Geochemistry of island arc assemblage in the Eastern Desert of Egypt and the role of Pan-African magmatism in crustal growth of the Arabian–Nubian Shield:A review

Neoproterozoic island arc assemblage of the Arabian–Nubian Shield(ANS)in the Eastern Desert(ED)of Egypt comprises juvenile suites of metavolcanics(MV),large amounts of meta-sedimentary rocks(MS),and voluminous metagabbros-diorites(MGD)and syn-tectonic intrusions of older granitoids(OG).We report here the updates of these four rock units in terms of classification,distribution,chemical characteristics,geodynamic evolution,metamorphism,and ages.In addition,we discuss these integrated data to elucidate a reasonable and reliable model for crustal evolution in the ANS.The main features of these rock units indicate their relation to each other and the geodynamic environment dominated by early immature oceanic island arcs to primitive continental arcs.Integrated information of the island arc metavolcanic and plutonic rocks(gabbros,diorites,tonalites,and granodiorites)furnish evidence of the genetic relationships.These include proximity and a coeval nature in the field;all protolith magmas are subalkaline in nature following calc-alkaline series with minor tholeiitic affinities;common geochemical signature of the arc rocks and subduction-related magmatism;their similar enrichment in LREEs;and similar major element compositions with mafic melts derived from metasomatized mantle wedge.The volcano-sedimentary and the OG rocks underwent multiphase deformation events whereas the MGD complexes deformed slightly.Based on the magmatic,sedimentological,and metamorphic evolutions constrained by geochronological data as well as the progressive evolutionary trend from extensional to compressional regimes,a possible gradual decrease in the subducted slab dip angle is the most infl uential in any geodynamic model for arc assemblage in the ED of Egypt.

Assessing the Performance of a Dynamical Downscaling Simulation Driven by a Bias-Corrected CMIP6 Dataset for Asian Climate

In this study,we aim to assess dynamical downscaling simulations by utilizing a novel bias-corrected global climate model(GCM)data to drive a regional climate model(RCM)over the Asia-western North Pacific region.Three simulations were conducted with a 25-km grid spacing for the period 1980–2014.The first simulation(WRF_ERA5)was driven by the European Centre for Medium-Range Weather Forecasts Reanalysis 5(ERA5)dataset and served as the validation dataset.The original GCM dataset(MPI-ESM1-2-HR model)was used to drive the second simulation(WRF_GCM),while the third simulation(WRF_GCMbc)was driven by the bias-corrected GCM dataset.The bias-corrected GCM data has an ERA5-based mean and interannual variance and long-term trends derived from the ensemble mean of 18 CMIP6 models.Results demonstrate that the WRF_GCMbc significantly reduced the root-mean-square errors(RMSEs)of the climatological mean of downscaled variables,including temperature,precipitation,snow,wind,relative humidity,and planetary boundary layer height by 50%–90%compared to the WRF_GCM.Similarly,the RMSEs of interannual-tointerdecadal variances of downscaled variables were reduced by 30%–60%.Furthermore,the WRF_GCMbc better captured the annual cycle of the monsoon circulation and intraseasonal and day-to-day variabilities.The leading empirical orthogonal function(EOF)shows a monopole precipitation mode in the WRF_GCM.In contrast,the WRF_GCMbc successfully reproduced the observed tri-pole mode of summer precipitation over eastern China.This improvement could be attributed to a better-simulated location of the western North Pacific subtropical high in the WRF_GCMbc after GCM bias correction.

