The spark energy, E ES , required for 50 percent initiation probability of 41 polynitro compounds was determined. The relationships between the E ES values and impact sensitivity, expressed as drop energies E d of the...The spark energy, E ES , required for 50 percent initiation probability of 41 polynitro compounds was determined. The relationships between the E ES values and impact sensitivity, expressed as drop energies E d of the "first reaction", were established and discussed. The conclusion is made that depending on intermolecular interaction factors in crystals of energetic materials, the mechanism of impact energy transition to the reaction centre of their molecule can be differ from that of transition of energy of electric spark.展开更多
文摘The spark energy, E ES , required for 50 percent initiation probability of 41 polynitro compounds was determined. The relationships between the E ES values and impact sensitivity, expressed as drop energies E d of the "first reaction", were established and discussed. The conclusion is made that depending on intermolecular interaction factors in crystals of energetic materials, the mechanism of impact energy transition to the reaction centre of their molecule can be differ from that of transition of energy of electric spark.