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Flower morphology of Allium(Amaryllidaceae)and its systematic significance
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作者 Ju Eun Jang Shukherdorj Baasanmunkh +5 位作者 Nudkhuu Nyamgerel Seung-Yoon Oh Jun-Ho Song Ziyoviddin Yusupov Komijlon Tojibaev Hyeok Jae Choi 《Plant Diversity》 SCIE CAS CSCD 2024年第1期3-27,共25页
Allium is a complicated genus that includes approximately 1000 species.Although its morphology is well studied,the taxonomic importance of many morphological traits,including floral traits,are poorly understood.Here,w... Allium is a complicated genus that includes approximately 1000 species.Although its morphology is well studied,the taxonomic importance of many morphological traits,including floral traits,are poorly understood.Here,we examined and measured the floral characteristics of 87 accessions of 74 Allium taxa(belonging to 30 sections and nine subgenera)from Central to Eastern Asian countries.We then examined the taxonomic relationships between select flower characteristics and a phylogenetic tree based on ITS sequences.Our results confirm that floral morphology provides key taxonomic information to assess species delimitation in Allium.We found that perianth color is an important characteristic within the subg.Melanocrommyum,Polyprason,and Reticulatobulbosa.In subg.Allium,Cepa,and Rhizirideum,significant characteristics include ovary shape,perianth shape,and inner tepal apex.For species in subg.Angunium,the key taxonomic character is ovule number(only one ovule in per locule).In the subg.Allium,Cepa,Polyprason,and Reticulatobulbosa,which belong to the third evolutionary line of Allium,hood-like appendages occur in the ovary,although these do not occur in subg.Rhizirideum.Our results also indicated that the flower morphology of several species in some sections are not clearly distinguished,e.g.,sect.Sacculiferum(subg.Cepa)and sect.Tenuissima(subg.Rhizirideum).This study provides detailed photographs and descriptions of floral characteristics and information on general distributions,habitats,and phenology of the studied taxa. 展开更多
关键词 ALLIUM Flower morphology Pistil character Statistical analysis Significant characteristic Species level
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Genome-wide identification and spatiotemporal expression profiling of zinc finger SWIM domain-containing protein family genes
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作者 Imtiaz Ul Hassan Hafiz Mamoon Rehman +7 位作者 Ziran Liu Liangji Zhou Muhammad Kaleem Samma Chengdong Wang Zixin Rong Xufeng Qi Dongqing Cai Hui Zhao 《Zoological Research》 SCIE CAS CSCD 2023年第3期663-674,共12页
The biological function of the novel zinc-finger SWIM domain-containing protein family(ZSWIM)during embryonic development remains elusive.Here,we conducted a genome-wide analysis to explore the evolutionary processes ... The biological function of the novel zinc-finger SWIM domain-containing protein family(ZSWIM)during embryonic development remains elusive.Here,we conducted a genome-wide analysis to explore the evolutionary processes of the ZSWIM gene family members in mice,Xenopus tropicalis,zebrafish,and humans.We identified nine putative ZSWIM genes in the human and mouse genome,eight in the Xenopus genome,and five in the zebrafish genome.Based on multiple sequence alignment,three members,ZSWIM5,ZSWIM6,and ZSWIM8,demonstrated the highest homology across all four species.Using available RNA sequencing(RNAseq)data,ZSWIM genes were found to be widely expressed across different tissues,with distinct tissuespecific properties.To identify the functions of the ZSWIM protein family during embryogenesis,we examined temporal and spatial expression patterns of zswim family genes in Xenopus embryos.Quantitative real-time polymerase chain reaction(qRT-PCR)revealed that each member had a distinct expression profile.Whole-mount in situ hybridization showed that both zswim1 and zswim3 were maternally expressed genes;zswim5 and zswim6were expressed throughout embryogenesis and displayed dynamic expression in the brain,eyes,somite,and bronchial arch at the late tailbud stages;zswim7 was detected in the eye area;zswim8 showed a dynamic expression pattern during the tailbud stages,with expression detected in the brain,eyes,and somite;zswim9 was faintly expressed throughout embryonic development.This study provides a foundation for future research to delineate the functions of ZSWIM gene members. 展开更多
关键词 ZSWIM gene family XENOPUS Gene expression Phylogenetic analysis BIOINFORMATICS