The impact of geological uncertainty on primary production from a fluvial reservoir

Deposition of fluvial sandbodies is controlled mainly by characteristics of the system, such as the rate of avulsion and aggradation of the fluvial channels and their geometry. The impact and the interaction of these parameters have not received adequate attention. In this paper, the impact of geological uncertainty resulting from the interpretation of the fluvial geometry, maximum depth of channels, and their avulsion rates on primary production is studied for fluvial reservoirs. Several meandering reservoirs were generated using a process-mimicking package by varying several con- trolling factors. Simulation results indicate that geometrical parameters of the fluvial channels impact cumulative pro- duction during primary production more significantly than their avulsion rate. The most significant factor appears to be the maximum depth of fluvial channels. The overall net-to-gross ratio is closely correlated with the cumulative oil production of the field, but cumulative production values for individual wells do not appear to be correlated with the local net-to-gross ratio calculated in the vicinity of each well. Connectedness of the sandbodies to each well, defined based on the minimum time-of-flight from each block to the well, appears to be a more reliable indicator of well-scale production.

"Miles wide and miles deep"-Exploring the depth and breadth of geoscience during the first ten years of Geoscience Frontiers

When early explorers first crossed the Platte River in what is now Nebraska (USA), it was said the river was “a mile wide and an inch deep”(Mokler, 1923;Smith, 1971). This phrase was used to describe not only the difficulty in crossing the river but also in navigating its length. The trouble with a river being too wide is the risk that it won’t provide the depth necessary to be useful. The same thing can be said of multidisciplinary scientific journals. While a journal can claim to be multidisciplinary, there is a risk of it being so broad that its articles can only engage the reader at a superficial level. Nothing could be further from the truth with Geoscience Frontiers. Over the past ten years, this journal has successfully navigated the wide breadth of geoscience while providing a level of depth and detail that rivals discipline-specific journals.

Reconstruction of the Yangtze Ramp during Floian to Darriwilian(Ordovician)in South China:Its Morphology,Controlling Factors and Significances

A robust stratigraphic framework and a coherent depositional ramp model for the Zitai,Dawan,Meitan and Ningkuo formations of Floian–Darriwilian age(Early–Middle Ordovician)in the Yangtze(Daoba,Xiangshuidong,Daling,Gudongkou and Honghuayuan sections)and Jiangnan regions(Nanba section)was created based on lithofacies and major element analysis.Three siliciclastic(LF1–3)and six carbonate(LF4–9)lithofacies are recognized representing sediments that were deposited in mixed siliciclastic and carbonate ramp environment.The intensity of mixed sedimentation and terrigenous input were evaluated using the elemental proxies Intensity of Mixed sedimentation(IM)and Aluminum Accumulation Rate(Al AR),as well as their mean values during certain time intervals.Mixed sediments are most well-developed along the marginal Yangtze region,strongly impacted by recurrent influx of westerly derived terrigenous materials in response to global eustatic changes and regional tectonic movements,shaping the gently southeast-dipping morphology.Regular terrigenous influx resulted in periods of enhanced primary productivity on the Yangtze Ramp as evidenced by matching biodiversity peaks in planktonic organisms,i.e.,chitinozoans and acritarchs.Brachiopods and other shelly fauna were also able to proliferate as new niches developed along the gently dipping ramp floor with substrate changes.The biodiversification patterns suggest that terrigenous influx controlled in part by regional tectonics played a more important role than previously thought in the development of Great Ordovician Biodiversification Event in South China.

Elucidating Dominant Factors Affecting Land Surface Hydrological Simulations of the Community Land Model over China

In order to compare the impacts of the choice of land surface model(LSM)parameterization schemes,meteorological forcing,and land surface parameters on land surface hydrological simulations,and explore to what extent the quality can be improved,a series of experiments with different LSMs,forcing datasets,and parameter datasets concerning soil texture and land cover were conducted.Six simulations are run for the Chinese mainland on 0.1°×0.1°grids from 1979 to 2008,and the simulated monthly soil moisture(SM),evapotranspiration(ET),and snow depth(SD)are then compared and assessed against observations.The results show that the meteorological forcing is the most important factor governing output.Beyond that,SM seems to be also very sensitive to soil texture information;SD is also very sensitive to snow parameterization scheme in the LSM.The Community Land Model version 4.5(CLM4.5),driven by newly developed observation-based regional meteorological forcing and land surface parameters(referred to as CMFD_CLM4.5_NEW),significantly improved the simulations in most cases over the Chinese mainland and its eight basins.It increased the correlation coefficient values from 0.46 to 0.54 for the SM modeling and from 0.54 to 0.67 for the SD simulations,and it decreased the root-mean-square error(RMSE)from 0.093 to 0.085 for the SM simulation and reduced the normalized RMSE from 1.277 to 0.201 for the SD simulations.This study indicates that the offline LSM simulation using a refined LSM driven by newly developed observation-based regional meteorological forcing and land surface parameters can better model reginal land surface hydrological processes.

