An efficient,inexpensive and simple method for the reduction of variousα,β-unsaturated ketones to corre-sponding saturated ketones using tosyl hydrazide as a hydrogen donor in DMF using calcium oxide powder has been...An efficient,inexpensive and simple method for the reduction of variousα,β-unsaturated ketones to corre-sponding saturated ketones using tosyl hydrazide as a hydrogen donor in DMF using calcium oxide powder has been reported.A variety of enones underwent reduction without forming undesirable side products.High chemose-lectivity,broad functional group tolerance and good yields are the noteworthy features of this protocol.展开更多
基金University Grant Commission-Basic Science Research(Order no DV-5/662/RFSMS/2012-13),New Delhi,India for financial support.
文摘An efficient,inexpensive and simple method for the reduction of variousα,β-unsaturated ketones to corre-sponding saturated ketones using tosyl hydrazide as a hydrogen donor in DMF using calcium oxide powder has been reported.A variety of enones underwent reduction without forming undesirable side products.High chemose-lectivity,broad functional group tolerance and good yields are the noteworthy features of this protocol.