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Antioxidant Activity and Phytochemical Screening in Acacia rigidula Benth. Leaves
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作者 Aneth Ochoa-Negrete Rene Rangel +1 位作者 Marcus Antonius Ynalvez Ruby A. Ynalvez 《Advances in Bioscience and Biotechnology》 CAS 2024年第1期15-38,共24页
This study aimed to compare the total phenolic content (TPC) and antioxidant activities of A. rigidula extracts. It also aimed to identify phenolic acids present in the extracts. The 2,2-azinobis-(3-ethylbenzothiazoli... This study aimed to compare the total phenolic content (TPC) and antioxidant activities of A. rigidula extracts. It also aimed to identify phenolic acids present in the extracts. The 2,2-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), 2,2-diphenyl-1-picrylhydrazyl (DPPH), ferric reducing antioxidant power (FRAP), and ferric thiocyanate lipid peroxidation antioxidant assays were performed. High performance liquid chromatography was used to identify phenolic acids. There was no solvent effect on TPC nor on scavenging activities, and inhibition of lipid peroxidation (p > 0.05) among solvent extracts. On the other hand, 1:1:3 water: acetone: methanol extract (10.22 mg GAE/g sample) had significantly higher reducing potential than 50% ethanol extract (EE) (9.259 mg GAE/g sample) (p < 0.05);but EE was not significantly different from 80% methanol extract (9.781 mg GAE/g sample) (p > 0.05). Phenolic fraction designated as fraction 4 had the highest antioxidant activity (p < 0.05) with 69.49% ABTS scavenging activity and FRAP reducing potential, 22.26 mg of GAE/g sample. DPPH scavenging activities of fractions 4 (55.59%) and 5 (55.64%) were significantly higher than the other fractions (p A. rigidula extracts contain gallic, caffeic, vanillic, p-coumaric, salicylic acids and vanillin. 展开更多
关键词 ACACIA Plant Extract Antioxidant Activity Total Phenolic Acid HPLC Gallic Acid
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Evaluation of Human Impacts on Bartlett Pond Ecosystem, Laredo, Southern Texas, USA, through Empirical Modeling
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作者 Maya P. Bhatt Amede Rubio +6 位作者 Ganesh B. Malla Cristobal Lopez Virginia Morales Erick Vazquez Cano David Marquez Orlando Berumen Alvarez Alfred Addo-Mensah 《Journal of Environmental Protection》 2024年第4期497-526,共30页
The trace elements chemistry of Bartlett Pond, a small shallow wetland pond in Laredo, Southern Texas, was sampled to evaluate the dynamics of trace elements impacts on water quality and ecosystems ecology of the pond... The trace elements chemistry of Bartlett Pond, a small shallow wetland pond in Laredo, Southern Texas, was sampled to evaluate the dynamics of trace elements impacts on water quality and ecosystems ecology of the pond. Two types of fish (bass and tilapia) were also sampled to see the trace element accumulation in different parts of their body. The concentrations of trace elements in water samples were found in the following order: Fe &Gt;Sb > Pb > As &Gt;Co > Tl > Cr > Cd within Bartlett Pond. Overall, the water quality of the pond is unacceptable for drinking and any other purposes as trace element concentrations (e.g. As, Cd, Co, Cr, Pb, Fe, Sb and Tl) are exceedingly higher (several fold) than the WHO and US EPA guidelines. Predictive and correlation analysis shows that most trace elements exhibit a strong positive correlation among them indicating the same anthropogenic sources and biogeochemical processes regulate these trace elements within the pond. Distributions of the trace elements in water exhibit different shapes mostly as positively skewed distribution for As, Cd, Co, Cr, and Tl, symmetrical distribution for Fe and almost symmetrical distribution for Pb and Sb. Concentrations of As, Co and Tl accumulated much higher in different parts of the Bass than Tilapia fish. The concentrations of As, Tl, Co, and Sb appeared significantly higher in different parts of the body of both Bass and Tilapia than the maximum SRM certified values. Accumulation of these contaminants in fish tissues pose increased health risks to humans who consume these contaminated fish although fishing is prohibited. Anthropogenic activities in the region primarily degrade the whole pond ecosystem ecology of the Bartlett Pond and waters of this pond to be not recommended for any use. These findings may be useful for the scientific community and concerned authorities to improve understanding about these precious natural resources and conservation of the ecosystem ecology. 展开更多