New Data on the Upper Miocene Presence in the Aegean Region: The Geological Evolution of Spetses Island, Peloponnesus, Greece

Based on detailed geological and geomorphological mapping, sampling and micro-palaeontological determinations, both of the alpine and neogene formations, new data have been derived for Spetses Island (SW Aegean). The applied methodology provided results on the paleogeographic evolution for Spetses Island and the nearby land of Argolida peninsula as well. Based mainly on characteristic nannofossils, a Miocene age of the post-alpine formations is determined. It is the first time that miocene formations have been identified, not only in Spetses Island and Argolida, but in the whole area of Peloponnesus, where only Plio-pleistocene deposits have been described. This work also leads to the conclusion that Spetses Island is attached to the Argolida peninsula, forming an independent paleogeographic unit since Upper Miocene.

The impact of climate change on groundwater quantity and quality in a semi-arid environment:a case study of Ain Azel plain(Northeast Algeria)

In the last decade,North Africa has witnessed significant population growth,particularly those bordering the Mediterranean Sea.This led to increased demand for groundwater,which is an essential source for various water uses such as drinking water supplies and irrigation.Generally,human activities play a crucial role in the different quantitative and qualitative changes in groundwater.Now,climate changes such as a decrease in precipitation have also led to a shortage of water resources and a decline in the groundwater table.This paper presents the impact of climate changes on groundwater resources in the Ain Azel region,Setif,northeastern Algeria.The analysis of longterm spatiotemporal variability in rainfall over 63 years(1958–2021)revealed a significant decline in groundwater recharge,especially after 2013.In contrast,the Pettitt and Mann–Kendall tests show increased temperatures with breaks between 1984 and 1986.A piezometric analysis of the alluvial aquifer demonstrated a significant decline in groundwater levels in the last 20 years.Hydrochemical analysis showed that groundwater in the region is dominated by Ca–Mg–Cl water type,which indicates the presence of water salinity phenomenon.Water Quality Index(WQI)analysis showed the deterioration of groundwater in the area,which may be caused by several factors:brine intrusion from the Salt Lake(Sebkha)in the north;the dissolution of evaporites(Triassic)and/or anthropogenic sources of agricultural and industrial origin.Our findings provide an overview summarizing the state of groundwater,which will help improve groundwater resource management in the region in the coming years.

Role of extracellular polymeric substances in resistance to allelochemical stress on Microcystis aeruginsosa and its mechanism

Using allelochemicals to suppress cyanobacteria growth is a prospective method for its high efficiency and ecological safety.However,the suppression efficiency is affected inevitably by the extracellular polymeric substances(EPS)produced by cyanobacteria,and the knowledge about the roles of EPS in resistance to allelochemical stress is scarce.For the study,two typical anti-cyanobacterial allelochemicals were adopted to investigate the role of EPS in resistance to allelochemical stress on Microcystis aeruginosa.Results show that EPS was crucial in alleviating the toxicity of allelochemicals to algae,especially in stabilizing the metabolism and photosynthetic activity of algal cells.The aggregation rate of algal cells increased with the increase of EPS secretion,which alleviated the stress of allelopathy.Tryptophan proteins and humic acids in EPS provided a binding site for allelochemicals,and the EPS-allelochemicals complex were formed by chemical bonding.This study improved our comprehension of the role of EPS in algal inhibition by allelochemicals.

