Data assimilation(DA)and uncertainty quantification(UQ)are extensively used in analysing and reducing error propagation in high-dimensional spatial-temporal dynamics.Typical applications span from computational fluid ...Data assimilation(DA)and uncertainty quantification(UQ)are extensively used in analysing and reducing error propagation in high-dimensional spatial-temporal dynamics.Typical applications span from computational fluid dynamics(CFD)to geoscience and climate systems.Recently,much effort has been given in combining DA,UQ and machine learning(ML)techniques.These research efforts seek to address some critical challenges in high-dimensional dynamical systems,including but not limited to dynamical system identification,reduced order surrogate modelling,error covariance specification and model error correction.A large number of developed techniques and methodologies exhibit a broad applicability across numerous domains,resulting in the necessity for a comprehensive guide.This paper provides the first overview of state-of-the-art researches in this interdisciplinary field,covering a wide range of applications.This review is aimed at ML scientists who attempt to apply DA and UQ techniques to improve the accuracy and the interpretability of their models,but also at DA and UQ experts who intend to integrate cutting-edge ML approaches to their systems.Therefore,this article has a special focus on how ML methods can overcome the existing limits of DA and UQ,and vice versa.Some exciting perspectives of this rapidly developing research field are also discussed.Index Terms-Data assimilation(DA),deep learning,machine learning(ML),reduced-order-modelling,uncertainty quantification(UQ).展开更多
Environmental stability is a major bottleneck of perovskite solar cells.Only a handful of studies are investigating the effect of moisture on the structural degradation of the absorber.They mostly rely on ex situ expe...Environmental stability is a major bottleneck of perovskite solar cells.Only a handful of studies are investigating the effect of moisture on the structural degradation of the absorber.They mostly rely on ex situ experiments and on completely degraded samples,which restrict the assessment on initial and final stage.By combining in situ X-ray diffraction under controlled 85%relative humidity,and live observations of the water-induced degradation using liquid-cell transmission electron microscopy,we reveal two competitive degradation paths leading on one hand to the decomposition of state-of-theart mixed cation/anion(Cs_(0.05)(MA_(0.17)FA_(0.83))_(0.95)Pb(Br_(0.17)I_(0.83))_(3)(CsMAFA)into PbI_(2) through a dissolution/recrystallization mechanism and,on the other hand,to a non-equilibrium phase segregation leading to CsPb_(2)Br_(5) and a Cesium-poor/iodide-rich Cs_(0.05)-x(MA_(0.17)FA_(0.83))_(0.95)Pb(Br_(0.17-2y)I_(0.83)+2y)_(3) perovskite.This degradation mechanism is corroborated at atomic-scale resolution through solid-state ^(1)H and ^(133)Cs NMR analysis.Exposure to moisture leads to a film containing important heterogeneities in terms of morphology,photoluminescence intensities,and lifetimes.Our results provide new insights and consensus that complex perovskite compositions,though very performant as champion devices,are comparatively metastable,a trait that limits the chances to achieve long-term stability.展开更多
The current climate and energy crisis urgently needs solar cells with efficiencies above the 29% single junction efficiency bottleneck.Silicon/perovskite tandem solar cells are a solution,which is attracting much atte...The current climate and energy crisis urgently needs solar cells with efficiencies above the 29% single junction efficiency bottleneck.Silicon/perovskite tandem solar cells are a solution,which is attracting much attention.While silicon/perovskite tandem cells in 2-terminal and 4-terminal configurations are well documented,the three-terminal concept is still in its infancy.It has significant advantages under low light intensities as opposed to concentrated sunlight,which is the critical factor in designing tandem solar cells for low-cost terrestrial applications.This study pre-sents novel studies of the sub-cell performance of the first three-terminal perovskite/silicon selective band offset barrier tandem solar cells fabricated in an ongoing research project.This study focuses on short circuit current and operating voltages of the subcells under light intensities of one sun and below.Lifetime studies show that the perovskite bulk carrier lifetime is insensitive to illumination,while the silicon cell's lifetime decreases with decreasing light intensity.The combination of perovskite and silicon in the 3T perovskite-silicon tandem therefore reduces the sensitivity of V_(OC) to light intensity and maintains a relatively higher V_(OC) down to low light intensities,whereas silicon single-junction cells show a marked decrease.This technological advantage is proposed as a novel advantage of three-terminal perovkite/silicon solar cells for low light intensities of one sun or less.展开更多