关键词 Trace Elements Bartlett Pond Laredo Southern Texas WETLANDS Ecosystem Ecology
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Heavy metal concentrations in edible bivalves and gastropods available in major markets of the Pearl River Delta 被引量:20
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作者 FANG Zhan-qiang CHEUNG R.Y.H. WONG M.H. 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2001年第2期210-217,共8页
Molluscs are able to accumulate heavy metals and impose health hazard to consumers. The main objective of the present study is to investigate the heavy metal concentrations in edible bivalves and gastropods available ... Molluscs are able to accumulate heavy metals and impose health hazard to consumers. The main objective of the present study is to investigate the heavy metal concentrations in edible bivalves and gastropods available in major markets of the Pearl River Delta. Fourteen species of edible molluscs were purchased from six markets in Hong Kong and Guangdong Province. The fresh of these biota were tested for their cadmium (Cd), copper (Cu), zinc (Zn), lead (Pb), nickel (Ni), chromium (Cr), antimony (Sb) and tin (Sn) concentrations (based on wet weight). The results indicated that amongst the 14 edible molluscs, only Cd, Pb, Ni, Cr, Sb and Sn concentrations in three species (Ruditapes philippinarum, Perna viridis and Hemifusus tuba) were within the local regulatory limits. Over 60% of bivalve species exceeded maximum permitted levels of Cd (2 mug/g) and Cr (1 mug/g), while over 40% of gastropod species exceeded the maximum levels of Sb (1 mug/g) and Cr (1 mug/g). Most of the samples collected from Hong Kong had significantly higher contents of Pb and Sb, but similar levels of Cd, Cu and Zn when compared with samples collected across the border ( p < 0.05; p 0.01; p < 0.001 respectively). In general, the molluscs purchased in Guangdong markets had higher metal contents than those purchased from the Hong Kong markets. When compared with the Provisional Tolerable Weekly Intake or Maximum Acceptable Daily Load recommended by FAO/WHO Expert Committee on Food Additives, Cd levels of five species (Anadara ferruginea, Pinna pectinata, Chlamys nobilis, Babylonia lutosa and Hemifusus terntanus) and Cr levels of seven species ( Anadara ferruginea, Paphia undulata, Pinna pectinata, Babylonia lutosa, Hemifusus terntanus, Cymbium melo and Cipangopaludina chinensis) were higher than both the human daily acceptable limits (for Cd and Cr respectively) and the local regulatory levels (for Cd and Cr respectively). 展开更多
关键词 heavy metals edible molluscs human health Pearl River Delta
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Effects of Accelerated Aging on Physiological and Biochemical Characteristics of Waxy and Non-waxy Wheat Seeds 被引量:10
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作者 QIN Peng KONG Zhiyou +1 位作者 LIAO Xiaohong LIU Yeju 《Journal of Northeast Agricultural University(English Edition)》 CAS 2011年第2期7-12,共6页
Experiments were conducted to evaluate the physiological and the biochemical characteristics of waxy wheat seeds under accelerated aging conditions. Five waxy wheat lines, which were Waxy 1, Waxy 4, Waxy 8, Waxy 9, an... Experiments were conducted to evaluate the physiological and the biochemical characteristics of waxy wheat seeds under accelerated aging conditions. Five waxy wheat lines, which were Waxy 1, Waxy 4, Waxy 8, Waxy 9, and Waxy 15; and five non-waxy wheat lines: S-39, 04J89, Jan-81, III42-4, and II110 were studied. The seeds were subjected to accelerated aging at 40℃, 45℃, 50℃, 55℃, and 60℃, and 90% relative humidity for 0, 2, 4, 6, and 8 days, respectively. The results showed a gradual increase in conductivity and decrease in germination rate during accelerated aging. SOD, POD and CAT activities increased at lowgrade treatment, but decreased at severe treatment. On the other hand, the soluble protein content decreased at 45 ℃, but successively increased, then decreased 50℃. From the above study, it showed that 90% RH at 55℃ was the best accelerated aging condition for optimum efficiency in a shorter period. 展开更多
关键词 accelerated aging waxy wheat non-waxy wheat physiological and biochemical characteristics
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Effects of Lanthanum on Formation and Bone-Resorbing Activity of Osteoclast-Like Cells 被引量:4
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作者 张金超 张天蓝 +3 位作者 许善锦 王夔 于世凤 杨梦苏 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第6期891-895,共5页
