Organic heterostructures(OHSs)consist of organic micro/nanocrystals are of essential importance for the construction of integrated optoelectronics in the future.However,the scarcity of materials and the problem of pha...Organic heterostructures(OHSs)consist of organic micro/nanocrystals are of essential importance for the construction of integrated optoelectronics in the future.However,the scarcity of materials and the problem of phase separation still hinder the fine synthesis of OHSs.Herein,based on theαphase one-dimensional(1D)microrods and theβphase 2D microplates of one organic compound 3,3′-((1 E,1′E)-anthracene-9,10-diylbis(ethane-2,1-diyl))dibenzonitril(m-B2BCB),we facilely synthesized the OHSs composed of these two polymorph phases,whose growth mechanism is attributed to the low lattice mismatch rate of5.8%between(001)plane ofαphase(trunk)and(010)crystal plane ofβphase(branch).Significantly,the multiport in/output channels can be achieved in the OHSs,which demonstrates the structure-dependent optical signals with the different output channels in the OHSs.Therefore,our experiment exhibits the great prospect of polymorphism in OHSs,which could provide further applications on multifunctional organic integrated photonics circuits.展开更多
基金supported by the National Natural Science Foundation of China(21703148,21971185)the Natural Science Foundation of Jiangsu Province(BK20170330)+2 种基金the Collaborative Innovation Center of Suzhou Nano Science and Technology(CIC-Nano)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the“111”Project of the State Administration of Foreign Experts Affairs of China。
文摘Organic heterostructures(OHSs)consist of organic micro/nanocrystals are of essential importance for the construction of integrated optoelectronics in the future.However,the scarcity of materials and the problem of phase separation still hinder the fine synthesis of OHSs.Herein,based on theαphase one-dimensional(1D)microrods and theβphase 2D microplates of one organic compound 3,3′-((1 E,1′E)-anthracene-9,10-diylbis(ethane-2,1-diyl))dibenzonitril(m-B2BCB),we facilely synthesized the OHSs composed of these two polymorph phases,whose growth mechanism is attributed to the low lattice mismatch rate of5.8%between(001)plane ofαphase(trunk)and(010)crystal plane ofβphase(branch).Significantly,the multiport in/output channels can be achieved in the OHSs,which demonstrates the structure-dependent optical signals with the different output channels in the OHSs.Therefore,our experiment exhibits the great prospect of polymorphism in OHSs,which could provide further applications on multifunctional organic integrated photonics circuits.