Molecular speciation of atmospheric organic matter was investigated during a short summer field campaign performed in a citrus fruit field in northern Corsica(June 2011). Aimedat assessing the performance on the field...Molecular speciation of atmospheric organic matter was investigated during a short summer field campaign performed in a citrus fruit field in northern Corsica(June 2011). Aimedat assessing the performance on the field of newly developed analytical protocols, this work focuses on the molecular composition of both gas and particulate phases and provides an insight into partitioning behavior of the semi-volatile oxygenated fraction. Limonene ozonolysis tracers were specifically searched for, according to gas chromatography–mass spectrometry(GC–MS) data previously recorded for smog chamber experiments. A screening of other oxygenated species present in the field atmosphere was also performed. About sixty polar molecules were positively or tentatively identified in gas and/or particle phases. These molecules comprise a wide range of branched and linear, mono and di-carbonyls(C_3–C7),mono and di-carboxylic acids(C_3–C_18), and compounds bearing up to three functionalities.Among these compounds, some can be specifically attributed to limonene oxidation and others can be related to α- or β-pinene oxidation. This provides an original snapshot of the organic matter composition at a Mediterranean site in summer. Furthermore, for compounds identified and quantified in both gaseous and particulate phases, an experimental gas/particle partitioning coefficient was determined. Several volatile products, which are not expected in the particulate phase assuming thermodynamic equilibrium, were nonetheless present in significant concentrations. Hypotheses are proposed to explain these observations, such as the possible aerosol viscosity that could hinder the theoretical equilibrium to be rapidly reached.展开更多
The spatial variability of stress fields resulting from polycrystalline aggregate calculations involving random grain geometry and crystal orientations is investigated. A periodogram-based method is proposed to identi...The spatial variability of stress fields resulting from polycrystalline aggregate calculations involving random grain geometry and crystal orientations is investigated. A periodogram-based method is proposed to identify the properties of homogeneous Gaussian random fields （power spectral density and related covariance structure）. Based on a set of finite element polycrystalline aggregate calculations the properties of the maximal principal stress field are identified. Two cases are considered, using either a fixed or random grain geometry. The stability of the method w.r.t the number of samples and the load level （up to 3.5% macroscopic deformation） is investigated.展开更多
The Energy Climate Package is the EU response to the Global Warming Challenge.Induction heating processes can contribute to the energy saving goal:20%saving within 2020.European induction manufacturer already propose ...The Energy Climate Package is the EU response to the Global Warming Challenge.Induction heating processes can contribute to the energy saving goal:20%saving within 2020.European induction manufacturer already propose many efficient solutions at industrial scale.To improve induction devices for an always better energy efficiency,EDF R&D set up a French cooperative project called ISIS with a financial support of the French National Research Agency.Its objective is to promote induction heating as Best Available Technology(BAT)and to develop innovative solutions to increase its efficiency.The ISIS innovations concern the electroheat conversion of induction devices(auto-adaptive multi-coil power supply,low losses coils)and the recovering of fatally lost energy.This paper shows the mid-term results of this project.Firsts control algorithms were successfully tested on a 100 kW 3-coil power supply.A homogenization technique is proposed to model a multi-strand coil.A heat recovery test bench is build and equipped with a PFC control loop to fit with the production fluctuations.展开更多
