We demonstrate the hybridization of the plasmonic modes in directly coupled whispering gallery cavities fabricated on silver films and present the mode patterns and energy levels using cathodoluminescence spectroscopy...We demonstrate the hybridization of the plasmonic modes in directly coupled whispering gallery cavities fabricated on silver films and present the mode patterns and energy levels using cathodoluminescence spectroscopy. Although the energy of the most antisymmetrically coupled modes is higher than that of the corresponding symmetrically coupled ones, the contrary cases happen for small quantum number modes. We attribute the phenomenon to the different surface plasmon polariton paths between the symmetrically and antisymmetrically coupled modes; These results provide an understanding of the resonant properties in coupled plasmonic cavities, which have potential applications in nanophotonic devices.展开更多
This paper describes the design of a battery-assisted Ultra-High Frequency (UHF) Radio-Fre- quency IDentification (RFID) tag suitable for embedding in concrete materials and its measurement in a mortar slab. The devic...This paper describes the design of a battery-assisted Ultra-High Frequency (UHF) Radio-Fre- quency IDentification (RFID) tag suitable for embedding in concrete materials and its measurement in a mortar slab. The device is built to communicate wirelessly not only the ID number of the RFID chip but also the digitalized output of a strain gauge sensor. Design optimizations of the RFID antenna is based on published permittivity and conductivity values of concrete. Experimental read ranges are measured from 800 to 1000 MHz with the help of commercial test equipment. Reading is possible up to 50 cm from the surface of a mortar block for a tag embedded 5 cm below the surface. This result is the first published one for RFID tags embedded in concrete or mortar.展开更多
This paper reports fast and efficient chemical decontamination of water within a tree-branched centimeter-scale microfluidic reactor.The microreactor integrates Zinc oxide nanowires(ZnO NWs)in situ grown acting as an ...This paper reports fast and efficient chemical decontamination of water within a tree-branched centimeter-scale microfluidic reactor.The microreactor integrates Zinc oxide nanowires(ZnO NWs)in situ grown acting as an efficient photocatalytic nanomaterial layer.Direct growth of ZnO NWs within the microfluidic chamber brings this photocatalytic medium at the very close vicinity of the water flow path,hence minimizing the required interaction time to produce efficient purification performance.We demonstrate a degradation efficiency of 95%in o5 s of residence time in one-pass only.According to our estimates,it becomes attainable using microfluidic reactors to produce decontamination of merely 1 l of water per day,typical of the human daily drinking water needs.To conduct our experiments,we have chosen a laboratory-scale case study as a seed for addressing the health concern of water contamination by volatile organic compounds(VOCs),which remain difficult to remove using alternative decontamination techniques,especially those involving water evaporation.The contaminated water sample contains mixture of five pollutants:Benzene;Toluene;Ethylbenzene;m–p Xylenes;and o-Xylene(BTEX)diluted in water at 10 p.p.m.concentration of each.Degradation was analytically monitored in a selective manner until it falls below 1 p.p.m.for each of the five pollutants,corresponding to the maximum contaminant level(MCL)established by the US Environmental Protection Agency(EPA).We also report on a preliminary study,investigating the nature of the chemical by-products after the photocatalytic VOCs degradation process.展开更多
Photocatalysis is one of the most promising processes for treating air and water pollution.Innovative civil engineering materials for environmental depollution by photocatalysis have already been synthesized by incorp...Photocatalysis is one of the most promising processes for treating air and water pollution.Innovative civil engineering materials for environmental depollution by photocatalysis have already been synthesized by incorporating TiO_(2) or ZnO nanoparticles in cement.This method suffers from two flaws:first,most of the NPs are incorporated into the cement and useless for photocatalysis;second,rain and wind could spread the potentially carcinogenic nanoparticles from the cement surface into nature.Thus,we propose the efficient synthesis of nontoxic and biocompatible ZnO nanostructures solely onto the surface of commercially available concrete and tiling pavements by a low-cost and lowtemperature hydrothermal method.Our samples exhibited enhanced photocatalytic activity for degrading organic dyes in aqueous media,and dye molecules are commonly used in the pharmaceutical,food,and textile industries.Durability studies showed no loss of efficiency after four photocatalysis experiments.Such supported structures,which are easy to implement onto the varying surfaces of commercially available materials,are promising for integration into civil engineering surfaces for environmental depollution in our daily life.展开更多