The effect of La^(3+) on formation of osteoclast-like cells in rabbit bone marrow cells induced by 1,25-dihydroxyvitamin D_3 and their bone-resorbing activity was evaluated by counting the number of tartrate resistant... The effect of La^(3+) on formation of osteoclast-like cells in rabbit bone marrow cells induced by 1,25-dihydroxyvitamin D_3 and their bone-resorbing activity was evaluated by counting the number of tartrate resistant-acid phosphatase-positive [TRAP(+)] multi-nucleated cells and measuring the number and surface area of bone resorption pits with photomicrography and image analysis. The formation and morphological characteristics of osteoclast-like cells and bone resorption pits were observed under a phase contrast inverted microscope. La^(3+) promotes the formation of osteoclast-like cells at the concentration of 1.00×10^(-8)mol·L^(-1) compared with the control group(P<(0.01)), whereas no significant change in cell number is observed at higher concentrations(1.00×10^(-5), (1.00×)10^(-6) and 1.00×10^(-7) mol·L^(-1))(P>0.05). La^(3+) at the concentration of 1.00×10^(-8)mol·L^(-1) also increases the number and surface area of the resorption pits(P<0.01), but inhibits the bone-resorbing activity dose-dependently(P<0.01)at higher concentrations(1.00×10^(-5), 1.00×10^(-6) and 1.00×10^(-7) mol·L^(-1)). These findings suggest that La^(3+) may promote or inhibit the formation and bone-resorbing activity of osteoclast-like cells depending on its concentration. 展开更多
关键词 LANTHANUM osteoclast-like cells 1 25-dihydroxyvitamin D_3 bone marrow cells bone resorption rare earths
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The First Example of Inorganic-organic Compound Involving the Largest Vanadium Cluster of [V_(34)O_(82)]^(10-): Hydrothermal Synthesis and Characterization of a One-dimensional Chain of {[NiC_(16)H_(36)N_4]_5[V_(34)O_(82)]}_n 被引量:5
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作者 欧光川 袁先友 李治章 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2013年第3期375-380,共6页
The title compound, [NiL]5[V34O82·8H2O (1, L=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), has been synthesized under hydrothermal conditions and structurally characterized by EA, IR, XPS, TG an... The title compound, [NiL]5[V34O82·8H2O (1, L=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), has been synthesized under hydrothermal conditions and structurally characterized by EA, IR, XPS, TG and single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group C2/c with a=33.061(4), b=15.3457(17), c=33.902(4), β=101.930(2)°, Mr=4904.08, V=16828(3)3 , Z=4, Dc=1.936 g/cm3 , F(000)=9832, μ=2.425 mm-1 , the final R=0.0402 and wR=0.0969. The mixed valence vanadium clusters of [V34O82]10- bridges [NiL]2+ to form a one-dimensional chain in 1. To the best of our knowledge, the title complex is the first example of organic-inorganic hybrid material involving the largest vanadium cluster of [V34O82]10-. 展开更多
关键词 hydrothermal synthesis macrocyclic nickel(Ⅱ) complexes vanadium cluster
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Synthesis,Crystal Structure and Antitumor Activities of(14S)-2,14-diphenyl-6,6a,11,12-tetrahydro-5H,10H,14H-[1,8]naphthyridino[1,2-c]pyrido[3,2,1-ij]quinazoline-3-carbonitrile 被引量:4
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作者 陈修文 贾国凯 王宗成 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2018年第9期1411-1416,共6页
The title compound(14 S)-2,14-diphenyl-6,6 a,11,12-tetrahydro-5 H,10 H,14 H-[1,8] naphthyridino[1,2-c]pyrido[3,2,1-ij]quinazoline-3-carbonitrile(C31 H26 N4, Mr = 454.56) has been synthesized with 2-aminonicotinald... The title compound(14 S)-2,14-diphenyl-6,6 a,11,12-tetrahydro-5 H,10 H,14 H-[1,8] naphthyridino[1,2-c]pyrido[3,2,1-ij]quinazoline-3-carbonitrile(C31 H26 N4, Mr = 454.56) has been synthesized with 2-aminonicotinaldehyde and 3-oxo-3-phenylpropanenitrile as starting materials, and its crystal structure was determined by single-crystal X-ray diffraction for the first time. The crystal belongs to the triclinic system, space group P1 with a = 8.5833(8), b = 11.9168(12), c = 14.4424(14) ?, α = 84.208(3)o, β = 88.427(3)o, γ = 73.704(3)o, V = 1410.7(2) ?3, Z = 2, F(000) = 480, μ = 0.064 mm–1, S = 0.966, the final R = 0.0484 and wR = 0.1388 for 5041 observed reflections with I 〉 2s(I) and 316 variable parameters. The preliminary biological tests show that the title compound has a good antitumor activity against K562 in vitro. 展开更多
关键词 NAPHTHYRIDINE tetrahydroquinazolines SYNTHESIS crystal structure antitumor activity
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Production of microbial oils co-fermented by Trichoderma.koningii and Trichosporon cutaneum with Daqu distiller's grains 被引量:2