This study assessed six commercially available in-duct air cleaning devices which are designed to be mounted in the central ventilation system of offices or commercial buildings.The selected devices use different air ...This study assessed six commercially available in-duct air cleaning devices which are designed to be mounted in the central ventilation system of offices or commercial buildings.The selected devices use different air cleaning technologies:mechanical filtration,electrostatic precipitation,gas filtration,ionization/cold plasma,photocatalytic oxidation(PCO)and catalysis under UV light.They were tested against particles,a mixture of volatile organic compounds containing acetone,acetaldehyde,toluene,heptane and formaldehyde,and two bio-contaminants:Aspergillus brasiliensis(fungus)and Staphylococcus epidermidis(bacteria).Two different test rigs were used.The single pass efficiency of each device was determined for three airflow rates,corresponding to face velocities ranging from 0.9 to 2.7 m/s,and two sets of temperature and humidity that are representative of indoor air conditions in wintertime and summertime.The concentration of the chal-lenge volatile organic compounds was also varied in the 30 to 100μg/m^(3)range as a way to characterize their influence on efficiency at realistic concentration levels for non-industrial buildings.Measurements of ozone and formaldehyde concentration downstream of the air cleaners were carried out to determine the emission rate of by-products into the air stream.Finally,the energy issue was addressed by measuring the electric power drawn and pressure loss of the devices.The results showed that two devices,namely a radiant catalytic ionizer and a plasma ionizer,had a very low single pass efficiency against all the challenge pollutants.The association of the plasma ionizer and the electrostatic precipitator did not produce a synergetic effect between the two technologies either,contrary to what their manufacturer claims.Finally,three of the six devices tested were effective in terms of pollutant removal,but only two had an acceptable energy effectiveness in view of their use in low or zero energy buildings.Their energy effectiveness ranged from a few thousand m^(3)/kWh for VOCs at the highest airflow rate(3600 m^(3)/h),to more than 60000 m^(3)/kWh for particles and bio-contaminants at 1200 or 1600 m^(3)/h.These results are at least one order of magnitude higher than the majority of stand-alone air cleaners.Moreover,they suggest that optimal IAQ and energy conditions can be achieved if variable air volume control methods are used to maintain indoor temperature and humidity.展开更多
The fascinating properties of two-dimensional （2D） crystals have gainedincreasing interest for many applications. The synthesis of a 2D silicon structure,namely silicene, is attracting great interest for possible de...The fascinating properties of two-dimensional （2D） crystals have gainedincreasing interest for many applications. The synthesis of a 2D silicon structure,namely silicene, is attracting great interest for possible development of nextgeneration electronic devices. The main difficulty in working with siliceneremains its strong tendency to oxidation when exposed to air as a consequenceof its relatively highly buckled structure. In this work, we univocaUy identifythe Raman mode of air-stable low-buckled silicene nanosheets synthesized onhighly oriented pyrolytic graphite （HOPG） located at 542.5 cm-1. The main focusof this work is Raman spectroscopy and mapping analyses in combination withab initio calculations. Scanning tunneling microscopy images reveal the presenceof a patchwork of Si three-dimensional （3D） clusters and contiguous Si areaspresenting a honeycomb atomic arrangement, rotated by 30° with respect to theHOPG substrate underneath, with a lattice parameter of 0.41±0.02 nm and abuckling of the Si atoms of 0.05 nm. Raman analysis supports the co-existenceof 3D silicon clusters and 2D silicene. The Raman shift of low-buckled siliceneon an inert substrate has not been reported so far and it is completely differentfrom the one calculated for free-standing silicene and the ones measured forsilicene grown on Ag（111） surfaces. Our experimental results are perfectlyreproduced by our ab initio calculations of deposited silicene nanosheets. Thisleads us to conclude that the precise value of the observed Raman shift crucially depends on the strain between the silicene and the HOPG substrate.展开更多