A MEMS electrostatic kinetic energy harvester(e-KEH)of about 1 cm2,working at ultralow frequency(1–20 Hz),without any supported additional mass on its mobile electrode,and working even without a vacuum environment is...A MEMS electrostatic kinetic energy harvester(e-KEH)of about 1 cm2,working at ultralow frequency(1–20 Hz),without any supported additional mass on its mobile electrode,and working even without a vacuum environment is reported.The prototype is especially suitable for environments with abundant low frequency motions such as wearable electronics.The proposed e-KEH consists of a capacitor with a finger-teeth interdigited comb structure.This greatly reduces the air damping effect,and thus the capacitance variation remains important regardless of the presence of air.With the new design,the energy transduced per cycle of excitation is no less than 33 times higher than the classic design within 10–40 Hz/2 g_(peak),while is 85 times higher at 15 Hz/2 g_(peak).An enclosed miniature ball combined with non-linear stoppers enables the oscillation of the movable electrode through impact-based frequency up-conversion mechanism,which is also improved by the low air damping.Thanks to this new design,a higher efficiency than the classic gap-closing comb structure is obtained,as a larger range of working frequency(1–180 Hz)in air.A maximum energy conversion of 450 nJ/cycle is obtained with a bias voltage of 45 V and an acceleration of 11 Hz,3 g_(peak).Working with a diode AC-DC rectifier,the proposed KEH is able to support up to 3 RFID communications within 16 s while operated at 11 Hz,3 g_(peak).展开更多
Optical spectrometers enable contactless chemical analysis.However,decreasing both their size and cost appears to be a prerequisite to their widespread deployment.Chip-scale implementation of optical spectrometers sti...Optical spectrometers enable contactless chemical analysis.However,decreasing both their size and cost appears to be a prerequisite to their widespread deployment.Chip-scale implementation of optical spectrometers still requires tackling two main challenges.First,operation over a broad spectral range extending to the infrared is required to enable covering the molecular absorption spectrum of a broad variety of materials.This is addressed in our work with an Micro-Electro Mechanical Systems(MEMS)-based Fourier transform infrared spectrometer with an embedded movable micro-mirror on a silicon chip.Second,fine spectral resolutionΔλis also required to facilitate screening over several chemicals.A fundamental limit states thatΔλis inversely proportional to the mirror motion range,which cannot exceed the chip size.To boost the spectral resolution beyond this limit,we propose the concept of parallel(or multi-core)FTIR,where multiple interferometers provide complementary optical paths using the same actuator and within the same chip.The concept scalability is validated with 4 interferometers,leading to approximately 3 times better spectral resolution.After the atmospheric contents of a greenhouse gas are monitored,the methane absorption bands are successfully measured and discriminated using the presented device.展开更多
Co-integration of nanomaterials into microdevices poses several technological challenges and presents numerous scientific opportunities that have been addressed in this paper by integrating zinc oxide nanowires(ZnO-NW...Co-integration of nanomaterials into microdevices poses several technological challenges and presents numerous scientific opportunities that have been addressed in this paper by integrating zinc oxide nanowires(ZnO-NWs)into a microfluidic chamber.In addition to the applications of these combined materials,this work focuses on the study of the growth dynamics and uniformity of nanomaterials in a tiny microfluidic reactor environment.A unique experimental platform was built through the integration of a noninvasive optical charaaerization technique with the microfluidic reactor.This platform allowed the unprecedented demonstration of time-resolved and spatially resolved monitoring of the in situ growth of NWs,in which the chemicals were continuously fed into the microfluidic reactor.The platform was also used to assess the uniformity of NWs grown quickly in a 10-mm-wide microchamber,which was intentionally chosen to be 20 times wider than those used in previous attempts because it can accommodate applications requiring a large surface of interaction while still taking advantage of submillimeter height.Further observations included the effects of varying the flow rate on the NW diameter and length in addition to a synergetic effect of continuous renewal of the growth solution and the confined environment of the chemical reaction.展开更多
