A novel metal-organic coordination polymer {[Co2（4-sphth）2（4,4＇-bpyh（H2O）4]- [Co（4,4＇-bpy）2（H2O）4]}, （4-sphth = 4-sulfophthalic acid, 4,4＇-bpy = 4,4＇-bipyridine） 1 has been hydrothermally synthesized an...A novel metal-organic coordination polymer {[Co2（4-sphth）2（4,4＇-bpyh（H2O）4]- [Co（4,4＇-bpy）2（H2O）4]}, （4-sphth = 4-sulfophthalic acid, 4,4＇-bpy = 4,4＇-bipyridine） 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and magnetic susceptibility measurements. The complex crystallizes in monoclinic, space group C2/c with a = 18.893（6）, b = 23.080（7）, c = 22.473（7） A, fl = 107.311 （4）°, V = 9356（5） A^3, C76H70Co3N12O22S2, Mr = 1744.35, De = 1.238 g/cm^3,μ（MoKα） = 0.640 mm^-1, F（000） = 3596, Z = 4, the final R = 0.0444 and wR = 0.0846 for 9178 observed reflections （I 〉 2σ（I））. It exhibits a novel three-dimensional supramolecular network formed by hydrogen-bonding and π-π interactions. Variable-temperature magnetic measure shows an overall anti-ferromagnetic behavior for compound 1.展开更多
基金The project was supported by the Education Office of Jilin Province (No. 0047)
文摘A novel metal-organic coordination polymer {[Co2（4-sphth）2（4,4＇-bpyh（H2O）4]- [Co（4,4＇-bpy）2（H2O）4]}, （4-sphth = 4-sulfophthalic acid, 4,4＇-bpy = 4,4＇-bipyridine） 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and magnetic susceptibility measurements. The complex crystallizes in monoclinic, space group C2/c with a = 18.893（6）, b = 23.080（7）, c = 22.473（7） A, fl = 107.311 （4）°, V = 9356（5） A^3, C76H70Co3N12O22S2, Mr = 1744.35, De = 1.238 g/cm^3,μ（MoKα） = 0.640 mm^-1, F（000） = 3596, Z = 4, the final R = 0.0444 and wR = 0.0846 for 9178 observed reflections （I 〉 2σ（I））. It exhibits a novel three-dimensional supramolecular network formed by hydrogen-bonding and π-π interactions. Variable-temperature magnetic measure shows an overall anti-ferromagnetic behavior for compound 1.