基金the support of the Leverhulme Centre for Wildfires,Environment and Society through the Leverhulme Trust(RC-2018-023)Sibo Cheng,César Quilodran-Casas,and Rossella Arcucci acknowledge the support of the PREMIERE project(EP/T000414/1)+5 种基金the support of EPSRC grant:PURIFY(EP/V000756/1)the Fundamental Research Funds for the Central Universitiesthe support of the SASIP project(353)funded by Schmidt Futures–a philanthropic initiative that seeks to improve societal outcomes through the development of emerging science and technologiesDFG for the Heisenberg Programm Award(JA 1077/4-1)the National Natural Science Foundation of China(61976120)the Natural Science Key Foundat ion of Jiangsu Education Department(21KJA510004)。
文摘Data assimilation(DA)and uncertainty quantification(UQ)are extensively used in analysing and reducing error propagation in high-dimensional spatial-temporal dynamics.Typical applications span from computational fluid dynamics(CFD)to geoscience and climate systems.Recently,much effort has been given in combining DA,UQ and machine learning(ML)techniques.These research efforts seek to address some critical challenges in high-dimensional dynamical systems,including but not limited to dynamical system identification,reduced order surrogate modelling,error covariance specification and model error correction.A large number of developed techniques and methodologies exhibit a broad applicability across numerous domains,resulting in the necessity for a comprehensive guide.This paper provides the first overview of state-of-the-art researches in this interdisciplinary field,covering a wide range of applications.This review is aimed at ML scientists who attempt to apply DA and UQ techniques to improve the accuracy and the interpretability of their models,but also at DA and UQ experts who intend to integrate cutting-edge ML approaches to their systems.Therefore,this article has a special focus on how ML methods can overcome the existing limits of DA and UQ,and vice versa.Some exciting perspectives of this rapidly developing research field are also discussed.Index Terms-Data assimilation(DA),deep learning,machine learning(ML),reduced-order-modelling,uncertainty quantification(UQ).
基金financial support from Region Hauts-de-France,FEDER,and Electricité de France(EDF)through PEROVSTAB programfinancial support from the IR-RMN-THC FR-3050 CNRS France for conducting solid-state NMR measurements.P.R.and G.N.M.R+1 种基金financial support from University of Lille and région Hauts-de-France.F.S“IMPRESSIVE”project which received funding from the European Union’s Horizon 2020 Research and Innovation Program under grant agreement number 826013.
文摘Environmental stability is a major bottleneck of perovskite solar cells.Only a handful of studies are investigating the effect of moisture on the structural degradation of the absorber.They mostly rely on ex situ experiments and on completely degraded samples,which restrict the assessment on initial and final stage.By combining in situ X-ray diffraction under controlled 85%relative humidity,and live observations of the water-induced degradation using liquid-cell transmission electron microscopy,we reveal two competitive degradation paths leading on one hand to the decomposition of state-of-theart mixed cation/anion(Cs_(0.05)(MA_(0.17)FA_(0.83))_(0.95)Pb(Br_(0.17)I_(0.83))_(3)(CsMAFA)into PbI_(2) through a dissolution/recrystallization mechanism and,on the other hand,to a non-equilibrium phase segregation leading to CsPb_(2)Br_(5) and a Cesium-poor/iodide-rich Cs_(0.05)-x(MA_(0.17)FA_(0.83))_(0.95)Pb(Br_(0.17-2y)I_(0.83)+2y)_(3) perovskite.This degradation mechanism is corroborated at atomic-scale resolution through solid-state ^(1)H and ^(133)Cs NMR analysis.Exposure to moisture leads to a film containing important heterogeneities in terms of morphology,photoluminescence intensities,and lifetimes.Our results provide new insights and consensus that complex perovskite compositions,though very performant as champion devices,are comparatively metastable,a trait that limits the chances to achieve long-term stability.
基金The authors acknowledge the support of the H2020 pro-gram for Solar-ERANET funding of the BOBTANDEM(2019-2022).
