Synthesis and high-temperature performance of Ti substituted α-Ni(OH)_2

Ti substituted α-Ni（OH）2（c=2.121nm, a =0.307nm） with perfect high-temperature performance was prepared by the co-precipitation method. The effects of Ti addition on the structure and the electrochemical properties were investigated. The results indicate that the substitution of Ti for Ni leads to the conversion of β-Ni（OH）2 to α-Ni（OH）2 and the increase of the inter layer distance along c-axis from 0.464nm to 0.707nm. Infrared study reveals that more anions（SO2-4 and CO2-3 ions） and H2O exist in the Ti substituted α-Ni（OH）2. The discharge capacity of the Ti substituted α-Ni（OH）2 is 210mA·h/g at 20℃ and reaches up to 270mA·h/g at 80℃ owing to the inhibition of the oxygen evolution at high temperature.

纳秒脉冲在普通单模光纤中产生超连续谱的实验研究

利用中心波长1064 nm的纳秒激光脉冲入射到普通单模光纤中,获得了从700 nm到超过1750 nm的超连续谱输出。在正常色散区抽运下,光谱首先出现多级拉曼斯托克斯线,随着抽运功率或光纤长度的增加,斯托克斯能量将进入光纤反常色散区,形成光孤子,随后与孤子相关的非线性效应将使光谱进一步展宽。实验结果表明,当单模光纤长度为28 m时,产生的光谱在1260~1750 nm范围内,有较好的光谱平坦度（小于3.8 dB）、较强的光谱光功率密度（平均约为0.4 mW/nm）并且单模输出。