Characterization and stability of sedimentary colloids in different ecology regions in Taihu Lake

Colloidal particles,heterogeneous mixture with various organic components and continuous molecular weight(MW)distribution,is omnipresent in lake sediments and substantially influence the retention,transportation,and fate of contaminants in lake ecosystem.We sampled and extracted sedimentary colloids from different ecology regions in Taihu Lake,Jiangsu,East China,in June 2020,and they were further separated into four different particle size ranges by tangent ultrafiltration,and the properties of colloids were studied in various methods,including zeta potential analysis,transmission electron micrograph images(TEM),Fourier transformation infrared(FTIR),and 3D fluorescence.Results show that the surface of the colloids is covered with organic macromolecular substances,such as humuslike substances and protein-like substances.There were significant differences in molecular weight and fraction content of colloids in the sediments from macrophyte-dominant(MD)area and algae-dominant(AD)area in the lake.Colloids from MD area are mainly composed of humic acid,protein,and fulvic acid;the content of fulvic acid is lower than that of humic acid and protein.The humic acid exists mainly in small molecular weight(10-100 kDa),protein exists in mainly large molecular weight colloids(0.45-1μm).Colloids from AD area are mainly composed of humic acid,and mainly distributed in the molecular weight(10 kDa-0.45μm).The presence of humic acid inhibits effectively the agglomeration of the colloids.Especially,the stability of colloids is closely related to the molecular weight,with low molecular weight from MD area show higher stability.The existence of humic acid in colloids increases the electrostatic repulsion between colloidal particles,which can effectively inhibit the agglomeration of colloids,thus enhancing the stability of colloids.Furthermore,both monovalent and divalent electrolytes enhance colloidal aggregation,and the low-molecular-weight(LMW)colloid fraction exhibits higher stability efficiency than the high-molecular-weight(HMW)colloidal.

Climate Variability & Establishment of Rainfall Threshold Line for Landslide Hazards in Rangamati, Bangladesh

This study aims to evaluate the impact of extreme rainfall events on landslides under current and past climate scenarios. Rainfall-triggered landslides are analyzed by rainfall estimates, derived using statistics of events. It is established that recent climate changes, mainly temperature and rainfall patterns have significantly increased the rainfall-induced landslide hazards in the Rangamati district, Bangladesh. It is also observed that the temperature and rainfall of Rangamati had increased gradually during the last 40 years (1981-2021). On 13 June 2017, a series of landslides triggered by heavy monsoon rains (300 mm/24 h) occurred and killed more than 112 people in the Rangamati hill district, Bangladesh. The highest annual decade rainfall is 3816 mm, recorded in 2010-21. A relationship between causalities and the number of events has also been established. The analysis shows that both antecedent and single-day major rainfall patterns can influence sliding events. It is established that monsoonal rainfall (June-September) can significantly influence catastrophic landslide hazard events. Finally, two rainfall threshold lines for the researched area are constructed based on antecedent and single-day major rainfall occurrences, as well as the number of fatalities caused by landslides. Total rainfall of 100 mm (16.66 mm/day) during six days appears to define the minimum rainfall that has led to shallow landslides/slope failures, while 210 mm (35 mm/day) within six days appears to define the lowest rainfall that could be a cause of catastrophic landslide in Rangamati district.

Influence of Seasonal Ground Water Level Fluctuations on the Stability of the Rohingya Refugee Camp Hills of Ukhiya, Teknaf, Cox’s Bazar, Bangladesh—A Threat for Sustainable Development

