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STUDY ON THE SYNTHESIS, STRUCTURE AND PROPERTIES OF A NOVEL TYPE Mo-Fe-S CLUSTER COMPOUND
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作者 张致贵 樊玉国 +2 位作者 李宇 牛淑云 李淑芹 《Chinese Science Bulletin》 SCIE EI CAS 1987年第20期1405-1409,共5页
Ⅰ. INTRODUCTION The structure of the active center in nitrogenase and the synthesis of a model compound are interesting subjects for many chemists. It is considered that the structure of the active center in nitrogen... Ⅰ. INTRODUCTION The structure of the active center in nitrogenase and the synthesis of a model compound are interesting subjects for many chemists. It is considered that the structure of the active center in nitrogenase can be a structure of Mo—Fe—S cluster compound. And two distinct models were proposed for the active center structure of nitrogenase. After that, the Mo—Fe—S cluster complexes with the active sites of the model nitrogenase have 展开更多
关键词 complexes BRIDGING YIELDING deviation BONDS BANDS empirical visible LISTED worked
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STUDY ON THE SYNTHESIS, STRUCTURE AND CATALYTIC PROPERTIES OF A Mo-Fe-S CLUSTER COMPOUND,{(C_2H_5)_4N}_3· {[( SCH_2CH_2S ) MoS_3 ]_2Fe}
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作者 张致贵 王凤山 樊玉国 《Chinese Science Bulletin》 SCIE EI CAS 1984年第11期1486-1489,共4页
In the past few years, as the research on nitrogenase has been making new progress continuously,most biologists have believed that the FeMo-co isolated from MoFe-pr is the active center of nitrogenase.Analyses of the ... In the past few years, as the research on nitrogenase has been making new progress continuously,most biologists have believed that the FeMo-co isolated from MoFe-pr is the active center of nitrogenase.Analyses of the extended X-ray absorption fine structure affirmed the micro-environment around the Mo 展开更多
关键词 ETHANE ACETYLENE continuously BRIDGING C2H5 MoS3 SCH2CH2S BORATE BONDS dithio
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ELECTRONIC STRUCTURES OF THE O-CONTAINING Fe-Mo-S CLUSTERS ANALOGOUS TO THE NITROGENASE Fe-Mo-COFACTOR
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作者 郭纯孝 王志中 唐敖庆 《Chinese Science Bulletin》 SCIE EI CAS 1984年第9期1196-1199,共4页
Ⅰ. INTRODUCTION With the development of studies on biological nitrogen fixation, the investigation on the micro-circumstances of active centers in metalloenzyme has reached the
关键词 circumstances FIXATION CENTERS bridging bonding BONDS readily analogous orbit valent
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