文摘The current climate and energy crisis urgently needs solar cells with efficiencies above the 29% single junction efficiency bottleneck.Silicon/perovskite tandem solar cells are a solution,which is attracting much attention.While silicon/perovskite tandem cells in 2-terminal and 4-terminal configurations are well documented,the three-terminal concept is still in its infancy.It has significant advantages under low light intensities as opposed to concentrated sunlight,which is the critical factor in designing tandem solar cells for low-cost terrestrial applications.This study pre-sents novel studies of the sub-cell performance of the first three-terminal perovskite/silicon selective band offset barrier tandem solar cells fabricated in an ongoing research project.This study focuses on short circuit current and operating voltages of the subcells under light intensities of one sun and below.Lifetime studies show that the perovskite bulk carrier lifetime is insensitive to illumination,while the silicon cell's lifetime decreases with decreasing light intensity.The combination of perovskite and silicon in the 3T perovskite-silicon tandem therefore reduces the sensitivity of V_(OC) to light intensity and maintains a relatively higher V_(OC) down to low light intensities,whereas silicon single-junction cells show a marked decrease.This technological advantage is proposed as a novel advantage of three-terminal perovkite/silicon solar cells for low light intensities of one sun or less.
文摘Molecular speciation of atmospheric organic matter was investigated during a short summer field campaign performed in a citrus fruit field in northern Corsica(June 2011). Aimedat assessing the performance on the field of newly developed analytical protocols, this work focuses on the molecular composition of both gas and particulate phases and provides an insight into partitioning behavior of the semi-volatile oxygenated fraction. Limonene ozonolysis tracers were specifically searched for, according to gas chromatography–mass spectrometry(GC–MS) data previously recorded for smog chamber experiments. A screening of other oxygenated species present in the field atmosphere was also performed. About sixty polar molecules were positively or tentatively identified in gas and/or particle phases. These molecules comprise a wide range of branched and linear, mono and di-carbonyls(C_3–C7),mono and di-carboxylic acids(C_3–C_18), and compounds bearing up to three functionalities.Among these compounds, some can be specifically attributed to limonene oxidation and others can be related to α- or β-pinene oxidation. This provides an original snapshot of the organic matter composition at a Mediterranean site in summer. Furthermore, for compounds identified and quantified in both gaseous and particulate phases, an experimental gas/particle partitioning coefficient was determined. Several volatile products, which are not expected in the particulate phase assuming thermodynamic equilibrium, were nonetheless present in significant concentrations. Hypotheses are proposed to explain these observations, such as the possible aerosol viscosity that could hinder the theoretical equilibrium to be rapidly reached.
文摘The spatial variability of stress fields resulting from polycrystalline aggregate calculations involving random grain geometry and crystal orientations is investigated. A periodogram-based method is proposed to identify the properties of homogeneous Gaussian random fields （power spectral density and related covariance structure）. Based on a set of finite element polycrystalline aggregate calculations the properties of the maximal principal stress field are identified. Two cases are considered, using either a fixed or random grain geometry. The stability of the method w.r.t the number of samples and the load level （up to 3.5% macroscopic deformation） is investigated.
基金Item Sponsored by French Research National Agency (ANR) Through "Efficacite Energetique et Reduction des Emissions de CO_2 Dans les Systemes Industriels" Program(Project ISIS n°ANR-09-EESI-004)
文摘The Energy Climate Package is the EU response to the Global Warming Challenge.Induction heating processes can contribute to the energy saving goal:20%saving within 2020.European induction manufacturer already propose many efficient solutions at industrial scale.To improve induction devices for an always better energy efficiency,EDF R&D set up a French cooperative project called ISIS with a financial support of the French National Research Agency.Its objective is to promote induction heating as Best Available Technology(BAT)and to develop innovative solutions to increase its efficiency.The ISIS innovations concern the electroheat conversion of induction devices(auto-adaptive multi-coil power supply,low losses coils)and the recovering of fatally lost energy.This paper shows the mid-term results of this project.Firsts control algorithms were successfully tested on a 100 kW 3-coil power supply.A homogenization technique is proposed to model a multi-strand coil.A heat recovery test bench is build and equipped with a PFC control loop to fit with the production fluctuations.
