsorption capacity.The designed encapsulation strategy reduces over 99.99% lead leakage to <2 ppb under varied simulations of weather conditions(hail,rain,or flood),which meet the safe level of drinking water set by the US Environmental Protection Agency(EPA).Moreover,the PSC efficiency is improved from 21.91% to22.82% due to the improved light absorption from the printed biodegradable lead absorption film.Finally,we present a prototype process of accumulation and recycling of lead compounds in PSCs derbies via the biodegradation process.Based on the low-cost biodegradable lead sequestration film,this environmental-friendly encapsulation strategy could address the lead leakage issue for further commercialization of PSCs.

MXene Ti_(3)C_(2) decorated g-C_(3)N_(4)/ZnO photocatalysts with improved photocatalytic performance for CO_(2) reduction

Photocatalytic reduction of CO_(2) is considered as a kind of promising technologies for solving the greenhouse effect.Herein,a novel hybrid structure of g-C_(3)N_(4)/ZnO/Ti_(3)C_(2) photocatalysts was designed and fabricated to investigate their abilities for CO_(2) reduction.As demonstration,heterojunction of g-C_(3)N_(4)/ZnO can improve photogenerated carriers’separation,the addition of Ti_(3)C_(2) fragments can further facilitate the photocatalytic performance from CO_(2) to CO.Hence,g-C_(3)N_(4)/ZnO/Ti_(3)C_(2) has efficiently increased CO production by 8 and 12 times than pristine g-C_(3)N_(4) and ZnO,respectively.Which is ascribed to the photogenerated charge migration promoted by metallic Ti_(3)C_(2).This work provides a guideline for designing efficient hybrid catalysts on other applications in the renewable energy fields.

Regulating solid electrolyte interphases on phosphorus/carbon anodes via localized high-concentration electrolytes for potassium-ion batteries

The resourceful and inexpensive red phosphorus has emerged as a promising anode material of potassium-ion batteries(PIBs) for its large theoretical capacities and low redox potentials in the multielectron alloying/dealloying reactions,yet chronically suffering from the huge volume expansion/shrinkage with a sluggish reaction kinetics and an unsatisfactory interfacial stability against volatile electrolytes.Herein,we systematically developed a series of localized high-concentration electrolytes(LHCE) through diluting high-concentration ether electrolytes with a non-solvating fluorinated ether to regulate the formation/evolution of solid electrolyte interphases(SEI) on phosphorus/carbon(P/C) anodes for PIBs.Benefitting from the improved mechanical strength and structural stability of a robust/uniform SEI thin layer derived from a composition-optimized LHCE featured with a unique solvation structure and a superior K+migration capability,the P/C anode with noticeable pseudocapacitive behaviors could achieve a large reversible capacity of 760 mA h g^(-1)at 100 mA g^(-1),a remarkable capacity retention rate of 92.6% over 200 cycles at 800 mA g^(-1),and an exceptional rate capability of 334 mA h g^(-1)at8000 mA g^(-1).Critically,a suppressed reduction of ether solvents with a preferential decomposition of potassium salts in anion-derived interfacial reactions on P/C anode for LHCE could enable a rational construction of an outer organic-rich and inner inorganic-dominant SEI thin film with remarkable mechanical strength/flexibility to buffer huge volume variations and abundant K+diffusion channels to accelerate reaction kinetics.Additionally,the highly reversible/durable full PIBs coupling P/C anodes with annealed organic cathodes further verified an excellent practical applicability of LHCE.This encouraging work on electrolytes regulating SEI formation/evolution would advance the development of P/C anodes for high-performance PIBs.

Bacterial Cellulose Nanofibers as Reinforcement for Preparation of Bamboo Pulp Based Composite Paper

Bamboo fibers(BFs),with features of renewability and biodegradability,have been widely used in paper-making products.In order to improve the mechanical properties and water absorption behaviors of the BF paper,bacterial cellulose nanofibers(BCNFs)as environmentally friendly nano-fibrillated cellulose(NFC)were combined with BFs.The structures and properties of the BF/BCNF composite paper were characterized by field emission scanning electron microscopy(FE-SEM),X-ray diffraction(XRD),Fourier transforms infrared(FTIR)spectroscopy,mechanical tests,pore size tests,and water absorption tests.The results indicated that the addition of BCNFs could significantly improve the water absorption capacity and mechanical properties.The water absorption ratio of the BF/BCNF composite paper with a BCNF mass fraction of 9%comes to 443%,about 1.33 times that of the pure BF paper.At the same BCNF content,the tensile strength of the BF/BCNF composite paper in dry and wet states was 12.37 MPa and 200.9 kPa,respectively,increasing by 98.24%and 136.91%as compared with that of the BF paper.

Resonance and Bifurcation of Fractional Nonlinear Systems with Power Damping Term for Robot Grinding

A fractional nonlinear system with power damping term is introduced to study the forced vibration system in order to solve the resonance and bifurcation problems between grinding wheel and steel bar during robot grinding.The robot,grinding wheel and steel bar are reduced to a spring-damping second-order system model.The implicit function equations of vibration amplitude of the dynamic system with coulomb friction damping,linear damping,square damping and cubic damping are obtained by average method.The stability of the system is analyzed and explained,and the stability condition of the system is proposed.Then,the amplitude-frequency characteristic curves of the system under different fractional differential orders,nonlinear stiffness parameters,fractional differential term coefficients and external excitation amplitude are analyzed.It is shown that the fractional differential term in the dynamic system is the damping characteristic.Then the influence of four kinds of damping on the vibration amplitude of the system under the same parameter is investigated and it is proved that the cubic damping suppresses the vibration of the system to the maximum extent.Finally,based on the idea that the equilibrium point of the system is the constant part of the Fourier series expansion term,the bifurcation behavior caused by the change of damping parameters in linear damping,square damping and cubic damping systems with different values of fractional differential order is investigated.