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作者 李新社 陆步诗 唐伟 《Journal of Central South University》 SCIE EI CAS 2011年第5期1738-1743,共6页
Abstract: Daqu distiller's grains were co-fermented as raw materials by Trichoderma.koningii and Trichosporon cutaneum to produce microbial oils, which can provide raw materials for bio-diesel development. The singl... Abstract: Daqu distiller's grains were co-fermented as raw materials by Trichoderma.koningii and Trichosporon cutaneum to produce microbial oils, which can provide raw materials for bio-diesel development. The single factor tests were used to investigate the effects of ratio of strains, inoculum size, culture temperature and culture time on the production of microbial oils. The best processing conditions were obtained by orthogonal test through measuring the content of microbial oils in product. The result shows that the microbial oils content of the co-fermented product under the ratio of Trichoderma.koningii to Trichosporon cutaneum of 1:1, the inoculum size of strains of 11% at 28 ℃ for 6 d is 7.15 g/L. It is shown that the production of microbial oils co-fermented by Trichoderma.koningii and Trichosporon cutaneum with Daqu distiller's grains is possible. The research provides a new idea for the reuse of Daqu distiller's grains and also provides a new way for the development of microbial oils. 展开更多
关键词 Daqu distiller's grains Trichoderma.koningii Trichosporon cutaneum CO-FERMENTATION microbial oils
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Synthesis and Characterization of Two Binuclear Macrocyclic Zinc(Ⅱ) Complexes by Anion Exchange 被引量:2
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作者 欧光川 黄中文 +2 位作者 潘泽毅 周东来 袁先友 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2014年第6期903-908,共6页
Two macrocyclic zinc(Ⅱ) complexes {[ZnL(VO3)2]·0.33H2O}n(1) and [ZnL(H2O)2][Ni(CN)4](2)(L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) have been obtained from the reactions of [Z... Two macrocyclic zinc(Ⅱ) complexes {[ZnL(VO3)2]·0.33H2O}n(1) and [ZnL(H2O)2][Ni(CN)4](2)(L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) have been obtained from the reactions of [ZnL](ClO4)2 with NH4VO3 and K2[Ni(CN)4], respectively, and structurally characterized by elemental analysis, IR, XRPD, TG and X-ray diffraction. Single-crystal X-ray diffraction analyses indicated that the Zn(Ⅱ) atom lies on an inversion center and is octahedrally coordinated by four nitrogen atoms of the tetradentate macrocyclic ligand in the equatorial plane and two oxygen atoms of [VO4] tetrahedra in the axial positions in 1, and two oxygen atoms of two water molecules in 2. Complex 1 shows a three-dimensional structure, which is constructed by the links of [VO3]nn- chains with [ZnL]2+, forming one-dimensional channels occupied by guest water molecules. The monomers of [ZnL(H2O)2]2+ and [Ni(CN)4]2- are connected through the intermolecular hydrogen bonds to form a two-dimensional sheet in complex 2. 展开更多
关键词 macrocyclic zinc(Ⅱ) complexes BINUCLEAR VANADIUM anion exchange
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Silica-alumina molar ratio and some factors effect on the synthesis of zeolites from fly ash 被引量:2
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作者 SUN Yue-zhi FU Ke-ming +1 位作者 ZHU Hong ZHU Tian-lin 《Journal of Coal Science & Engineering(China)》 2009年第4期430-433,共4页
In order to improve the activity and eliminate some impurities, pretreatment was used before hydrothermal synthesis. The fly ash was mixed with an aqueous NaOH solution, the alkali melted fly ash was also adopted, whi... In order to improve the activity and eliminate some impurities, pretreatment was used before hydrothermal synthesis. The fly ash was mixed with an aqueous NaOH solution, the alkali melted fly ash was also adopted, which is hydrothermally treated at about 104 ℃, and the liquid/solid ratio was controlled at 6:1. In order to control Si/Al molar ratio, SiO2 or Al2O3 powers were added to the fly ash. The results of XRD and SEM show that the alkali melted can activate fly ash and eliminate its quartz and mullite, along with the improvement of Si/Al molar ratio and alkalinity. In addition, zeolite Na-A changes into sodalite gradually, and nepheline is the synthesized intermediate product. Those results were discussed on the basis of a formation mechanism of zeolite from fly ash. 展开更多
关键词 fly ash ZEOLITE hydrothermal treatment Si/Al molar ratio