Miniaturized optical benches process free-space light propagating in-plane with respect to the substrate and have a large variety of applications,including the coupling of light through an optical fiber.High coupling ...Miniaturized optical benches process free-space light propagating in-plane with respect to the substrate and have a large variety of applications,including the coupling of light through an optical fiber.High coupling efficiency is usually obtained using assembled micro-optical parts,which considerably increase the system cost and integration effort.In this work,we report a high coupling efficiency,monolithically integrated silicon micromirror with controlled three-dimensional(3D)curvature that is capable of manipulating optical beams propagating in the plane of the silicon substrate.Based on our theoretical modeling,a spherical micromirror with a microscale radius of curvature as small as twice the Gaussian beam Rayleigh range provides a 100%coupling efficiency over a relatively long optical path range.Introducing dimensionless parameters facilitates the elucidation of the role of key design parameters,including the mirror’s radii of curvature,independent of the wavelength.A micromachining method is presented for fabricating the 3D micromirror using fluorinated gas plasmas.The measured coupling efficiency was greater than 50%over a 200-mm optical path,compared to less than 10%afforded by a conventional flat micromirror,which was in good agreement with the model.Using the 3D micromirror,an optical cavity was formed with a round-trip diffraction loss of less than 0.4%,resulting in one order of magnitude enhancement in the measured quality factor.A nearly 100%coupling was also estimated when matching the sagittal and tangential radii of curvature of the presented micromirror’s surface.The reported class of 3D micromirrors may be an advantageous replacement for the optical lenses usually assembled in silicon photonics and optical benches by transforming them into real 3D monolithic systems while achieving wideband high coupling efficiency over submillimeter distances.展开更多
In 2015,195 countries of the United Nations proposed Sustainable Development Goals so as to alleviate the problems of climate change and global pollution.In France,there is a scientist dedicated to contribute providin...In 2015,195 countries of the United Nations proposed Sustainable Development Goals so as to alleviate the problems of climate change and global pollution.In France,there is a scientist dedicated to contribute providing solutions for above issues by virtue of MEMS,Lab-On-Chip and metamaterials.This expert is Prof.Tarik Bourouina,a Professor of Physics at ESIEE Paris,UniversitéGustave Eiffel.He devoted himself to the investigations on micro sensors and metamaterials,and kept seeking their applications in the future blueprint of“Sustainable”and“Smart”cities.展开更多
基金Supported by the National Basic Research Program of China under Grant No 2013CB932602the National Natural Science Foundation of China under Grant Nos 11574011,61377050 and 11234001
文摘We demonstrate the hybridization of the plasmonic modes in directly coupled whispering gallery cavities fabricated on silver films and present the mode patterns and energy levels using cathodoluminescence spectroscopy. Although the energy of the most antisymmetrically coupled modes is higher than that of the corresponding symmetrically coupled ones, the contrary cases happen for small quantum number modes. We attribute the phenomenon to the different surface plasmon polariton paths between the symmetrically and antisymmetrically coupled modes; These results provide an understanding of the resonant properties in coupled plasmonic cavities, which have potential applications in nanophotonic devices.
文摘This paper describes the design of a battery-assisted Ultra-High Frequency (UHF) Radio-Fre- quency IDentification (RFID) tag suitable for embedding in concrete materials and its measurement in a mortar slab. The device is built to communicate wirelessly not only the ID number of the RFID chip but also the digitalized output of a strain gauge sensor. Design optimizations of the RFID antenna is based on published permittivity and conductivity values of concrete. Experimental read ranges are measured from 800 to 1000 MHz with the help of commercial test equipment. Reading is possible up to 50 cm from the surface of a mortar block for a tag embedded 5 cm below the surface. This result is the first published one for RFID tags embedded in concrete or mortar.
基金This work has received funding from the ANR EquipEx SENSECITY projectthe FUI 18 MIMESYS funded by Region Ile-de-France and the European Union’s H2020 Programme for research,technological development and demonstration under grant agreement No 644852.
