Fischer-Tropsch synthesis under supercritical phase condition was examined in a continuous and a high-pressure fixed bed reactor by employing a cobalt catalyst （Co-Ru/γ-Al2O3）. An integral reactor model involving F...Fischer-Tropsch synthesis under supercritical phase condition was examined in a continuous and a high-pressure fixed bed reactor by employing a cobalt catalyst （Co-Ru/γ-Al2O3）. An integral reactor model involving Fischer-Tropsch reaction kinetics in the supercritical fluid n-hexane was used to describe the overall performance. On the basis of Langmuir-Hinshelwood-Hougen-Watson （LHHW） model, the reaction rate constants were obtained for the rate equations of CO conversion to CH4 formation under supercritical conditions.展开更多
文摘Fischer-Tropsch synthesis under supercritical phase condition was examined in a continuous and a high-pressure fixed bed reactor by employing a cobalt catalyst （Co-Ru/γ-Al2O3）. An integral reactor model involving Fischer-Tropsch reaction kinetics in the supercritical fluid n-hexane was used to describe the overall performance. On the basis of Langmuir-Hinshelwood-Hougen-Watson （LHHW） model, the reaction rate constants were obtained for the rate equations of CO conversion to CH4 formation under supercritical conditions.