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Response of meiofaunal and nematode communities to sewage pollution abatement:a field transplantation experiment 被引量:1
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作者 刘晓收 张肇坚 单锦城 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2011年第6期1174-1185,共12页
To assess the recovery rate of meiofaunal and nematode communities upon abatement of sewage pollution, a field transplantation experiment was conducted in Tat Tam, which is a non-polluted, shallow subtidal habitat on ... To assess the recovery rate of meiofaunal and nematode communities upon abatement of sewage pollution, a field transplantation experiment was conducted in Tat Tam, which is a non-polluted, shallow subtidal habitat on the southern portion of Hong Kong Island. The sediments used were from one site located in Victoria Harbour that was heavily influenced by sewage pollution, and one site in the outside-harbor area, which was relatively clean. In addition, sediments from Tat Tam were used as a control. Fresh sediments with meiofauna were collected from the aforementioned sites, placed in plastic trays and transplanted to Tat Tam. Sediments were retrieved at the beginning of the experiment and at 1-, 3-, and 8-weeks after transplantation for analysis of the meiofaunal and nematode communities as well as the sediment characteristics. The results showed that the meiofaunal and nematode communities in the control sediments were consistent at the four sampling periods, while it took three and eight weeks, respectively, for the nematode communities from the outside-harbor and inside-harbor sites to become similar to the control. These findings indicated that the relatively poor habitat quality and the nematode community composition in the sewage polluted inside-harbor sediments required a longer time for recovery than samples from the better habitat quality and the nematode community composition in the outside-harbor sediments. 展开更多
关键词 MEIOFAUNA NEMATODE recovery SEDIMENT sewage pollution
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Synthesis and Photoluminescence of Ln^(3+) Doped TiO_2 Nanocrystal 被引量:1
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作者 潘再法 段昌奎 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第S1期268-272,共5页
Eu3+ doped TiO2 nanocrystals were prepared by the hydrothermal method and characterized by XRD, ESEM, IR, UV absorption and emission spectra. XRD and ESEM micrograph revealed that the samples are in pure rutile phase.... Eu3+ doped TiO2 nanocrystals were prepared by the hydrothermal method and characterized by XRD, ESEM, IR, UV absorption and emission spectra. XRD and ESEM micrograph revealed that the samples are in pure rutile phase. Emission spectra under 355 nm radiative were measured to characterize the spectroscopic properties, which showed that the samples probably contain trace Tb3+ ions. The energy transfer mechanism from rutile TiO2 to the 4f shell of Tb3+ and Eu3+ was discussed in connection with the excitation and emission properties of the samples. 展开更多
关键词 hydrothermal method TiO_2 nanocrystal PHOTOLUMINESCENCE energy transfer rare earths
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Effects of used lubricating oil on two mangroves Aegiceras corniculatum and Avicennia marina 被引量:1
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作者 YE Yong TAM N FY 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第11期1355-1360,共6页
An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more... An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m^2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more sensitive to used lubricating oil than A. corniculatum and canopy-oiling resulted in more direct physical damage and stronger lethal effects than base-oiling. When treated with canopy-oiling, half of A. corniculatum plants survived for the whole treatment time (90 d); but, for A. marina, high mortality (83%) resulted from canopy-oiling within 3 weeks and no plants survived for 80 d. Base-oiling had no lethal effects on A. corniculatum plants even at the termination of this experiment, but 83% of A. marina plants died 80 d after treatment. Forty days after canopyoiling, 93% ofA. corniculatum leaves fell and no live leaves remained on A. marina plants. By the end of the experiment, base-oiling treatment resulted in about 45% ofA. corniculatum leaves falling, while all A. mar/na leaves and buds were burned to die. Lubricating oil resulted in physiological damage to A. corniculatum leaves, including decreases in chlorophyll and carotenoid contents, nitrate reductase, peroxidase and superoxide dismutase activities, and increases in malonaldehyde contents. For both species, oil pollution significantly reduced leaf, root, and total biomass, but did not significantly affect stem biomass. Oil pollution resulted in damage to the xylem vessels of fine roots but not to those of mediate roots. 展开更多
