Neodymium dialkylthiophosphate （NdDDP） with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti...Neodymium dialkylthiophosphate （NdDDP） with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti-wear and friction-reducing of the two additives were investigated with four ball experiment and the commercial anti-wear additive ZDDP was selected as control. The elemental analysis of the wear scars after 10 s friction at low stress were investigated by EDXA （Energy Dispersion Analysis of X-ray）. Primary results showed that the NdDDPs possess better lubrication ability than ZDDP. This might mainly be contributed to the formation of a boundary film containing Nd2O3, FeS and sulphate, phosphate, organo-sulfide, etc., and a neodymium-rich diffused layer which changes the crystal structure of the surface of friction materials.展开更多
The vitrification characteristics of municipal solid waste incinerator (MSWI) fly ash were investigated. Effects of temperature on the binding efficiency of heavy metals, the change of chemical compositions and the we...The vitrification characteristics of municipal solid waste incinerator (MSWI) fly ash were investigated. Effects of temperature on the binding efficiency of heavy metals, the change of chemical compositions and the weight loss of fly ash in the range of 800-1350 ℃ were studied. Toxicity Characteristic Leaching Procedure (TCLP) of the United States was used to analyze the leaching characteristics of heavy metals in fly ash and molten slag. Results indicate that chemical compositions, the weight loss of fly ash and the binding efficiency of heavy metals in fly ash have a tremendous change in the range of 1150-1260 ℃. The percentage of CaO, SiO2 and Al2O3 increases with the increasing temperature, whereas it is contrary for SO3, K2O, Na2O and Cl; especially when the temperature is 1260 ℃, the percentage of these four elements decreases sharply from 43.72% to 0.71%. The weight loss occurs obviously in the range of 1150-1260 ℃. Heavy metals of Pb and Cd are almost vaporized above 1000 ℃. Cr is not volatile and its binding efficiency can reach 100% below 1000 ℃. Results of TCLP indicate that the heavy metal content of molten slag is beyond stipulated limit values.展开更多
文摘Neodymium dialkylthiophosphate （NdDDP） with alkyls of isopropyl and isooctyl were synthesized by exchanged reaction respectively. The structures of the two NdDDPs were determined using IR and XRD. Properties of anti-wear and friction-reducing of the two additives were investigated with four ball experiment and the commercial anti-wear additive ZDDP was selected as control. The elemental analysis of the wear scars after 10 s friction at low stress were investigated by EDXA （Energy Dispersion Analysis of X-ray）. Primary results showed that the NdDDPs possess better lubrication ability than ZDDP. This might mainly be contributed to the formation of a boundary film containing Nd2O3, FeS and sulphate, phosphate, organo-sulfide, etc., and a neodymium-rich diffused layer which changes the crystal structure of the surface of friction materials.
基金Sponsored by the Chinese Postdoctoral Fund(Grant No.023205030)National Natural Science Foundation of China(Grant No.20577047)
文摘The vitrification characteristics of municipal solid waste incinerator (MSWI) fly ash were investigated. Effects of temperature on the binding efficiency of heavy metals, the change of chemical compositions and the weight loss of fly ash in the range of 800-1350 ℃ were studied. Toxicity Characteristic Leaching Procedure (TCLP) of the United States was used to analyze the leaching characteristics of heavy metals in fly ash and molten slag. Results indicate that chemical compositions, the weight loss of fly ash and the binding efficiency of heavy metals in fly ash have a tremendous change in the range of 1150-1260 ℃. The percentage of CaO, SiO2 and Al2O3 increases with the increasing temperature, whereas it is contrary for SO3, K2O, Na2O and Cl; especially when the temperature is 1260 ℃, the percentage of these four elements decreases sharply from 43.72% to 0.71%. The weight loss occurs obviously in the range of 1150-1260 ℃. Heavy metals of Pb and Cd are almost vaporized above 1000 ℃. Cr is not volatile and its binding efficiency can reach 100% below 1000 ℃. Results of TCLP indicate that the heavy metal content of molten slag is beyond stipulated limit values.