文摘This paper reports fast and efficient chemical decontamination of water within a tree-branched centimeter-scale microfluidic reactor.The microreactor integrates Zinc oxide nanowires(ZnO NWs)in situ grown acting as an efficient photocatalytic nanomaterial layer.Direct growth of ZnO NWs within the microfluidic chamber brings this photocatalytic medium at the very close vicinity of the water flow path,hence minimizing the required interaction time to produce efficient purification performance.We demonstrate a degradation efficiency of 95%in o5 s of residence time in one-pass only.According to our estimates,it becomes attainable using microfluidic reactors to produce decontamination of merely 1 l of water per day,typical of the human daily drinking water needs.To conduct our experiments,we have chosen a laboratory-scale case study as a seed for addressing the health concern of water contamination by volatile organic compounds(VOCs),which remain difficult to remove using alternative decontamination techniques,especially those involving water evaporation.The contaminated water sample contains mixture of five pollutants:Benzene;Toluene;Ethylbenzene;m–p Xylenes;and o-Xylene(BTEX)diluted in water at 10 p.p.m.concentration of each.Degradation was analytically monitored in a selective manner until it falls below 1 p.p.m.for each of the five pollutants,corresponding to the maximum contaminant level(MCL)established by the US Environmental Protection Agency(EPA).We also report on a preliminary study,investigating the nature of the chemical by-products after the photocatalytic VOCs degradation process.
基金This study was funded by the“I-Street”project(2017,ADEME via the Investissements d’Avenir Program,France)The financial and technical support linked to this project provided by IFSTTAR are gratefully acknowledged.
文摘Photocatalysis is one of the most promising processes for treating air and water pollution.Innovative civil engineering materials for environmental depollution by photocatalysis have already been synthesized by incorporating TiO_(2) or ZnO nanoparticles in cement.This method suffers from two flaws:first,most of the NPs are incorporated into the cement and useless for photocatalysis;second,rain and wind could spread the potentially carcinogenic nanoparticles from the cement surface into nature.Thus,we propose the efficient synthesis of nontoxic and biocompatible ZnO nanostructures solely onto the surface of commercially available concrete and tiling pavements by a low-cost and lowtemperature hydrothermal method.Our samples exhibited enhanced photocatalytic activity for degrading organic dyes in aqueous media,and dye molecules are commonly used in the pharmaceutical,food,and textile industries.Durability studies showed no loss of efficiency after four photocatalysis experiments.Such supported structures,which are easy to implement onto the varying surfaces of commercially available materials,are promising for integration into civil engineering surfaces for environmental depollution in our daily life.
文摘A MEMS electrostatic kinetic energy harvester(e-KEH)of about 1 cm2,working at ultralow frequency(1–20 Hz),without any supported additional mass on its mobile electrode,and working even without a vacuum environment is reported.The prototype is especially suitable for environments with abundant low frequency motions such as wearable electronics.The proposed e-KEH consists of a capacitor with a finger-teeth interdigited comb structure.This greatly reduces the air damping effect,and thus the capacitance variation remains important regardless of the presence of air.With the new design,the energy transduced per cycle of excitation is no less than 33 times higher than the classic design within 10–40 Hz/2 g_(peak),while is 85 times higher at 15 Hz/2 g_(peak).An enclosed miniature ball combined with non-linear stoppers enables the oscillation of the movable electrode through impact-based frequency up-conversion mechanism,which is also improved by the low air damping.Thanks to this new design,a higher efficiency than the classic gap-closing comb structure is obtained,as a larger range of working frequency(1–180 Hz)in air.A maximum energy conversion of 450 nJ/cycle is obtained with a bias voltage of 45 V and an acceleration of 11 Hz,3 g_(peak).Working with a diode AC-DC rectifier,the proposed KEH is able to support up to 3 RFID communications within 16 s while operated at 11 Hz,3 g_(peak).