文摘This study assessed six commercially available in-duct air cleaning devices which are designed to be mounted in the central ventilation system of offices or commercial buildings.The selected devices use different air cleaning technologies:mechanical filtration,electrostatic precipitation,gas filtration,ionization/cold plasma,photocatalytic oxidation(PCO)and catalysis under UV light.They were tested against particles,a mixture of volatile organic compounds containing acetone,acetaldehyde,toluene,heptane and formaldehyde,and two bio-contaminants:Aspergillus brasiliensis(fungus)and Staphylococcus epidermidis(bacteria).Two different test rigs were used.The single pass efficiency of each device was determined for three airflow rates,corresponding to face velocities ranging from 0.9 to 2.7 m/s,and two sets of temperature and humidity that are representative of indoor air conditions in wintertime and summertime.The concentration of the chal-lenge volatile organic compounds was also varied in the 30 to 100μg/m^(3)range as a way to characterize their influence on efficiency at realistic concentration levels for non-industrial buildings.Measurements of ozone and formaldehyde concentration downstream of the air cleaners were carried out to determine the emission rate of by-products into the air stream.Finally,the energy issue was addressed by measuring the electric power drawn and pressure loss of the devices.The results showed that two devices,namely a radiant catalytic ionizer and a plasma ionizer,had a very low single pass efficiency against all the challenge pollutants.The association of the plasma ionizer and the electrostatic precipitator did not produce a synergetic effect between the two technologies either,contrary to what their manufacturer claims.Finally,three of the six devices tested were effective in terms of pollutant removal,but only two had an acceptable energy effectiveness in view of their use in low or zero energy buildings.Their energy effectiveness ranged from a few thousand m^(3)/kWh for VOCs at the highest airflow rate(3600 m^(3)/h),to more than 60000 m^(3)/kWh for particles and bio-contaminants at 1200 or 1600 m^(3)/h.These results are at least one order of magnitude higher than the majority of stand-alone air cleaners.Moreover,they suggest that optimal IAQ and energy conditions can be achieved if variable air volume control methods are used to maintain indoor temperature and humidity.
文摘The fascinating properties of two-dimensional （2D） crystals have gainedincreasing interest for many applications. The synthesis of a 2D silicon structure,namely silicene, is attracting great interest for possible development of nextgeneration electronic devices. The main difficulty in working with siliceneremains its strong tendency to oxidation when exposed to air as a consequenceof its relatively highly buckled structure. In this work, we univocaUy identifythe Raman mode of air-stable low-buckled silicene nanosheets synthesized onhighly oriented pyrolytic graphite （HOPG） located at 542.5 cm-1. The main focusof this work is Raman spectroscopy and mapping analyses in combination withab initio calculations. Scanning tunneling microscopy images reveal the presenceof a patchwork of Si three-dimensional （3D） clusters and contiguous Si areaspresenting a honeycomb atomic arrangement, rotated by 30° with respect to theHOPG substrate underneath, with a lattice parameter of 0.41±0.02 nm and abuckling of the Si atoms of 0.05 nm. Raman analysis supports the co-existenceof 3D silicon clusters and 2D silicene. The Raman shift of low-buckled siliceneon an inert substrate has not been reported so far and it is completely differentfrom the one calculated for free-standing silicene and the ones measured forsilicene grown on Ag（111） surfaces. Our experimental results are perfectlyreproduced by our ab initio calculations of deposited silicene nanosheets. Thisleads us to conclude that the precise value of the observed Raman shift crucially depends on the strain between the silicene and the HOPG substrate.
