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Imidazol-1-yl-acetic acid as a novel green bifunctional organocatalyst for the synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions
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作者 Simin Nazari Mosadegh Keshavarz +2 位作者 Bahador Karami Nasir Iravani Masoumeh Vafaee-Nezhad 《Chinese Chemical Letters》 SCIE CAS CSCD 2014年第2期317-320,共4页
Imidazol-1-yl-acetic acid is introduced as a new, efficient and recyclable green bifunctional organocatalyst for the synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions. This catalyst is water solub... Imidazol-1-yl-acetic acid is introduced as a new, efficient and recyclable green bifunctional organocatalyst for the synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions. This catalyst is water soluble and can be separated from the products by simple filtration. The filtrate can be evaporated to dryness and recrystallized from cool methanol to give the recovered catalyst. This organocatalyst was used for the synthesis of 1,8-dioxooctahydroxanthenes under solvent-flee conditions and recycled up to 8 consecutive runs without any losing of its efficiency. 展开更多
关键词 Bifunctional catalyst ORGANOCATALYST SOLVENT-FREE 1 3-Dicarbonyl compounds 1 8-Dioxooctahydroxanthenes
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