This paper describes the combustion synthesis ofα-Fe2O3 nanopowder at much lower temperature and its catalytic activity for the one-pot preparation of 3,4-dihydropyrano[c]chromenes.The combustion derivedα-Fe_2O_3 na...This paper describes the combustion synthesis ofα-Fe2O3 nanopowder at much lower temperature and its catalytic activity for the one-pot preparation of 3,4-dihydropyrano[c]chromenes.The combustion derivedα-Fe_2O_3 nanopowder was characterized by powder X-ray diffraction（PXRD）,Braunauer,Emmett and Teller（BET） surface area,scanning electron microscopy（SEM） and Fourier transform infrared spectroscopy（FTIR）.Highly efficient,three-component condensation of aromatic aldehyde,malanonitrile and 4- hydroxycoumarin catalyzed byα-Fe2O3 nanoparticles at room temperature is described.The method offers an excellent alternative to the synthesis of 3,4-dihydropyrano[c]chromenes.The reactions are rapid,clean,and the products with good yield and high purity.展开更多
An efficient,inexpensive and simple method for the reduction of variousα,β-unsaturated ketones to corre-sponding saturated ketones using tosyl hydrazide as a hydrogen donor in DMF using calcium oxide powder has been...An efficient,inexpensive and simple method for the reduction of variousα,β-unsaturated ketones to corre-sponding saturated ketones using tosyl hydrazide as a hydrogen donor in DMF using calcium oxide powder has been reported.A variety of enones underwent reduction without forming undesirable side products.High chemose-lectivity,broad functional group tolerance and good yields are the noteworthy features of this protocol.展开更多
基金VTU(VTU/Aca./2009-10/A-9/11714) for the financial support and Chemistry-TEQIP Laboratory of MSRIT and SSMRV College, Chemistry Research Center
文摘This paper describes the combustion synthesis ofα-Fe2O3 nanopowder at much lower temperature and its catalytic activity for the one-pot preparation of 3,4-dihydropyrano[c]chromenes.The combustion derivedα-Fe_2O_3 nanopowder was characterized by powder X-ray diffraction（PXRD）,Braunauer,Emmett and Teller（BET） surface area,scanning electron microscopy（SEM） and Fourier transform infrared spectroscopy（FTIR）.Highly efficient,three-component condensation of aromatic aldehyde,malanonitrile and 4- hydroxycoumarin catalyzed byα-Fe2O3 nanoparticles at room temperature is described.The method offers an excellent alternative to the synthesis of 3,4-dihydropyrano[c]chromenes.The reactions are rapid,clean,and the products with good yield and high purity.
基金University Grant Commission-Basic Science Research(Order no DV-5/662/RFSMS/2012-13),New Delhi,India for financial support.
文摘An efficient,inexpensive and simple method for the reduction of variousα,β-unsaturated ketones to corre-sponding saturated ketones using tosyl hydrazide as a hydrogen donor in DMF using calcium oxide powder has been reported.A variety of enones underwent reduction without forming undesirable side products.High chemose-lectivity,broad functional group tolerance and good yields are the noteworthy features of this protocol.