关键词 used lubricating oil MANGROVE Aegiceras corniculatum Avicennia marina
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Does a shift in shade tolerance as suggested by seedling morphology explain differences in regeneration success of northern red oak in native and introduced ranges? 被引量:1
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作者 Peter Nosko Kerri Moreau +2 位作者 Christian Kuehne Kelly C.Major Jürgen Bauhus 《Journal of Forestry Research》 SCIE CAS CSCD 2022年第3期949-962,共14页
Across North America, forests dominated by Quercus rubra L. (northern red oak), a moderately shade-tolerant tree species, are undergoing successional replacement by shade-tolerant competitors. Under closed canopies, Q... Across North America, forests dominated by Quercus rubra L. (northern red oak), a moderately shade-tolerant tree species, are undergoing successional replacement by shade-tolerant competitors. Under closed canopies, Q. rubra seedlings are unable to compete with these shade-tolerant species and do not recruit to upper forest strata. In Europe, natural regeneration of introduced Q. rubra is often successful despite the absence of fire, which promotes regeneration in the native range. Considering that understorey light availability is a major factor affecting recruitment of seedlings, we hypothesized that Q. rubra seedlings are more shade tolerant in the introduced range than in the native range. Morphological traits and biomass allocation patterns of seedlings indicative of shade tolerance were compared for Q. rubra and three co-occurring native species in two closed-canopy forests in the native range (Ontario, Canada) and introduced range (Baden-Württemburg, Germany). In the native range, Q. rubra allocated a greater proportion of biomass to roots, while in the introduced range, growth and allocation patterns favored the development of leaves. Q. rubra seedlings had greater annual increases in height, diameter and biomass in the introduced range. Q. rubra seedlings in the introduced range were also younger;however, they had a mean area per leaf and a total leaf area per seedling that were five times greater than seedlings in the native range. Such differences in morphological traits and allocation patterns support the hypothesis that Q. rubra expresses greater shade tolerance in the introduced range, and that natural regeneration of Q. rubra is not as limited by shade as in the native range. The ability of Q. rubra seedlings to grow faster under closed canopies in Europe may explain the discrepancy in regeneration success of this species in native and introduced ranges. Future research should confirm findings of this study over a greater geographical range in native and introduced ecosystems, and examine the genetic and environmental bases of observed differences in plant traits. 展开更多
关键词 Alien species Cross-continental study Forest regeneration Introduced species Seedling morphology Plant functional traits Quercus rubra
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Synthesis, Crystal Structure and Antitumor Activities of 1,2,3,4-Tetrahydroquinoline-2,4-diyl(bisdiphenylphosphine oxide) Derivatives 被引量:1
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作者 LI Yi-Biao YANG Zhi-Hai +2 位作者 WANG Zong-Cheng ZHU Zhong-Zhi CHEN Xiu-Wen 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2019年第5期713-718,668,共7页
A novel and efficient Ir-catalyzed 1,4-and 1,2-addition of diphenylphosphine oxide to quinolines was developed to obtain various 1,2,3,4-tetrahydroquinoline-2,4-diyl(bisdiphenylphosphine oxide) derivatives. The stru... A novel and efficient Ir-catalyzed 1,4-and 1,2-addition of diphenylphosphine oxide to quinolines was developed to obtain various 1,2,3,4-tetrahydroquinoline-2,4-diyl(bisdiphenylphosphine oxide) derivatives. The structures of these derivatives were characterized by H-RMS and NMR analysis. X-ray crystallography showed that 3 a is in a monoclinic system, space group of P21/c with a = 13.0464(16), b = 12.6244(16), c = 20.210(3) ?, β = 105.215(2)o, V =3211.9(7) ?3, Z = 4, F(000) = 1352, μ = 0.42 mm–1, S = 1.07, the final R = 0.059 and wR = 0.195.The in vitro antitumor activities of target compounds were evaluated by MTT assay against human cancer K562, HL-60, HeLa and BGC-823. The target compounds demonstrated weak or moderate antitumor activity against these cell lines. 展开更多
