Methyltrioxorhenium (MTO) and its derivatives were utilized as catalysts for a broad variety of organic reactions after the discovery of an easy synthetic access way to this class of compounds. Among the numerous char...Methyltrioxorhenium (MTO) and its derivatives were utilized as catalysts for a broad variety of organic reactions after the discovery of an easy synthetic access way to this class of compounds. Among the numerous characterization techniques, 17O-NMR spectroscopy and vibrational spectroscopy were exemplary discussed. The immobilization of MTO and its derivatives is of significant current interest as is the synthesis of chiral derivatives.展开更多
基金This work was financially supported by FEK is grateful to the Funds of Chemical Industrie for continuous support KRJ thanks BASF for financial support.
文摘Methyltrioxorhenium (MTO) and its derivatives were utilized as catalysts for a broad variety of organic reactions after the discovery of an easy synthetic access way to this class of compounds. Among the numerous characterization techniques, 17O-NMR spectroscopy and vibrational spectroscopy were exemplary discussed. The immobilization of MTO and its derivatives is of significant current interest as is the synthesis of chiral derivatives.