文摘Optical spectrometers enable contactless chemical analysis.However,decreasing both their size and cost appears to be a prerequisite to their widespread deployment.Chip-scale implementation of optical spectrometers still requires tackling two main challenges.First,operation over a broad spectral range extending to the infrared is required to enable covering the molecular absorption spectrum of a broad variety of materials.This is addressed in our work with an Micro-Electro Mechanical Systems(MEMS)-based Fourier transform infrared spectrometer with an embedded movable micro-mirror on a silicon chip.Second,fine spectral resolutionΔλis also required to facilitate screening over several chemicals.A fundamental limit states thatΔλis inversely proportional to the mirror motion range,which cannot exceed the chip size.To boost the spectral resolution beyond this limit,we propose the concept of parallel(or multi-core)FTIR,where multiple interferometers provide complementary optical paths using the same actuator and within the same chip.The concept scalability is validated with 4 interferometers,leading to approximately 3 times better spectral resolution.After the atmospheric contents of a greenhouse gas are monitored,the methane absorption bands are successfully measured and discriminated using the presented device.
基金the l-SITE FUTURE Initiative(reference ANR-16-IDEX-0003)in the frame of the project NANO-4-WATER.
文摘Co-integration of nanomaterials into microdevices poses several technological challenges and presents numerous scientific opportunities that have been addressed in this paper by integrating zinc oxide nanowires(ZnO-NWs)into a microfluidic chamber.In addition to the applications of these combined materials,this work focuses on the study of the growth dynamics and uniformity of nanomaterials in a tiny microfluidic reactor environment.A unique experimental platform was built through the integration of a noninvasive optical charaaerization technique with the microfluidic reactor.This platform allowed the unprecedented demonstration of time-resolved and spatially resolved monitoring of the in situ growth of NWs,in which the chemicals were continuously fed into the microfluidic reactor.The platform was also used to assess the uniformity of NWs grown quickly in a 10-mm-wide microchamber,which was intentionally chosen to be 20 times wider than those used in previous attempts because it can accommodate applications requiring a large surface of interaction while still taking advantage of submillimeter height.Further observations included the effects of varying the flow rate on the NW diameter and length in addition to a synergetic effect of continuous renewal of the growth solution and the confined environment of the chemical reaction.
基金This work was partially supported by the Information Technology Industry Development Agency(ITIDA)through the ITAC program.
文摘Miniaturized optical benches process free-space light propagating in-plane with respect to the substrate and have a large variety of applications,including the coupling of light through an optical fiber.High coupling efficiency is usually obtained using assembled micro-optical parts,which considerably increase the system cost and integration effort.In this work,we report a high coupling efficiency,monolithically integrated silicon micromirror with controlled three-dimensional(3D)curvature that is capable of manipulating optical beams propagating in the plane of the silicon substrate.Based on our theoretical modeling,a spherical micromirror with a microscale radius of curvature as small as twice the Gaussian beam Rayleigh range provides a 100%coupling efficiency over a relatively long optical path range.Introducing dimensionless parameters facilitates the elucidation of the role of key design parameters,including the mirror’s radii of curvature,independent of the wavelength.A micromachining method is presented for fabricating the 3D micromirror using fluorinated gas plasmas.The measured coupling efficiency was greater than 50%over a 200-mm optical path,compared to less than 10%afforded by a conventional flat micromirror,which was in good agreement with the model.Using the 3D micromirror,an optical cavity was formed with a round-trip diffraction loss of less than 0.4%,resulting in one order of magnitude enhancement in the measured quality factor.A nearly 100%coupling was also estimated when matching the sagittal and tangential radii of curvature of the presented micromirror’s surface.The reported class of 3D micromirrors may be an advantageous replacement for the optical lenses usually assembled in silicon photonics and optical benches by transforming them into real 3D monolithic systems while achieving wideband high coupling efficiency over submillimeter distances.
文摘In 2015,195 countries of the United Nations proposed Sustainable Development Goals so as to alleviate the problems of climate change and global pollution.In France,there is a scientist dedicated to contribute providing solutions for above issues by virtue of MEMS,Lab-On-Chip and metamaterials.This expert is Prof.Tarik Bourouina,a Professor of Physics at ESIEE Paris,UniversitéGustave Eiffel.He devoted himself to the investigations on micro sensors and metamaterials,and kept seeking their applications in the future blueprint of“Sustainable”and“Smart”cities.