关键词 1 2 3 4-tetrahydroquinoline-2 4-diyl(bisdiphenylphosphine oxide) DERIVATIVES SYNTHESIS crystal structure antitumor activity
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Syntheses and Structures of Three Hybrid Materials Using Vanadium Polyoxoanions and Macrocyclic Copper Complex as Building Blocks 被引量:4
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作者 欧光川 廖阳 +2 位作者 向岳峰 袁先友 李治章 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第1期135-142,共8页
The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO... The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO3]2·2.33H2O(1), [CuL]3[V(10)O(28)]·8H2O(2) and [Cu L]3[V6O(18)]·8H2O(3). Single-crystal X-ray diffraction analyses reveal that three diverse vanadium polyoxoanions, [V6O(18)]6- ring, [V(10)O(28)]6- cluster, and [V(12)O(35)]^10- ring, were isolated from the same reactant NH4VO3 under different conditions. The [CuL]^2+ bridges the [V10O28]6- clusters to form a two-dimensional sheet in 2, and link the [V6O(18)]^6- rings in 1 and [V(12)O(35)]^10- rings in 3 into three-dimensional frameworks, respectively. 展开更多
关键词 polyoxovanadate macrocyclic copper(Ⅱ) complexes hybrid materials
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Plant communities and reproductive phenology in mountainous regions of northern Libya 被引量:1
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作者 Ahmad K. Hegazy Hanan F. Kabiel +2 位作者 Saud L. Al-Rowaily Lesley Lovett-Doust Abd El-Nasser S. Al Borki 《Journal of Forestry Research》 SCIE CAS CSCD 2017年第4期741-761,共21页
Within the semi-desert landscape of northern Libya, two sub-humid escarpments occur: Al-Akhdar in the east and Nafusa (Jabal Al-Gharbi) in the west. This study compares plant communities in the two regions, which are ... Within the semi-desert landscape of northern Libya, two sub-humid escarpments occur: Al-Akhdar in the east and Nafusa (Jabal Al-Gharbi) in the west. This study compares plant communities in the two regions, which are along an elevation gradient, in terms of species composition and diversity, frequency of different Raunkiaer life forms, and reproductive phenology. The two regions differed in species composition and life-form frequency between regions and between elevation zones within each region. Patterns were associated with the lower rainfall and lower moisture-holding capacity of soils at Nafusa, resulting in more xeric conditions. Only 13% of species were shared between the two regional landscapes. Species diversity, life-form frequency, and duration of the flowering-fruiting phenophase were all affected by elevation above sea level. The duration of flowering and fruiting in spring and fall was associated with environmental conditions, although there were different thresholds in the two regions. There was both a spring and fall episode of flowering at Nafusa, but only spring flowering at Al-Akhdar. It is anticipated that there will be a gradual shift of plant communities to higher elevations and loss of certain sensitive species in response to ongoing climate change. 展开更多
关键词 Altitudinal gradient Raunkiaer life forms Reproductive phenology Southern Mediterranean
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Synthesis,Crystal Structure and Anti-fungal Activity of 2-(4-Chlorophenyl)-(1,3-dimethyl-2,3-dihydro-1H)-perimidine 被引量:4
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作者 袁霖 李中燕 +1 位作者 张敏 袁先友 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第8期1181-1185,共5页
The title compound 2-(4-chlorophenyl)-1,3-dimethyl-2,3-dihydro-1H-perimidine(C(19)H(17)ClN2) was synthesized and characterized by elemental analysis, ^1H NMR, HRMS and single-crystal X-ray diffraction. The cry... The title compound 2-(4-chlorophenyl)-1,3-dimethyl-2,3-dihydro-1H-perimidine(C(19)H(17)ClN2) was synthesized and characterized by elemental analysis, ^1H NMR, HRMS and single-crystal X-ray diffraction. The crystal of the title compound belongs to orthorhombic system,space group Pnma with a = 11.385(2), b = 12.170(2), c = 11.210(2)A, V = 1553.2(5)A^3, Z = 4, Dc =1.321 g/cm^3, m(Mo-Ka) = 0.244 mm^-1, F(000) = 648, S = 1.309, R = 0.0400 and w R(I 〉 2s(I)) =0.1065. X-ray diffraction results showed that the molecular structure is highly symmetric and the new-formed N-heterocyclic ring is non-planar. In addition, the biological experiment showed that the title compound showed inhibitory activities against fungi with varied potencies. 展开更多
关键词 perimidine synthesis crystal structure biological activity
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