Facile synthesis of chromium chloride/poly(methyl methacrylate) core/shell nanocapsules by inverse miniemulsion evaporation method and application as delayed crosslinker in secondary oil recovery

Cr(III)ehydrolyzed polyacrylamide(HPAM)gels have been extensively studied as a promising strategy controlling waste water production for mature oilfields.However,the gelation time of the current technologies is not long enough for in-depth placement.In this study,we report a novel synthesis method to obtain chromium chloride/poly(methyl methacrylate)(PMMA)nanocapsules which can significantly delay the gelation of HPAM through encapsulating the chromium chloride crosslinker.The chromium chloride-loaded nanocapsules(CreNC)are prepared via a facile inverse miniemulsion evaporation method during which the hydrophobic PMMA polymers,pre-dispersed in an organic solvent,were carefully controlled to precipitate onto stable aqueous miniemulsion droplets.The stable aqueous nanodroplets(W)containing Cr(III)are dispersed in a mixture of organic solvent(O1)with PMMA and nonsolvent medium(O2)to prepare an inverse miniemulsion.With the evaporation of the O1,PMMA forms CreNCs around the aqueous droplets.The CreNCs are readily transferred into water from the organic nonsolvent phase.The CreNCs exhibit the tunable size(358-983 nm),Cr loading(7.1%-19.1%),and Cr entrapment efficiency(11.7%-80.2%),with tunable zeta potentials in different PVA solutions.The CreNCs can delay release of Cr(III)and prolong the gelation time of HPAM up to 27 days.

Generalized Extreme Value-Pareto Distribution Function and Its Applications in Ocean Engineering

In this paper, we establish a generalized extreme Value-Pareto distribution model and derive an analytical expression of Weibull–Pareto distribution model. Based on a data sample of 26-year wave height, we adopt the new model to estimate the design wave height for 500, 700 and 1000-year return periods. Results show that the design wave height from Weibull–Pareto distribution is between that of the Weibull distribution and that of the Pearson-Ⅲ distribution.For the 500-year return period design wave height, the results from the new model is 1.601% lower than those from the Weibull distribution and 1.319% higher than those from the Pearson-Ⅲ distribution. The Weibull–Pareto distribution innovatively considers the fractal features, extreme-value statistics and the truncated data in the derivation process. Therefore, it is a more holistic and practical model for estimating the design parameters in marine and coastal environments.