Bangladesh is a south Asian Monsoonal Country and the recent precipitation pattern in the Cox’s Bazar area of Bangladesh is changing and increasing the number of monsoonal slope failures and landslide hazards in the Kutubpalong & Balukhali Rohingya camp area. An attempt has been made to see the influence of seasonal variation of ground water level (G.W.L.) fluctuations on the stability of the eco hills and forests of Ukhiya Teknaf region. Ukhiya hills are in great danger because of cutting trees from the hill slopes and it is well established that due to recent change of climate, short term rainfall for few consecutive days during monsoon might show an influence on the factor of safety (Fs) values of the camp hill slopes. A clear G.W.L. variation between dry and wet seasons has an influence on the stability (Fs) values indicating that climate has a strong influence on the stability and threatening sustainable development. A stable or marginally stable slope might be unstable during raining and show a variation of ground water level (G.W.L.). The generation of pore water pressure (P.W.P.) is also influenced by seasonal variation of ground water level. During wet season negative P.W.P. called suction plays an important role to occur slope failures in the Ukhiya hills. Based on all calculated factor of safety values (Fs) at different locations, four (4) susceptible landslide risk zones are identified. They are very high risk (Fs = 0.18 to 0.46), high risk (Fs = 0.56 to 0.75), medium risk (Fs = 0.76 to 1.0) and marginally stable areas (Fs ≈ 1). Proper geo-engineering measures must be taken by the concerned authorizes to reduce P.W.P. during monsoon by installing rain water harvesting system, allowing sufficient drainage & other geotechnical measures to reduce the risk of slope failures in the Ukhiya hills. Based on the stability factor (Fs) at different slope locations of the camp hills, a risk map of the investigated area has been produced for the local community for their safety and to build up awareness & to motivate them to evacuate the site during monsoonal slope failures. The established “Risk Maps” can be used for future geological engineering works as well as for sustainable planning, design and construction purposes relating to adaptation and mitigation of landslide risks in the investigated area.

Multistage Triaxial Behavior of Shallow Landslide Hazard Site Soil of Rangamati Sadar Area, Bangladesh

The soil samples were collected from a shallow landslide hazard site of the Rangamati Sadar in Bangladesh to determine the shear strength properties of the soil. Multistage triaxial consolidation undrained test has become worldwide more accepted to determine the shear strength parameters. Multistage triaxial undrained tests were performed on five samples taken from five different depths of boreholes. Samples were evaluated under two natural conditions and three remolded situations. Samples were consolidated before shearing at confining pressures from 50 kPa to 1200 kPa. All the test results are discussed in terms of deviator stress versus axial strain, mean effective stress versus deviator curves, stress ratio versus axial strain, and excess p. w. p. versus axial strain curves. The samples consolidated at low effective stress first displayed peak positive values of excess p. w. p., followed by increased strains due to sample bulging failure, and only a few samples formed a shear surface failure. The strength parameters were estimated using the maximum deviator stress as the failure criterion i.e. the overall value of the cohesion is 20 kPa and the friction angle is 34°. Hence, the critical state line has been constructed and the critical state parameters have been calculated. The critical state stress ratio M was calculated to be 0.036. The shear strength of soil is one of the significant mechanical properties that are thoroughly used to assess the landslide and liquefaction potentiality of the soil.

The Hidden Earthquake Induced Liquefaction Risks in the Rohingya Refugee Camp Hills & Surrounding Areas of Ukhiya, Cox’s Bazar, Bangladesh—A Geotechnical Engineering Approach

Liquefaction is one of the major catastrophic geohazards which usually occurs in saturated or partially saturated sandy or silty soils during a seismic event. Evaluating the potential liquefaction risks of a seismically prone area can significantly reduce the loss of lives and damage to civil infrastructures. This research is mainly focused on the earthquake-induced liquefaction risk assessment based on Liquefaction Potential Index (LPI) values at different earthquake magnitudes (M = 5.0, 7.0 and 8.0) with a peak ground acceleration (amax) of 0.28 g in the Rohingya Refugee camp and surrounding areas of Ukhiya, Cox’s Bazar, Bangladesh. Standard Penetration Test (SPT) results have been evaluated for potential liquefaction assessment. The soils are mainly composed of very loose to loose sands with some silts and clays. Geotechnical properties of these very loose sandy soils are very much consistent with the criteria of liquefiable soil. It is established from the grain size analysis results;the soil of the study area is mainly sand dominated (SP) with some silty clay (SC) which consists of 93.68% to 99.48% sand, 0.06% to 4.71% gravel and 0% to 6.26% silt and clay. Some Clayey Sand (SC) is also present. The silty clay can be characterized as medium (CI) to high plasticity (CH) inorganic clay soil. LPI values have been calculated to identify risk zones and to prepare risk maps of the investigated area. Based on these obtained LPI values, four (4) susceptible liquefaction risk zones are identified as low, medium, high and very high. The established “Risk Maps” can be used for future geological engineering works as well as for sustainable planning, design and construction purposes relating to adaptation and mitigation of seismic hazards in the investigated area.

