Unraveling the coordination behavior and transformation mechanism of Cr^(3+) in Fe–Cr redox flow battery electrolytes

Currently,the iron chromium redox flow battery(ICRFB)has become a research hotspot in the energy storage field owing to its low cost and easily-scaled-up.However,the activity of electrolyte is still ambiguous due to its complicated solution environment.Herein,we performed a pioneering investigation on the coordination behavior and transformation mechanism of Cr^(3+)in electrolyte and prediction of impurity ions impact through quantum chemistry computations.Based on the structure and symmetry of electrostatic potential distribution,the activity of different Cr^(3+)complex ions is confirmed as[Cr(H2O)5Cl]^(2+)>[Cr(H2O)4Cl2]+>[Cr(H2O)6]^(3+).The transformation mechanism between[Cr(H2O)6]^(3+)and[Cr(H2O)5Cl]^(2+)is revealed.We find the metal impurity ions(especially Mg^(2+))can exacerbate the electrolyte deactivation by reducing the transformation energy barrier from[Cr(H2O)5Cl]^(2+)(24.38 kcal mol^(−1))to[Cr(H2O)6]^(3+)(16.23 kcal mol^(−1)).The solvent radial distribution and mean square displacement in different solvent environments are discussed and we conclude that the coordination configuration limits the diffusivity of Cr^(3+).This work provides new insights into the activity of electrolyte,laying a fundamental sense for the electrolyte in ICRFB.

Research on the Flow and Heat Transfer Characteristics of a Water-Cooling Plate in a Heat Dissipation System

The water-cooling heat dissipation technology can solve the heat dissipation and noise problems of the calculation plate.Therefore,the structural design of the water-cooling plate directly affects its flow and heat transfer characteristics,which restricts the promotion and application of the technology.To this end,the water-cooling plate of a heat dissipation system was taken as the research object,and its flow and heat transfer characteristics were numerical simulated and experimental studied.Through comparative analysis,the rationality of the numerical simulation method was verified.Based on this,three improved schemes of water-cooling plate structure were proposed and numerical simulation was carried out,and the optimal model was verified by experiments.The results of the study show that compared with the original water-cooling plate,the optimized water-cooling plate has increased internal flow velocity and distributes uniformly,increased heat transfer amount by 4.2%,and the average temperature of the calculation plate decreased by 5.3%.

Numerical Simulation of Contamination Accumulation Characteristics of Composite Insulators in Salt Fog Environment

To investigate the fouling characteristics of the composite insulator surface under the salt fog environment,the FXBW-110/120-2 composite insulator was taken as the research object.Based on the field-induced charge mechanism,the multi-physical field coupling software COMSOL was used to numerically simulate the fouling characteristics,explored the calculation method of ESDD,and demonstrated its rationality.Based on this method,the pollution characteristics of the composite insulator under the pollution fog environment were studied,and the influence of wind speed,droplet size,and voltage type on the pollution characteristics of the composite insulator was analyzed.The results showed that:with the increase in wind speed,the amount of accumulated pollution of insulator increases in the range of droplet size,and the relationship between wind speed and accumulated pollution is approximately linear;at the same wind speed,the amount of accumulated pollution increases with the increase of droplet size under the action of DC voltage;when there is no voltage,the amount of dirt on the upper surface of the insulator is more than that on the lower surface,while it is the opposite under DC voltage.

Influence of Electrical Field Distortions Induced by Water Droplets on the Contamination Characteristics of an Insulator

When separated water droplets condense on the surface of a composite insulator,the electrical field on the insulator surface is distorted.In turn,such distortions change the trajectories of pollution particles.In this study,the COMSOL software is used to simulate such a process for the FXBW4-10/100 composite insulator with or without water droplets condensation under a 10 kV DC voltage.The influence of the wind speed and particles concentration on the contamination characteristics of the considered 110 kV insulator is analyzed.The results show that:1)in the presence of water droplets on the insulator surface,the ratio of electrical field force and gravity acting on the particles is large;2)the contamination on the insulator surface increases with the wind speed;3)when the wind speed is small,the relationship between the contamination amount and the pollution concentration is essentially linear.

Simulation of Electric Field Distribution along Insulator Surface in Polluted Environments

In recent years,more than 50%of the cities in the inland area of our country have suffered from moderate pollution.It can affect the distribution of electric field along the surface of insulator and the pollution characteristics of its surface area,even endanger the safe operation of transmission lines.This paper takes the XSP-160 porcelain three umbrella insulator under the action of 0–±30 kV DC voltage as the research object,and establishes the physical model of the insulator;uses COMSOL software to simulate the electric field of the insulator.The comparison with the results of the wind tunnel test of North China Electric Power University verifies the rationality of the simulation method.In view of the medium pollution environment which often occurs in the inland area,the force of the polluted particles deposited on the insulator under 110 kV DC voltage was analyzed.The distribution characteristics of the electric field along the surface in the clean and three kinds of pollution environment(light,medium and heavy)were simulated and compared.The results showed that:1)In the moderate pollution environment,the influence of fluid drag force on the movement of polluted particles is greater at the initial stage(0.28–0.33 s);at the late stage(after 0.33 s),the influence of the electric field force begins to increase,and gradually plays a major role in the process of fouling.2)In the three different polluted environments,the potential along the surface of each umbrella skirt of the insulator increases non-linearly with the increasing of the pollution concentration,and there are apparent potential inflection points near b and l.3)The pollution particle concentration has the most obvious influence on the electric field along the low-voltage umbrella skirt,whose potential distortion rate can be up to 220 times in the heavy polluted environment.

Preface: Wind turbines: aeromechanics and farm optimization

1 Preface With the oil and gas supply security and climate change emerging as high concerns,the need for renewable energy sources to alleviate dependence on hydrocarbons and reduce carbon dioxide(CO2)emissions is becoming increasingly urgent.Wind energy is one of the cleanest renewable power sources in the world today.The U.S.Department of Energy(DOE)initiated the Wind Vision study where the costs and benefits of continued investments on wind energy was quantified.The study evaluated an ambitious,yet credible scenario in which wind energy will serve 20%of the nation’s total electric power demand by 2030,and 35%by 2050.In Europe,the wind power generation accounted for 15%of all European electricity demand in the past year.Wind power installation in China has been growing by an annual rate of^10%in recent years.Currently,wind power has become the second largest renewable energy in China,only after hydro-power.