基于实验和元胞自动机模拟的TiNb合金非连续动态再结晶研究

TiNb合金因其良好的塑性、机械加工性能和超导电性而被广泛应用于低温超导领域。动态再结晶作为材料加工过程中常见的软化行为,对材料的组织和性能有重要的影响。将实验与元胞自动机模拟相结合,研究了TiNb合金在热压缩过程中的非连续动态再结晶行为。元胞自动机模拟可以较为准确地预测TiNb合金的非连续动态再结晶行为。再结晶晶粒的平均尺寸和体积分数随着变形温度的升高而增大,随着应变速率的升高而减小。TiNb合金变形试样中的锯齿状晶界和再结晶晶粒形核位置符合晶界弓出机制特征。此外,非连续动态再结晶晶粒的随机取向效应有助于减弱TiNb合金中变形织构的强度。

Dynamic Analysis and Dimensional Synthesis of Easy-to-Protect Large-Load Robot for Extracting Fermented Grains

To improve the operation situation of difficulty and low efficiency in the extraction of fermented grains(FG),a high-load and large-workspace reclaiming robot for ceramic cylinder fermentation is designed,and a reclaiming effector is designed according to the operating characteristics.Firstly,the kinematics and singularity of the mechanism are analyzed.A multi-domain polar coordinate search method is proposed to obtain the workspace and the volume of the mechanism.Secondly,the dynamic modeling is completed and the example simulation is carried out.Thirdly,the motion-force transmission index of the mechanism is established.And based on the global transmissibility and the good-transmission workspace,the dimensional synthesis of the driving mechanism is completed by using the performance atlas-based method.Finally,aiming at the regular workspace size,stiffness and loading capacity,the Pareto optimal solution set of the executive mechanism dimension is obtained by using the multi-objective particle swarm optimization(MOPSO)algorithm.This paper can provide a theoretical basis for the optimal design and control of FG reclaiming robot.

Hybrid reinforced thermoset polymer composite in energy absorption tube application:A review

The custom of hybridization fibre composite in energy absorption tube application has gained the attention of structural crashworthiness in composite material industry. Thus, the approach of this review is to understand the effect in hybridization within metal/synthetic fibre composite, synthetic/synthetic fibre composite and nature/synthetic fibre composite as energy absorption tube, which reflects on the energy absorption characteristics and crashworthiness behaviors in previous the study. By way of instance, a wide range of methodology and particular parameter in previous study such as the effect in fibre arrangement, matrix polymer, technique of fabrication, fibre treatment(natural fibre), design in geometry/cross-section and others mechanism of hybrid fibre composite tube are highlighted which to comprehend the capability of the mechanical performance and collapsible behavior as sacrificial structure in high-performance structure applications. Moreover, in the recently studies there have been many of the research regarding structural materials as energy absorption tube has been introduced such as metal/matrix composites, new alloy metals and polymer composites which intended to evaluate the performance of these materials into circumstance in loading and impact characteristic. Therefore, this review article is trying to explore the research articles related to the effect of hybridization fibres and thermoset polymer as reinforcement for energy absorption tube research and expected would provide an information and idea which to expend the knowledge in future study of hybridization effect for energy absorption tube, moreover the development for future potential as new hybrid composite fibre materials from the natural/synthetic fibres reinforced composite material in employing of high-performance energy absorption tube application is still less discover and highlighted.

Structure and Oxidation Behavior of a Plasma Sprayed Yttrium Silicates Coated SiC-C/C with a Glass Outer Sealant from 1573K to 1873K

Different compositions of yttrium silicates coatings were deposited on SiC-C/C by plasma spraying and an outer borosilicate glass was applied on the yttrium silicates coatings surfaces. The structure of the multi-layer coatings was characterized by XRD and SEM analyses. High temperature oxidation behavior of the multi-layer coatings coated C/C composites was investigated. Results show that SiC/2SiO2 Y2O3/1.5SiO2 Y203/ SiO2 Y2O3/glass multi-layer coating has better high temperature oxidation resistance, protecting carbon/ carbon composites from oxidation at 1 773 K in air for 164 h with the weight loss of 1.65%. The oxidation weight loss of the coated C/C with time accorded with parabolic rule in the temperature range 1 573 K-1 873 K; and the corresponding oxidation activation energy of the coated carbon/carbon composites is 132.2 kJ/mol.

Prediction and Analysis of the Force and Shape Parameters in Variable Gauge Rolling

Variable gauge rolling is a new process to obtain a plate for which the thickness changes continuously by continuously and dynamically adjusting the roll gap upward and downward in the rolling process.This technology is an efective method for producing lightweight,low-cost,and economical plates.However,variable gauge rolling is an unsteady process,and the changes in the force and deformation parameters are complex.In this research,based on the minimum energy theory of the variational principle and considering the characteristics of the roll movement and workpiece deformation comprehensively,the internal plastic deformation,friction,shear and tension powers,and the minimum result of the total power functional in upward and downward rolling are obtained with the frst integral and then with a variation of adopting the specifc plastic power and strain rate vector inner product.The analytical results of the deformation and force parameters are also established using the variational method.Then the precision of this model is certifed using the measured values in a medium plate hot rolling plant and the experimental data for Tailor Rolled Blank rolling.Good agreement is found.Additionally,the variation rule of bite angle,neutral angle,and location neutral points are shown,and the change mechanism of the friction parameter on the stress state efect coefcient is given in variable gauge rolling.This research proposes a new mathematical model for rolling process control that provides a scientifc basis and technical support for obtaining an accurate section shape in variable gauge rolling production.