Kaili Biota: A Taphonomic Window on Diversification of Metazoans from the Basal Middle Cambrian: Guizhou, China

A Burgess Shale-type biota is, in part, characterized by a wide diversity of taxa and soft-part preservation. Each provides unique historical insights into early metazoan evolution. Among the more than 40 globally distributed biotas, the early Cambrian Chengjiang and Middle Cambrian Burgess-type biotas are the largest. The Kaili Biota, from the earliest Middle Cambrian of Guizhou, China, contains representatives of 110 metazoan genera belonging to 10 phyla. It contains many well-persevered soft-bodied specimens. This Chinese biota has become the third most taxonomically diverse Burgess Shale-type fauna. Because the Kaili Biota formed in an outer-shelf environment, its main faunal character is large numbers of eocrinoids and planktoic trilobites. The Kaili is younger than the Chengjiang Biota but older than the Canadian Burgess Shale Biota; it shares 30 genera with the Chengjiang and 38 genera with the Burgess Biota. The Kaili Biota displays a taphonomic window to the diversification and evolution of marine offshore organisms covering 5.13 million years between the Early and Middle Cambrian.

Variation and mechanisms of clastic reservoir quality in the Paleogene Shahejie Formation of the Dongying Sag, Bohai Bay Basin, China

Reservoir quality varies greatly in the Shahejie Formation in the Dongying Sag. It is essential to analyze the variation and mechanisms of reservoir quality for determining the controlling factors based on cores, porosity measurements and fluid inclusion techniques and so on. The sandstones in the fluvial, （fan） delta-front have the best reservoir quality due to the depositional conditions mechanically controlling the petrology configuration and the primary porosity, and chemically influencing the diagenesis and development of secondary pores. The activity of the boundary faults and the sedimentary facies dominate the variation of reservoir quality in different areas and intervals. The reservoir quality varies with the position of sandstone beds in different vertical models of sandstone and mudstone. This mainly arose from the strong cementation or strong dissolution in the sandstone caused by the diagenesis evolution of adjacent mudstone. With higher oil saturation reservoir quality is better because the hydrocarbon charge favors dissolution and restricts cementation. Diagenesis, depositional conditions and tectonic setting are the key controls of reservoir quality in the Shahejie Formation of the Dongying Sag.

Carbon and Oxygen Isotopic Composition of Surface-Sediment Carbonate in Bosten Lake (Xinjiang,China) and its Controlling Factors

Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inlet and the single outlet in the western part of the lake. The analytical results show that the carbon and oxygen isotopic composition of recent lake sediments is related to this specific lacustrine depositional environment and to the resulting carbonate mineralogy. In the southwestern lake region between the Kaidu River inlet and the Kongqi River outlet, carbon isotope composition （δ^13C） values of the carbonate sediment （-1‰ to -2‰） have no relation to the oxygen isotope composition of the carbonate （δ^18O） values （-7‰ to -8‰）, with both isotopes showing a low variability. The carbonate content is low （〈20%）. Carbonate minerals analyzed by X-ray diffraction are mainly composed of calcite, while aragonite was not recorded. The salinity of the lake water is low in the estuary region as a result of the Kaidu River inflow. In comparison, the carbon and oxygen isotope values are higher in the middle and eastern parts of the lake, with δ^13C values between approximately ＋0.5‰ and ＋3‰, and δ^18O values between -1‰ and -5‰. There is a moderate correlation between the stable oxygen and carbon isotopes, with a coefficient of correlation r of approximately 0.63. This implies that the lake water has a relatively short residence time. Carbonate minerals constitute calcite and aragonite in the middle and eastern region of the lake. Aragonite and Mg-calcite are formed at higher lake water salinity and temperatures, and larger evaporation effects. More saline lake water in the middle and eastern region of the lake and the enhanced isotopic equilibrium between water and atmospheric CO2 cause the correlating carbon and oxygen isotope values determined for aragonite and Mg-calcite. Evaporation and biological processes are the main reasons for the salinity and carbonate mineralogy influence of the surface-sediment carbonate in Bosten Lake. The lake water residence time and the CO2 exchange between the atmosphere and the water body control the carbon and oxygen isotope composition of the carbonate sediment. In addition, organic matter pollution and decomposition result in the abnormally low carbon isotope values of the lake surface-sediment carbonate.

Assimilation of carbonate country rock by the parent magma of the Panzhihua Fe-Ti-V deposit(SW China):Evidence from stable isotopes

The Panzhihua intrusion in southwest China is part of the Emeishan Large Igneous Province and host of a large Fe-Ti-V ore deposit.During emplacement of the main intrusion,multiple generations of mafic dykes invaded carbonate wall rocks,producing a large contact aureole.We measured the oxygen-isotope composition of the intrusions,their constituent minerals,and samples of the country rock.Magnetite and plagioclase from Panzhihua intrusion haveδ18O values that are consistent with magmatic equilibrium, and formed from magmas withδ18O values that were 1-2‰higher than expected in a mantle-derived magma.The unmetamorphosed country rock has highδ18O values,ranging from 13.2‰（sandstone） to 24.6-28.6‰（dolomite）.The skarns and marbles from the aureole have lowerδ18O andδ13C values than their protolith suggesting interaction with fluids that were in exchange equilibrium with the adjacent mafic magmas and especially the numerous mafic dykes that intruded the aureole.This would explain the alteration ofδ18O of the dykes which have significantly higher values than expected for a mantle-derived magma.Depending on the exactδ18O values assumed for the magma and contaminant, the amount of assimilation required to produce the elevatedδ18O value of the Panzhihua intrusion was between 8 and 13.7 wt.%,assuming simple mixing.The exact mechanism of contamination is unclear but may involve a combination of assimilation of bulk country rock,mixing with a melt of the country rock and exchange with CO2-rich fluid derived from decarbonation of the marls and dolomites.These mechanisms,particularly the latter,were probably involved in the formation of the Fe-Ti-V ores.

Thermal Ionization Mass Spectrometry (TIMS)-U-Series Ages of Corals from the South China Sea and Holocene High Sea Level

Coral samples collected from the waters off the Leizhou Peninsula, the Hainan Island and the Yongxing Island of the Xisha Islands were analyzed by thermal ionization mass spectrometry (TIMS) and multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) for their U-Th systematics. Their uranium contents are mostly lower than 3μg/g, and the δ+{234}U(T) values are within the range of 150±5. X-ray diffraction analysis showed that the corals are all composed of aragonite. This demonstrates that the corals determined have maintained a close system for 7000 years and their skeletons bear much information about the primitive tropical marine environment. The highly precise age sequence of the corals determined has revealed that there occurred three phases of high sea level in the South China Sea waters, which are dated at 6799-6307 a B.P., 4472-4285 a B.P. and 1279-1012 a B.P., respectively. The three phases lasted 492 a, 187 a and 267 a, respectively. These three phases of high sea level are corresponding to the warm environments that had appeared in China during the Megathermal Period and the Medieval Warm Period in the past ten thousand years.